Abstract
Lake sediments can be significantly impacted by industrial activities. These impacts vary among sites and include both local point sources and atmospherically-derived pollution. Here we present results of a lake sediment pollution record from Ullswater, UK, where lead mining activities have taken place within the catchment since 1690, although large-scale mining did not begin until 1840. Metal concentration data from 12 cores taken along a lake bed transect illustrate that lead mining at Greenside Mine had a significant impact on the lake sediments. High Pb concentrations were identified throughout Ullswater, and exhibited a spatial gradient from south to north, with concentrations decreasing with greater distance from the main source of input at Glenridding. Furthermore, inter-element correlations exhibit spatial variation that reflects the processes by which they are incorporated into the lake sediment record. Together, these observations illustrate potential shortcomings in palaeoenvironmental reconstructions and pollution studies based on single cores from large and morphologically variable lakes. Sedimentation rates were estimated by matching this pollution record with the historical record of mining activities. Within Ullswater, sedimentation rates from 1840 to the present varied from 0.67 to 2.33 mm year−1 with a mean of 1.4 mm year−1; highest sedimentation rates were observed in the deepest section of the lake and close to the main inputs, and lowest sedimentation rates were observed in the northern part of the lake, furthest from the main input. Despite the considerable changes in mining techniques and production, there is little evidence to suggest significant changes in sedimentation rates over time.
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References
Allen JRL, Rae JE (1986) Time sequence of metal pollution, Severn Estuary, Southwestern UK. Mar Pollut Bull 17:427–431. doi:10.1016/0025-326X(86)90323-1
Anderton J, Haworth EY, Horne DJ, Wray DS (1998) Environmental impacts of lead mining in the Ullswater catchment (English Lake District): dam failures and flooding. In: Bennett MR, Doyle P (eds) Issues in environmental geology: a British perspective. The Geological Society, London, pp 226–242
Appleby PG (1996) Radiometric dating of a sediment core from Ullswater, Cumbria. Unpublished report, Environmental Radioactivity Research Centre, University of Liverpool
Boyle JF (1995) A simple closure mechanism for a compact, large-diameter, gravity corer. J Paleolimnol 13:85–87. doi:10.1007/BF00678113
Boyle JF (2000) Rapid elemental analysis of sediment samples by isotope source XRF. J Paleolimnol 23:213–221. doi:10.1023/A:1008053503694
Brannvall ML, Bindler R, Renberg I, Emteryd O, Bartnicki J, Billstrom K (1999) The Medieval metal industry was the cradle of modern large scale atmospheric lead pollution in northern Europe. Environ Sci Technol 33:4391–4395. doi:10.1021/es990279n
British Geological Survey (1992) Regional geochemistry of the Lake District and adjacent areas. British Geological Survey, Keyworth, Nottingham
Everard M, Denny P (1984) The transfer of lead by fresh-water snails in Ullswater, Cumbria. Environ Pollut Ecol Biol 35:299–314
Everard M, Denny P (1985) Particulates and the cycling of lead in Ullswater, Cumbria. Freshw Biol 15:215–226. doi:10.1111/j.1365-2427.1985.tb00194.x
Farmer JG, Eades LJ, Mackenzie AB, Kirika A, Bailey Watts TE (1996) Stable lead isotope record of lead pollution in Loch Lomond sediments since 1630 AD. Environ Sci Technol 30:3080–3083. doi:10.1021/es960162o
Farmer JG, MacKenzie AB, Eades LJ, Kirika A, Bailey Watts AE (1997) Influences on the extent and record of heavy metal pollution in sediment cores from Loch Tay in a mineralised area of Scotland. J Geochem Explor 58:195–202. doi:10.1016/S0375-6742(96)00060-X
Heyvaert AC, Reuter JE, Slotton DG, Goldman CR (2000) Paleolimnological reconstruction of historical atmospheric lead and mercury deposition at Lake Tahoe, California-Nevada. Environ Sci Technol 34:3588–3597. doi:10.1021/es991309p
Kember HM (2001) A study of metal contamination of sediments within Lake Ullswater and the Glenridding Beck catchment. Undergraduate Dissertation, Department of Environmental Science, University of Lancaster
King L, Barker P, Jones RI (2000) Epilithic algal communities and their relationship to environmental variables in lakes of the English Lake District. Freshw Biol 45:425–442. doi:10.1046/j.1365-2427.2000.00633.x
Met Office (2007) Historic station data. Last accessed 2/12/2007. http://www.metoffice.gov.uk/climate/uk/stationdata/newtonriggdata.txt
Mighall TM, Abrahams PW, Grattan JP, Hayes D, Timberlake S, Forsyth S (2002) Geochemical evidence for atmospheric pollution derived from prehistoric copper mining at Copa Hill, Cwmystwyth, mid-Wales, UK. Sci Total Environ 292:69–80. doi:10.1016/S0048-9697(02)00027-X
Mill HR (1895) Bathymetrical survey of the English Lake District. Geogr J 6:46–73. doi:10.2307/1773952
Morrill C, Overpeck JT, Cole JE, Liu KB, Shen CM, Tang LY (2006) Holocene variations in the Asian monsoon inferred from the geochemistry of lake sediments in central Tibet. Quat Res 65:232–243. doi:10.1016/j.yqres.2005.02.014
Murphy S (1996) Grey gold: men, mining and metallurgy at the Greenside Mine in Cumbria, England 1825 to 1962. Moiety Publishing, Tanworth-in-Arden, UK
Oldfield F, Wake R, Boyle J, Jones R, Nolan S, Gibbs Z, Appleby P, Fisher E, Wolff G (2003) The late-Holocene history of Gormire Lake (NE England) and its catchment: a multiproxy reconstruction of past human impact. Holocene 13:677–690. doi:10.1191/0959683603hl654rp
Peyron O, Begeot C, Brewer S, Heiri O, Magny M, Millet L, Ruffaldi P, Van Campo E, Yu G (2005) Late-glacial climatic changes in Eastern France (Lake Lautrey) from pollen, lake-levels, and chironomids. Quat Res 64:197–211. doi:10.1016/j.yqres.2005.01.006
Plater AJ, Ridgway J, Appleby PG, Berry A, Wright MR (1998) Historical contaminant fluxes in the Tees estuary, UK: geochemical, magnetic and radionuclide evidence. Mar Pollut Bull 37:343–360. doi:10.1016/S0025-326X(99)00052-1
Price GD, Winkle K, Gehrels WR (2005) A geochemical record of the mining history of the Erme Estuary, south Devon, UK. Mar Pollut Bull 50:1706–1712. doi:10.1016/j.marpolbul.2005.07.016
Renberg I, Bindler R, Brannvall ML (2001) Using the historical atmospheric lead-deposition record as a chronological marker in sediment deposits in Europe. Holocene 11:511–516. doi:10.1191/095968301680223468
Renberg I, Brannvall ML, Bindler R, Emteryd O (2002) Stable lead isotopes and lake sediments—a useful combination for the study of atmospheric lead pollution history. Sci Total Environ 292:45–54. doi:10.1016/S0048-9697(02)00032-3
Settle DM, Patterson CC (1980) Lead in Albacore—a guide to lead pollution in Americans. Science 207:1167–1176. doi:10.1126/science.6986654
Tarasov P, Bezrukova E, Karabanov E, Nakagawa T, Wagner M, Kulagina N, Letunova P, Abzaeva A, Granoszewski W, Riedel F (2007) Vegetation and climate dynamics during the Holocene and Eemian interglacials derived from Lake Baikal pollen records. Palaeogeogr Palaeoclimatol Palaeoecol 252:440–457. doi:10.1016/j.palaeo.2007.05.002
Tyler I (2001) Greenside and the mines of the Ullswater valley. Blue Rock Publications, Keswick, Cumbria
Vermillion B, Brugam R, Retzlaff W, Bala I (2005) The sedimentary record of environmental lead contamination at St. Louis, Missouri (USA) area smelters. J Paleolimnol 33:189–203. doi:10.1007/s10933-004-4078-x
VonGunten HR, Sturm M, Moser RN (1997) 200-year record of metals in lake sediments and natural background concentrations. Environ Sci Technol 31:2193–2197. doi:10.1021/es960616h
Wedepohl KH (ed) (1969) Handbook of geochemistry. Springer, Berlin
Wennrich R, Mattusch J, Morgenstern P, Freyer K, Treutler HC, Stark HJ, Bruggemann L, Paschke A, Daus B, Weiss H (2004) Characterization of sediments in an abandoned mining area; a case study of Mansfeld region, Germany. Environ Geol 45:818–833. doi:10.1007/s00254-003-0942-7
Yang HD, Rose N (2005) Trace element pollution records in some UK lake sediments, their history, influence factors and regional differences. Environ Int 31:63–75. doi:10.1016/j.envint.2004.06.010
Yang HD, Rose NL, Battarbee RW, Monteith D (2002) Trace metal distribution in the sediments of the whole lake basin for Lochnagar, Scotland: a palaeolimnological assessment. Hydrobiologia 479:51–61. doi:10.1023/A:1021054112496
Acknowledgements
The authors extend their thanks to Peter Appleby for the unpublished 137Cs data from Ullswater.
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Grayson, R.P., Plater, A.J. A lake sediment record of Pb mining from Ullswater, English Lake District, UK. J Paleolimnol 42, 183–197 (2009). https://doi.org/10.1007/s10933-008-9270-y
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DOI: https://doi.org/10.1007/s10933-008-9270-y