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Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes

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Abstract

The defiance of this study was to explore the potential of alginate/MIL-101 beads containing Fe3O4 nanoparticles as a catalyst for the reduction of dyes. The Fe3O4@MIL-101 magnetic composite was obtained by the mechanical method and then encapsulated using calcium alginate (CA) as a crosslinked matrix. The Fe3O4(X)@MIL-101/CA composites beads at different content (X) of Fe3O4 nanoparticles were evaluated for the catalytic reduction of methylene blue (MB) and orange G (OG). The aerogel beads have completed the MB dye reduction after 7 min with a rate constant of 0.962 min–1. This strong activity is assigned to the synergistic effect between Cr containing MIL-101 the Fe3O4 particles and the hydrides formed on the catalyst surface. The obtained optimal conditions of MB dye reduction were used for the reduction of OG dye in simple and binary system.The best catalyst M(1)@MIL-101/CA showed a high affinity via MB dye in a binary system. Then was easily recovered by an external magnetic field and reused for 4 cycles. On the other hand, the time of the catalytic activity clearly increased in its 4th reuse in the reduction of MB dye but did not affect the efficiency of catalytic reduction.

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Acknowledgements

We thank DGRSDT and the Ministry of Education and Scientific Research of Algeria for funding this work.

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux LCM, Université Oran1, Ahmed Ben Bella, El Mnaouer, BP 1524, 31000, Oran, Algeria

    Mohammed Hachemaoui, Adel Mokhtar, Soumia Abdelkrim, Rachida Hamacha, Abdelkader Bengueddach & Bouhadjar Boukoussa

  2. Département de Génie des Procédés, Institut des Sciences et Technologies, Centre Universitaire Ahmed Zabana Relizane, Relizane, Algeria

    Adel Mokhtar

  3. Laboratoire des Sciences, Technologie et Génie des Procédés, Université des Sciences et de la Technologie d’Oran Mohamed Boudiaf, El M’naouer, BP 1505, Oran, Algeria

    Rachida Ouargli-Saker

  4. Laboratoire de Chimie Physique Macromoléculaire, Département de Chimie, Université Oran1 Ahmed Ben Bella, BP 1524 EL-Mnaouer, 31100, Oran, Algeria

    Farouk Zaoui

  5. Laboratoire de Chimie Fine LCF, Université Oran1 Ahmed Ben Bella, BP‑1524, El‑Mnaouer, 31000, Oran, Algeria

    Hadjira Habib Zahmani & Salih Hacini

  6. Département de Génie des Matériaux, Faculté de Chimie, Université des Sciences et de la Technologie Mohamed Boudiaf, El-Mnaouer, BP 1505, Oran, Algeria

    Bouhadjar Boukoussa

Authors
  1. Mohammed Hachemaoui
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  2. Adel Mokhtar
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  3. Soumia Abdelkrim
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  4. Rachida Ouargli-Saker
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  10. Bouhadjar Boukoussa
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Correspondence to Mohammed Hachemaoui, Adel Mokhtar or Bouhadjar Boukoussa.

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Hachemaoui, M., Mokhtar, A., Abdelkrim, S. et al. Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes. J Polym Environ 29, 3813–3826 (2021). https://doi.org/10.1007/s10924-021-02177-4

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