Abstract
Blends of water—soluble polymers based on Poly vinyl alcohol (PVA) and Polyethylene glycol (PEG) have been prepared by the solution casting technique. The effect of various doses of γ-radiation on the structural properties of PVA/PEG polymer blends with all its compositions has been investigated. From the visual observation of all the blend compositions, it was found that, the best compatibility of the blend is up to 40% PVA/60%PEG. The structure–Property behavior of all the prepared blends before and after γ-irradiation was investigated by IR Spectroscopy, thermogravimetric analysis (TGA), mechanical properties and Scanning electron microscope (SEM). The gel content and the swelling behavior of the PVA/PEG blends were investigated. It was found that the gel content increases with increasing irradiation dose and PVA concentration in the blend. Swelling percent increased as the composition of PEG increased in the blend. The results obtained by FTIR analysis and SEM confirm the existence of possible interaction between PVA and PEG homopolymers. TGA of PVA/PEG blend, before and after γ-irradiation, showed that the unirradiated and irradiated PVA/PEG blends are more stable against thermal decomposition than pure PVA. Improvement in tensile mechanical properties of PVA/PEG blends was occurred.
Similar content being viewed by others
References
El-Salmawi K, Abu Zeid MM, El- Naggar AM, Mamdouh M (1999) Appl Polym Sci 72:509
Huang SJ (1985) Biodegradable Polymers, in Encyclopedia of Polymer Science and Engineering, vol 2. Wiley, New York, p 220
Lenz RW (1994) Adv Polym Sci 112:1
Verhoogi H, Ramsay B, Favis BD (1994) Polymer 35:5155
Ikejima T, Cao A, Yoshie N, Inoue Y (1998) Polym Degrad Stab 62:463
Buchanan CM, Gedon SC, White AW, Wood MD (1992) Macromolecules 25:7373
Wang XL, Yang KK, Wang YZ (2003) J Macromol Sci Polym Rev 43:385
Shimamura E, Kashuya K, Kobayashic ST, Shima Y, Doi Y (1994) Macromolecules 27:878
Herold DA, Keil K, Bruns DE (1989) Biochem Pharmacol 38:73
Dong Y, Niholay V, Jean M (1999) J Macromol 32:5186
Teresa M, Adilson RG, Pessona A (2001) Polym Int 50:1068
El-Salmawi KM, Abu Zaid MM, Ibrahim SM, El-Naggar AM, Zahran AH (2001) J Appl Polym Sci 82:136
Masuhiro T, Giuliano F, John SC (1994) J Polym Sci A Polym Chem 32:243
Coffin DR, Fishman MI, Ly TV (1996) J Appl Polym Sci 61:71
Paladhi R, Singh RP (1994) J Appl Polym Sci 51:1559
Lai JY, Chen YC, Hus KY (1991) J Polym Sci 43:1795
Hassan CM, Peppas NA (2000) Adv Polym Sci 153:37
Coates J (2000) In: Meyers RA (ed) Encyclopedia of analytical chemistry, vol 37. Wiley, Chichester, p 10815
Peppas NA (1977) Polymer 18:403
Pritchard JG (1970) Poly(vinyl alcohol), basic properties and uses. Gorden and Breach, New York
Samskog PO, Lund A, Nilssion G (1989) Chem Phys Lett 79:447
Hass HC, Husah H, Taylor LD (1963) J Polym Sci A1:1215–1226
Sriram V, Subramari S, Radhakrishan G (2001) Polym Int 50:1124
Senna MM, Aly HA, EL-Naggar AM (2001) Polym Degrad Stabil 71:53
EL-Naggar AM, Lopez LC, Wilkes GL (1990) J Appl Polym Sci 39:427
EL-Naggar AM, Kim HC, Lopez LC, Wilkes GL (1989) J Appl Polym Sci 37:1655
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Abdel Tawab, K., Magida, M.M. & Ibrahim, S.M. Effect of Ionizing Radiation on the Morphological, Thermal and Mechanical Properties of Polyvinyl Alcohol/Polyethylene Glycol Blends. J Polym Environ 19, 440–446 (2011). https://doi.org/10.1007/s10924-011-0294-4
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10924-011-0294-4