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Composite Nanoarchitectonics of Poly(lactic acid)/Metal Organic Framework with Property Investigations Toward Packaging Applications

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Abstract

In this study, poly(lactic acid) (PLA), metal organic framework (MOF-5) and metal organic framework/graphene oxide (MOF-5/GO) were associated to prepare nanocomposites through melt extrusion method using a vertical co-rotating twin-screw micro compounder. GO, MOF-5 and MOF-5/GO composites were synthesized, respectively, using the modified Hummer’s method, facile method at room temperature and in situ incorporation of GO into MOF-5 precursors. PLA and MOF nanocomposites were obtained with the incorporation of 3 and 5% w/w of MOF-5 and MOF-5/GO nanofillers into the PLA matrix. The morphological, rheological, thermal, impact tests and barrier properties of the composites were evaluated by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), impact resistance tests and water vapor permeability test (WVP). According to the XRD results, MOF-5 and MOF-5/GO composites were successfully incorporated into the PLA matrix without altering the crystal structure of the MOF-5 and MOF-5/GO composites. The SEM images and FT-IR spectra indicate that MOF-5 and MOF-5/GO fillers are compatibles with PLA matrix. In the rheological study, the non-terminal behavior observed for PLA nanocomposites indicates pseudo-solid behavior, characteristic of a good dispersion state of the used nanofillers. The decrease in cold crystallization enthalpy indicates a high potential of these materials in various applications including gas separation, energy and packaging. Water vapor permeations (WVP) were strongly reduced by the incorporation of MOF-5/GO, and the better results are obtained with PLA/MOF-5/GO containing 5 mass% of MOF-5/GO-5. The results indicate that the structure–properties relationship is established and packaging application can be considered for these materials.

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Authors and Affiliations

  1. Laboratoire des Matériaux Organiques, Faculté de Technologie, Université de Bejaia, 06000, Bejaia, Algeria

    Badiaa Bouider, Boubkeur Seddik Bouakaz, Slimane Haffad & Abderrahmane Habi

  2. Laboratoire de Recherche sur les Macromolécules, Faculté des Sciences, Université Aboubakr Belkaïd, Tlemcen, Algeria

    Abdelkader Berrayah

  3. Centre de recherche Christiaan Huygens, IRDL CNRS 6027, Rue de St Maudé, BP 92116, 56321, Lorient, France

    Anthony Magueresse

  4. COMPOSITIC, Université de Bretagne-Sud, 2 Allée Copernic, 56270, Ploemeur, France

    Yves Grohens

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  1. Badiaa Bouider
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Contributions

BB, BSB and AH wrote the manuscript. SH, YG and AH Reviewed the manuscript. AB analyzed the samples by Rheology and DSC. AM analyzed the samples by SEM microscopy.

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Correspondence to Abderrahmane Habi.

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Bouider, B., Bouakaz, B.S., Haffad, S. et al. Composite Nanoarchitectonics of Poly(lactic acid)/Metal Organic Framework with Property Investigations Toward Packaging Applications. J Inorg Organomet Polym 33, 3689–3702 (2023). https://doi.org/10.1007/s10904-023-02780-z

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