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Nanoarchitectonics of Chitosan/Glutaraldehyde/Zinc Oxide as a Novel Composite for the Efficient Removal of Eriochrome Black T Dye from Aqueous Media

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Abstract

In this paper, crosslinking polymerization of chitosan with glutaraldehyde in the presence of zinc oxide nanoparticles was utilized for the synthesis of chitosan/glutaraldehyde/zinc oxide as a novel composite. The fabricated composite was characterized using some tools such as SEM, XRD, TGA, and BET. The successful formation of the chitosan/glutaraldehyde/zinc oxide composite was evidenced through the appearance of one broad XRD peaks at 2θ = 23.50°. Besides, the obvious destruction of the crystalline structure of zinc oxide has confirmed the successful formation of the composite. The FE-SEM images displayed that the surface of chitosan/glutaraldehyde/zinc oxide composite was wrinkled and rough, while the chitosan was dense and smooth, indicating important change in the morphology of the chitosan/glutaraldehyde/zinc oxide composite owing to the crosslinking of glutaraldehyde with chitosan and incorporation of ZnO. The BET surface area, average pore radius, and total pore volume of the chitosan/glutaraldehyde/zinc oxide composite are 32.50 m2/g, 39.36 Å, and 0.06 cc/g, respectively. The synthesized composite was operated for the efficient removal of eriochrome black T dye from aqueous media where its adsorption capacity is 1201.42 mg/g. The adsorption process of eriochrome black T dye obeys the Langmuir isotherm and pseudo-second-order model. Also, the adsorption process of eriochrome black T dye is endothermic, chemical, and spontaneous. The analytical influences that achieved the highest % removal of eriochrome black T dye are observed at pH 2, contact time = 140 min, and temperature = 318 K.

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Funding

Authors are grateful to King Saud University, Riyadh, Saudi Arabia for funding the work through Researchers Supporting Project (No. RSP-2021/359).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Applied Sciences, Umm Al-Qura University, Mecca, 21955, Saudi Arabia

    Reem Kamal Shah

  2. Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, Riyadh, 11451, Saudi Arabia

    Ahmed Mohamed Naglah

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  1. Reem Kamal Shah
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  2. Ahmed Mohamed Naglah
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Correspondence to Ahmed Mohamed Naglah.

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Shah, R.K., Naglah, A.M. Nanoarchitectonics of Chitosan/Glutaraldehyde/Zinc Oxide as a Novel Composite for the Efficient Removal of Eriochrome Black T Dye from Aqueous Media. J Inorg Organomet Polym 32, 2030–2039 (2022). https://doi.org/10.1007/s10904-022-02258-4

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