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Electrochemical Measurement of Bismuth Clusters in Dendrimer Through Transformation from Atomicity Controlled Complexes

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Abstract

Dendrimers can provide unique reaction space for sub-nano sized materials. Recently, we have demonstrated a luminous bismuth dendrimer and the on/off switching by stepwisely assembled bismuth units in a phenylazomethine dendrimers. In addition, formation of bismuth clusters was also demonstrated by the reduction of the bismuth salts assembled in the dendrimer. In this study, we have revealed the atomicity dependency about the reduction and oxidation potentials of the assembled bismuth complexes and clusters, respectively. The measurements were conducted by the electrochemical process of the bismuth assembled dendritic poly-phenylazomethines.

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Acknowledgements

This study was supported by JSPS KAKENHI Grand Numbers 17K05804 and 15H05757, the ERATO program of the Japan Science and Technology (JST) Agency (JPMJER1503), and the cooperative research program of the Network Joint Research Center for Materials and Devices of Japan.

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Authors and Affiliations

  1. Laboratory for Chemistry and Life Science, Tokyo Institute of Technology, Yokohama, 226-8503, Japan

    Tetsuya Kambe, Shotaro Imaoka, Risaki Hasegawa, Takamasa Tsukamoto, Takane Imaoka & Kimihisa Yamamoto

  2. JST-ERATO, Tokyo Institute of Technology, Yokohama, 226-8503, Japan

    Tetsuya Kambe, Takamasa Tsukamoto, Takane Imaoka & Kimihisa Yamamoto

  3. Department of Chemistry, Keio University, 3-14-1 Hiyoshi, Yokohama, 223-8522, Japan

    Keisuke Natsui & Yasuaki Einaga

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  1. Tetsuya Kambe
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  4. Takamasa Tsukamoto
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Correspondence to Kimihisa Yamamoto.

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Kambe, T., Imaoka, S., Hasegawa, R. et al. Electrochemical Measurement of Bismuth Clusters in Dendrimer Through Transformation from Atomicity Controlled Complexes. J Inorg Organomet Polym 30, 169–173 (2020). https://doi.org/10.1007/s10904-019-01390-y

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