Skip to main content
SpringerLink
Log in

Uptake of Metal Ions (Co(II) and Ni(II)) by Silica-Salicylaldehyde Derived from Rice Husks

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

The source of silica in silica-salicylaldehyde was rice husk ash (RHA). RHA was converted to sodium silicate by reacting with sodium hydroxide solution. The technique of sol–gel was used to synthesize RHAPrNH2 through the reaction of 3-(aminopropyl)triethoxysilane with sodium silicate in a strong acidic medium. Novel nanomaterial (RHA-SALED) was prepared from the reaction of salicylaldehyde with RHAPrNH2 by condensation reaction in toluene solvent. The technique of FTIR showed that the peak at 1622 cm−1 belongs to C=N. XRD technique showed the amorphous nature for RHA-SALED with maximum intensity at 22° (2θ). CHNS technique proved that RHA-SALED contain 9.28% of N higher than that of RHAPrNH2. SEM confirmed that the functionalized particles are granular and shaped irregularly with a common diameter of ca. 40.36 nm. BET measurements additionally confirmed that the surface place is 1.0356 m2 g−1 of RHA-SALED with pore size distribution 10.879 nm. The material RHA-SALED was used for absorption from an aqueous solution of heavy contaminating metal ions Ni(II) and Co(II).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. S. Azat, A.V. Korobeinyk, K. Moustakas, V.J. Inglezakis, J. Clean. Prod. 217, 352 (2019)

    Article  CAS  Google Scholar 

  2. F. Requena, R. Jiménez-Quero, A. Vargas, M. Moriana, R. Chiralt, A. Vilaplana, A.C.S. Sustain, Chem. Eng. 7, 6275 (2019)

    CAS  Google Scholar 

  3. M. Ullah, Z. Man, Z. Khan, A.S. Muhammad, N. Mahmood, H. Ghanem, O.B. Raheel, J. Clean. Prod. 220, 620 (2019)

    Article  CAS  Google Scholar 

  4. M.F. De Souza, W.L.E. Magalhães, M.C. Persegil, Mater. Res. 5, 467 (2002)

    Article  Google Scholar 

  5. D. Sivakumar, Glob. J. Environ. Sci. Manag. 1, 27 (2015)

    CAS  Google Scholar 

  6. P. Sturm, G.J.G. Gluth, H.J.H. Brouwers, H.-C. Kühne, Constr. Build. Mater. 124, 961 (2016)

    Article  CAS  Google Scholar 

  7. H.X. Nguyen, N.T.T. Dao, H.T.T. Nguyen, A.Q.T. Le, in IOP Conference Series: Earth and Environmental Science (2019), p. 12007

  8. M. Beidaghy, D.H. Zeng, T. Hartmann, I. Enke, D. Schliermann, T. Lenz, V. Bidabadi, Appl. Sci. 9, 1083 (2019)

    Article  Google Scholar 

  9. J.T. Librea, F.D. Dacanay, Z.Z. Martin, L.L. Diaz, in IOP Conference Series: Earth and Environmental Science (2019), p. 12007

  10. S. Sembiring, R. Situmeang, Z. Sembiring, Cerâmica 65, 194 (2019)

    Article  CAS  Google Scholar 

  11. C. Real, M.D. Alcala, J.M. Criado, J. Am. Ceram. Soc. 79, 2012 (1996)

    Article  CAS  Google Scholar 

  12. R.A. Bakar, R. Yahya, S.N. Gan, Procedia Chem. 19, 189 (2016)

    Article  Google Scholar 

  13. J.A. Santana Costa, C.M. Paranhos, J. Clean. Prod. 192, 688 (2018)

    Article  CAS  Google Scholar 

  14. X. Xu, Y. Zheng, B. Gao, X. Cao, Chem. Eng. J. 368, 564 (2019)

    Article  CAS  Google Scholar 

  15. J. Acharya, U. Kumar, P.M. Rafi, Int. J. Curr. Eng. Technol. 3, 525 (2018)

    Google Scholar 

  16. M. Najafi, Y. Yousefi, A.A. Rafati, Sep. Purif. Technol. 85, 193 (2012)

    Article  CAS  Google Scholar 

  17. Y. Liu, H. Feng, S. Zhang, N. Du, X. Liu, Front. Environ. Sci. Eng. 8, 329 (2014)

    Article  CAS  Google Scholar 

  18. S.K. Gunatilake, Methods 1, 12 (2015)

    Google Scholar 

  19. S. Naushad, M. Ahamad, T. Al-Maswari, B.M. Alqadami, A.A. Alshehri, Chem. Eng. J. 330, 1351 (2017)

    Article  CAS  Google Scholar 

  20. Z. An, F.Q. Wu, R.Y. Li, M. Hu, T.P. Gao, J.F. Yuan, React. Funct. Polym. 118, 42 (2017)

    Article  CAS  Google Scholar 

  21. G. Li, Z. Zhao, J. Liu, G. Jiang, J. Hazard. Mater. 192, 277 (2011)

    CAS  PubMed  Google Scholar 

  22. S. Ahmad, N. Sereshti, H. Mousazadeh, M. Nodeh, H.R. Kamboh, M.A. Mohamad, Mater. Chem. Phys. 226, 73 (2019)

    Article  CAS  Google Scholar 

  23. J. El-Ashgar, N.M. El-Nahhal, I.M. Chehimi, M.M. Babonneau, F. Livage, Int. J. Environ. Anal. Chem. 89, 1057 (2009)

    Article  CAS  Google Scholar 

  24. I.M. El-Nahhal, F.R. Zaggout, N.M. El-Ashgar, Anal. Lett. 33, 2031 (2000)

    Article  CAS  Google Scholar 

  25. I.M. El-Nahhal, N.M. El-Ashgar, J. Organomet. Chem. 692, 2861 (2007)

    Article  CAS  Google Scholar 

  26. T.J. Al-Hasani, H.H. Mihsen, K.M. Hello, F. Adam, Arab. J. Chem. 10, S1492 (2017)

    Article  CAS  Google Scholar 

  27. M.M. El-Ashgar, N.M. El-Nahhal, I.M. Ahmed, M.A. Shaweesh, A.A.A. Chehimi, J. Iran. Chem. Soc. 15, 2325 (2018)

    Article  CAS  Google Scholar 

  28. K.M. Hello, H.H. Mihsen, M.J. Mosa, Iran. J. Catal. 4, 195 (2014)

    CAS  Google Scholar 

  29. K.M. Hello, H.H. Mihsen, M.J. Mosa, M.S. Magtoof, J. Taiwan Inst. Chem. Eng. 46, 74 (2015)

    Article  CAS  Google Scholar 

  30. H.H. Mihsen, H.S. Sobh, Asian J. Chem. 30, 937 (2018)

    Article  CAS  Google Scholar 

  31. F. Adam, K.M. Hello, H. Osman, Chin. J. Chem. 28, 2383 (2010)

    Article  CAS  Google Scholar 

  32. T. Chanadee, S. Chaiyarat, J. Mater. Environ. Sci. 7, 2369 (2016)

    CAS  Google Scholar 

  33. J.M. Carmona, V.B. Oliveira, R.M. Silva, W.T.L. Mattoso, L.H.C. Marconcini, Ind. Crops Prod. 43, 291 (2013)

    Article  CAS  Google Scholar 

  34. R. Fernandes, I.J. Calheiro, D. Kieling, A.G. Moraes, C.A. Rocha, T.L. Brehm, F.A. Modolo, Fuel 165, 351 (2016)

    Article  CAS  Google Scholar 

  35. S.R. Kamath, A. Proctor, Cereal Chem. 75, 484 (1998)

    Article  CAS  Google Scholar 

  36. M.J. Barnabas, S. Parambadath, S. Nagappan, C.S. Ha, Heliyon 5, e01521 (2019)

    Article  Google Scholar 

  37. F. Adam, H. Osman, K.M. Hello, J. Colloid Interface Sci. 331, 143 (2009)

    Article  CAS  Google Scholar 

  38. F. Adam, K.M. Hello, S.J. Chai, Chem. Eng. Res. Des. 90, 633 (2012)

    Article  CAS  Google Scholar 

  39. A.E. Ahmed, F. Adam, Microporous Mesoporous Mater. 103, 284 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We would like to thank Department of Chemistry, College of Science, Kerbala University, for financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry, College of Science, University of Kerbala, Karbala, Iraq

    Aliyaa Dhahir Mohsin & Hayder Hamied Mihsen

Authors
  1. Aliyaa Dhahir Mohsin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hayder Hamied Mihsen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hayder Hamied Mihsen.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mohsin, A.D., Mihsen, H.H. Uptake of Metal Ions (Co(II) and Ni(II)) by Silica-Salicylaldehyde Derived from Rice Husks. J Inorg Organomet Polym 30, 2172–2181 (2020). https://doi.org/10.1007/s10904-019-01379-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-019-01379-7

Keywords

Search

Navigation