Abstract
This paper describes the synthesis, as well the structural of a novel complex of Cu(II) with pyridine-2,6-dicarboxylic acid and melamine. The complex was characterized by differential scanning calorimetry (DSC) analysis, Fourier transform infrared and Raman spectroscopy with a detailed analysis of Hirshfeld surfaces and fingerprint plots. The single X-ray diffraction studies have revealed that the compound crystallizes in triclinic P\(\bar{1}\) space group with cell parameters a = 6.9839 (14), b = 11.037 (2), c = 12.990 (2), α = 72.268 (9), β = 75.237 (9), δ = 87.855 (10) and Z = 1. The crystal structure was stabilized by an extensive network of N–H···Br, N–H···O, O–H···N, O–H···Br, C–H···Br and non-classical N–H···N hydrogen bonds. Furthermore, the room temperature IR and Raman spectra of the title compound were recorded and analyzed on the basis of literature data. The DSC study shows three anomalies at 385, 495 and 507 K.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig4_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig5_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig6_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig7_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig8_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig9_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig10_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig11_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10904-016-0371-1/MediaObjects/10904_2016_371_Fig12_HTML.gif)
Similar content being viewed by others
References
D.P. Murtha, R.A. Walton, Metal carboxylates. VI. mixed ligand complexes of copper (II) containing pyridine-2,6-dicarboxylic acid in its monoanionic and dianionic forms. Inorg. Chim. Acta 8, 279–284 (1974)
X.X. Zhong, X.L. Wang, Y.M. Jiang, Crystal structure and synthesis of cobalt pyridine 2,6-dicarboxylate. J. Guangxi Normal Univ. 22, 60 (2004)
T. Douki, B. Setlow, P. Setlow, J. Photochem. Photobiol. B Biol. 4, 591–597 (2005)
K. Murakami, Y. Tanemura, M. Yoshino, J. Nutr. Biochem. 14, 99–103 (2003)
Y. Kazuhiro, Y. Noriko, F. Tadayasu, Eur. Patent EP0603165, 591–597 (1994)
G.A. Burdock, Encyclopedia of Food and Color Additives, CRC Press, New York (1996)
F.A. La Porta, P.H. Ramos, E.C. de Resende, M.C. Guerreiro, J.O.S. Giacoppo, T.C. Ramalho, J.R. Sambrano, J. Andrés, E. Longo, J. Inorg. Chem. Acta 416, 200–206 (2014)
G.A. van Albada, M. Ghazzali, K. Al-Farhan, E. Bouwman, J. Reedijk, J. Polyhedron. 52, 1059–1064 (2013)
M. Brandi-Blanco, D. Choquesillo-Lazarte, A. Domínguez-Martín, A. Matilla-Hernández, J. González-Pérez, A. Castiñeiras, J.M. Niclós-Gutiérrez, J. Inorg. Biochem. 127, 211–219 (2013)
Y. Tyan, M. Yang, S. Jong, C. Wang, J. Shiea, Anal. Bioanal. Chem. 395, 729–735 (2009)
E.L. Kennaway, Biochem. J. 15, 510–512 (1921)
C. Kluwer, International Tables for X-ray crystallography, Dordrecht (1992)
G.M. Sheldrick, Acta Crystallogr. Sect. A 64, 112–122 (2007)
O.V. Dolomanov, L.J. Bourhis, R.J. Gildea, J.A.K. Howard, H. Puschmann, J. Appl. Cryst. 42, 339–341 (2009)
L.J. Farrugia, ORTEP3 for windows. J. Appl. Crystallogr. 30, 565 (1997)
K. Brandenburg, (1998) Diamond Version 2.0 Impact Gbr. Bonn, Germany
M. Koman, M. Melník, M. Moncol, Inorg. Chem. Commun. 3, 262–266 (2000)
J. Shou-Wen, C. Wan-Zhi, Polyhedron 26, 3074–3084 (2007)
C. Julienne, M. Jerome, R. Didier, Acta Crystallogr. Sect. C 60, m101–m103 (2004)
P.K. Bhaumik, S. Jana, S. Chattopadhyay, Inorg. Chim. Acta 390, 167–177 (2012)
J. Janczak, G.J. Perpetuo, Acta Cryst. C 57, 123–125 (2001)
J. Janczak, G.J. Perpetuo, Acta Crystallogr. C 57, 1120–1122 (2001)
J. Janczak, G.J. Perpetuo, Acta Crystallogr. C 57, 1431–1433 (2001)
J. Bernstein, R.E. Davis, L. Shimoni, N.-L. Chang, J. Angew, Chem. Int. Ed. Engl. 34, 1555–1573 (1995)
N. Karâa, B. Hamdi, A. Ben Salah, R. Zouari, J. Mol. Struct. 1013, 48–58 (2012)
C. Ben Nasr, I. Said, M. Rzaigui, Mater. Res. Bull. 36, 789–798 (2001)
N. Chaari, Z. Abdelkefi, S. Chaabouni, N. Chniba-Boudjada, P. Bordet, Phase Transit. 81, 101–111 (2008)
M.A. Spackman, J.J. McKinnon, CrystEngComm 4, 378–392 (2002)
F.P.A. Fabbiani, C.K. Leech, K. Shankland, A. Johnston, P. Fernandes, A.J. Florence, N. Shankland, Acta Cryst. C 63, o659–o663 (2007)
L. Checinska, S. Grabowsky, M. Malecka, A.J. Rybarczyk-Pirek, A. Józwiak, C. Paulmann, P. Luger, Acta Cryst. B 67, 569–581 (2011)
H. Pérez, R.S. Corrêa, A.M. Plutín, B. O’Reilly, M.B. Andrade, Acta Cryst. C. 68, o19–o22 (2012)
S.K. Seth, D. Sarkar, A.D. Jana, T. Kar, Cryst. Growth Des. 11, 4837–4849 (2011)
S.K. Seth, I. Saha, C. Estarellas, A. Frontera, T. Kar, S. Mukhopadhyay, Cryst. Growth Des. 11, 3250–3265 (2011)
S.K. Seth, D. Sarkar, T. Kar, CrystEngComm 13, 4528–4535 (2011)
S.K. Seth, D. Sarkar, A. Roy, T. Kar, CrystEngComm 13, 6728–6741 (2011)
S.K. Seth, N.C. Saha, S. Ghosh, T. Kar, Chem. Phys. Lett. 506, 309–314 (2011)
S.K. Seth, P.C. Mandal, T. Kar, S. Mukhopadhyay, J. Mol. Struct. 994, 109–116 (2011)
P. Manna, S.K. Seth, A. Das, J. Hemming, R. Prendergast, M. Helliwell, S.R. Choudhury, A. Frontera, S. Mukhopadhyay, Inorg. Chem. 51, 3557–3571 (2012)
S.K. Seth, G.C. Maity, T. Kar, J. Mol. Struct. 1000, 120–126 (2011)
J.J. McKinnon, M.A. Spackman, A.S. Mitchell, Acta Crystallogr. Sect. B 60, 627–668 (2004)
A.L. Rohl, M. Moret, W. Kaminsky, K. Claborn, J.J. Mckinnon, B. Kahr, Cryst. Growth Des. 8, 4517–4525 (2008)
A. Parkin, G. Barr, W. Dong, C.J. Gilmore, D. Jayatilaka, J.J. Mckinnon, M.A. Spackman, C.C. Wilson, CrystEngComm 9, 648–652 (2007)
F.P.A. Fabbiani, L.T. Byrne, J.J. Mckinnon, M.A. Spackman, CrystEngComm 9, 728–731 (2007)
S.K. Wolff, D.J. Grimwood, J.J. McKinnon, D. Jayatilaka, M.A. Spackman, in Crystal Explorer 2.1, University of Western Australia, Perth, 2007
Acknowledgments
The authors thank the members of units of common services, at the University of Sfax for their assistance in the measurements for X-ray diffraction. The authors are also thankful to Prof Hamadi KHEMAKHEM, for his co-operating in the Raman spectroscopy measurement.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mesbeh, R., Hamdi, B. & Zouari, R. (H2pdcCuBr2)2∙2(MH+)∙2Br− (M = Melamine, H2pdc = Pyridine-2,6-Dicarboxylic Acid): Crystal Structure, Hirshfeld Surface Analysis, Vibrational and Thermal Studies. J Inorg Organomet Polym 26, 744–755 (2016). https://doi.org/10.1007/s10904-016-0371-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-016-0371-1