Abstract
Large-area boron doped multi-layer carbon is synthesized by the plasma enhanced chemical vapour deposition (PECVD) using boron oxide powder and ethanol vapor. We have reviewed the carbon molecular crystals preparation by the PECVD method. The three main synthesis methods of carbon nanocrystals (CNCs) are the arc discharge, the laser ablation and the chemical vapour deposition with a special regard to the later one. By two different methods, ZnO layers were coated on the tubes. RF sputtering was one of the ways to directly deposit ZnO thin layer on the MWCNCs. On the other hand, we used thermally physical vapour deposition for making thin Zn film to oxidize it later. Scanning electron microscopy and also Raman spectroscopy measurements of the prepared samples confirmed the presence of ZnO nanolayers on the CNC bodies.
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12 July 2023
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1007/s10904-023-02793-8
References
Y. Xia, P. Yang, Y. Sun, Y. Wu, B. Mayers, B. Gates, Y. Yin, F. Kim, H. Yan, One-dimensional nanostructures: synthesis, characterization, and applications. Adv. Matter. (Weinheim, Ger.) 15, 353–389 (2003)
S. Iijima, Helical microtubules of graphitic carbon. Nature (London) 354, 56–58 (1991)
M.S. Dresselhaus, G. Dresselhaus, P. Avouris, Carbon Nanotubes; Synthesis, Structure, Properties, and Applications (Springer, New York, 2001)
W.B. Choi, D.S. Chung, J.H. Kang, H.Y. Kim, Y.W. Jin, I.T. Han, Y.H. Lee, J.E. Jung, N.S. Lee, G.S. Park, J.M. Kim, Fully sealed, high-brightness carbon-nanotube field-emission display. Appl. Phys. Lett. 75, 3129–3131 (1999)
I.C. Chen, L.H. Chen, X.R. Ye, C. Daraio, S. Jin, C.A. Orme, A. Quist, R. Lal, Extremely sharp carbon nanocone probes for atomic force microscopy imaging. Appl. Phys. Lett. 88, 153102–153104 (2006)
S.S. Wong, A.T. Woolley, E. Joselevich, C.M. Lieber, Functionalization of carbon nanotube AFM probes using tip-activated gases. Chem. Phys. Lett. 306, 219–225 (1999)
R. Martel, T. Schmidt, H.R. Shea, T. Hertel, P. Avouris, Single- and multi-wall carbon nanotube field-effect transistors. Appl. Phys. Lett. 73, 2447–2449 (1998)
Q.H. Wang, T.D. Corrigan, J.Y. Dai, R.P.H. Chang, A.R. Krauss, Field emission from nanotube bundle emitters at low fields. Appl. Phys. Lett. 70, 3308–3310 (1997)
S. Fan, M.G. Chapline, N.R. Franklin, T.W. Tombler, A.M. Cassell, H. Dai, Self-oriented regular arrays of carbon nanotubes and their field emission properties. Science 283, 512–514 (1990)
C.S. Huang, C.Y. Yeh, Y.H. Chang, Y.M. Hsieh, C.Y. Ku, Q.T. Lai, Field emission properties of CNT–ZnO composite materials. Diam. Relat. Mater. 18, 452–456 (2009)
W.A. de Heer, A. Châtelain, D. Ugarte, Science “a carbon nanotube field-emission electron source”. Science 270, 1179–1180 (1995)
A.G. Rinzler, J.H. Hafner, P. Nikolaev, P. Nordlander, D.T. Colbert, R.E. Smalley, L. Lou, S.G. Kim, D. Tománek, Unraveling nanotubes: field emission from an atomic wire. Science 269, 1550–1553 (1995)
N. de Jonge, Y. Lamy, K. Schoots, T.H. Oosterkamp, High brightness electron beam from a multi-walled carbon nanotube. Nature (London) 420, 393–395 (2002)
J. Jiao, L.F. Dong, D.W. Tuggle, C.L. Mosher, S. Foxley, J. Tawdekar, Fabrication and characterization of carbon nanotube field emitters. Mater. Res. Soc. Symp. Proc. 706, 113–117 (2002)
W. Zhu, C. Bower, O. Zhou, G. Kochanski, S. Jin, Large current density from carbon nanotube field emitters. Appl. Phys. Lett. 75, 873–875 (1999)
J.M. Bonard, J.P. Salvetat, T. Stöckli, L. Forró, A. Châtelain, Field emission from carbon nanotubes: perspectives for applications and clues to the emission mechanism. Appl. Phys. A Mater. Sci. Process. 69, 245–254 (1999)
M. Sveningsson, R.E. Morjan, O.A. Nerushev, Y. Sato, J. Bäckström, E.E.B. Campbell, F. Rohmund, Raman spectroscopy and field emission properties of CVD-grown carbon nanotube films. Appl. Phys. A 73, 409–418 (2001)
J.M. Green, L. Dong, T. Gutu, J. Jiao, J.F. Conley, Y. Ono, ZnO-nanoparticle-coated carbon nanotubes demonstrating enhanced electron field-emission properties. J. Appl. Phys. 99, 094308–094311 (2006)
H. Kim, W. Sigmund, Zinc oxide nanowires on carbon nanotubes. Appl. Phys. Lett. 81, 2085–2087 (2002)
L. Jiang, L. Gao, Fabrication and characterization of ZnO-coated multi-walled carbon nanotubes with enhanced photocatalytic activity. Mater. Chem. Phys. 91, 313–316 (2005)
Z.L. Wang, Zinc oxide nanostructures: growth, properties and applications. J. Phys. Condens. Matter. 16, R829 (2004)
S.J. Pearton, D.P. Norton, K. Ip, Y.W. Heo, T. Steiner, Recent progress in processing and properties of ZnO. Superlattice Microstruct. 34, 3–32 (2003)
W.Z. Li, H. Zhang, C.Y. Wang, Y. Zhang, L.W. Xu, K. Zhu, S.S. Xie, Raman characterization of aligned carbon nanotubes produced by thermal decomposition of hydrocarbon vapor. Appl. Phys. Lett. 70, 2684–2686 (1997)
A. Hirsch, Functionalization of single-walled carbon nanotubes. Angew. Chem. Int. Ed. 41, 1853–1859 (2002)
Y. Zhu, H.I. Elim, Y.L. Foo, T. Yu, Y. Liu, W. Ji, J.Y. Lee, Z. Shen, A.T.S. Wee, J.T.L. Thong, C.H. Sow, Multiwalled carbon nanotubes beaded with ZnO nanoparticles for ultrafast nonlinear optical switching. Adv. Mater. 18, 587–592 (2006)
P.H. Tan, S.L. Zhang, K.T. Yue, F.M. Huang, Z.J. Shi, X.H. Zhou, Z.N. Gu, Comparative Raman study of carbon nanotubes prepared by D.C. arc discharge and catalytic methods. J. Raman Spectrosc. 28, 369–372 (1997)
C.F. Chen, C.L. Tsai, C.L. Lin, The characterization of boron-doped carbon nanotube arrays. Diam. Relat. Mater. 12, 1500–1504 (2003)
L. Velantini, I. Armentano, J.M. Kenny, L. Lozzi, S. Santucci, Effect of catalyst layer thickness and Ar dilution on the plasma deposition of multi-walled carbon nanotubes. Diam. Relat. Mater. 12, 821–826 (2003)
X.L. Li, C. Li, Y. Zhang, D.P. Chu, W.I. Milne, H.J. Fan, Atomic layer deposition of ZnO on multi-walled carbon nanotubes and its use for synthesis of CNT–ZnO heterostructures. Nanoscale Res. Lett. 5, 1836–1840 (2010)
T.C. Damen, S.P.S. Porto, B. Tell, Raman effect in zinc oxide. Phys. Rev. 142, 570–574 (1966)
H.T. Ng, B. Chen, J. Li, J. Han, M. Meyyappan, J. Wu, S.X. Li, E.E. Haller, Optical properties of single-crystalline ZnO nanowires on m-sapphire. Appl. Phys. Lett. 82, 2023–2025 (2003)
C. Geng, Y. Jiang, Y. Yao, X. Meng, J.A. Zapien, C.S. Lee, Y. Lifshitz, S.T. Lee, Well-aligned ZnO nanowire arrays fabricated on silicon substrates. Adv. Funct. Mater. 14, 589–594 (2004)
Y. Du, M.S. Zhang, J. Hong, Y. Shen, Q. Chen, Z. Yin, Structural and optical properties of nanophase zinc oxide. Appl. Phys. A Matter. Sci. Process. 76, 171–176 (2003)
D. Temple, C.A. Ball, W.D. Palmer, L.N. Yadon, D. Vellenga, J. Mancusi, G.E. McGuire, H.F. Gray, Fabrication of column-based silicon field emitter arrays for enhanced performance and yield. J. Vac. Sci. Technol. B 13, 150–157 (1995)
M. Sveningsson, R.E. Morjan, O.A. Nerushev, E.B. Campbell Eleanor, D. Malsch, J.A. Schaefer, Highly efficient electron field emission from decorated multiwalled carbon nanotube films”. Appl. Phys. Lett. 85, 4487–4489 (2004)
C.J. Lee, T.J. Lee, S.C. Lyu, Y. Zhang, H. Ruh, H.J. Lee, Field emission from well-aligned zinc oxide nanowires grown at low temperature. Appl. Phys. Lett. 81, 3648–3650 (2002)
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Salar Elahi, A., Ghoranneviss, M. RETRACTED ARTICLE: Increase of the Surface Mobility of Carbon Molecular Crystals (CMCs) Using the PECVD Technique. J Inorg Organomet Polym 26, 773–779 (2016). https://doi.org/10.1007/s10904-016-0368-9
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DOI: https://doi.org/10.1007/s10904-016-0368-9