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Layer-by-Layer Synthesis of Nanostructure NiBTC Porous Coordination Polymer for Iodine Removal from Wastewater

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Abstract

We present here a textile for the adsorptive removal iodine from wastewater using three-dimensional Ni3(BTC)2·12H2O (NiBTC) mesoporous coordination polymer and silk fibers. NiBTC upon fiber has been synthesized under ultrasound irradiation of identical reaction mixtures of Ni(II) salt and H3BTC. The effects of ultrasound irradiation and sequential dipping steps on the growth of NiBTC upon fiber have been studied. These systems depicted a decrease in the particles size with a decrease in the power of ultrasound irradiation. Results suggest that an increasing of sequential dipping steps led to a decrease of particle size. A comparison of adsorption and desorption rates of iodine between samples was also conducted. The silk fibers containing NiBTC exhibited high antibacterial activity against P. aeruginosa and S. aureus.

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Acknowledgments

Support of this investigation by Razi University of Kermanshah and Iran National Science Foundation: INSF are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Islamic Republic of Iran

    Azadeh Azadbakht

  2. Faculty of Chemistry, Razi University, 67194, Kermanshah, Islamic Republic of Iran

    Amir Reza Abbasi & Nourolah Noori

Authors
  1. Azadeh Azadbakht
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  2. Amir Reza Abbasi
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  3. Nourolah Noori
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Correspondence to Amir Reza Abbasi.

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Azadbakht, A., Abbasi, A.R. & Noori, N. Layer-by-Layer Synthesis of Nanostructure NiBTC Porous Coordination Polymer for Iodine Removal from Wastewater. J Inorg Organomet Polym 26, 479–487 (2016). https://doi.org/10.1007/s10904-016-0332-8

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  • DOI: https://doi.org/10.1007/s10904-016-0332-8

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