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Synthesis, Characterization and Antibacterial Properties of Nano-Porous Zn3(BTC)2·12H2O upon Silk Yarn Under Ultrasound Irradiation

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Abstract

A porous coordination polymer, Zn3(BTC)2·12H2O (Zn-BTC) upon silk yarn, has been synthesized under ultrasound irradiation of identical reaction mixtures of Zn(II) and H3BTC (BTC = 1,3,5-benzenetricarboxylate). Effects of temperature, sequential dipping steps and sonication on the growth of Zn-BTC upon silk yarn were investigated. These systems depicted a decrease in the particles size accompanying a decrease in the sequential dipping steps. Results showed a decrease in the particles size as decreasing frequency of ultrasound irradiation. The antimicrobial activity of Zn-BTC upon fiber was tested against the Gram positive strain Micrococcus sp. and Gram negative bacterial strain Escherichia coli. The samples were characterized with X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy spectra and scanning electron microscopy. XRPD analyses indicated that the prepared Zn-BTC nanostructures on silk fibers were crystalline.

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Acknowledgment

Support of this investigation by Iran National Science Foundation: INSF (No. 92031906) and Razi University of Kermanshah are gratefully acknowledged.

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Authors and Affiliations

  1. Faculty of Chemistry, Razi University, 67194, Kermanshah, Iran

    Amir Reza Abbasi & Nourolah Noori

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  1. Amir Reza Abbasi
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  2. Nourolah Noori
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Correspondence to Amir Reza Abbasi.

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Abbasi, A.R., Noori, N. Synthesis, Characterization and Antibacterial Properties of Nano-Porous Zn3(BTC)2·12H2O upon Silk Yarn Under Ultrasound Irradiation. J Inorg Organomet Polym 24, 1096–1102 (2014). https://doi.org/10.1007/s10904-014-0101-5

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