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Synthesis of Metal-Coordinated Poly(azomethine-urethane)s: Thermal Stability, Optical and Electrochemical Properties

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Abstract

In this study, the novel thermally stable metal-coordinated-poly(azomethine-urethane)s (PAMU-M)s were synthesized to investigate some physical properties such as thermal stability, optical and electrochemical properties. For this reason, we firstly synthesized the Schiff base via condensation reaction of p-phenylenediamine with 2,4-dihydroxy benzaldehyde. Secondly, metal-coordinated Schiff bases were synthesized by coordination reaction of the obtained Schiff base and different metal ions such as Cu(II), Ni(II), Pb(II) and Zn(II). Then, these metal-coordinated Schiff bases were converted to their PAMU derivatives by the step-polymerization reaction using 2,4-toluenediisocyanate. Also, thermal stability, electrochemical and optic properties of the obtained materials were investigated.

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Acknowledgments

The authors would like to thank Government Planning Organization for the financial support (Project No: GPO2010K120710).

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Authors and Affiliations

  1. Department of Chemistry, Kamil Özdağ Science Faculty, Karamanoğlu Mehmetbey University, 70100, Karaman, Turkey

    Musa Kamacı

  2. Polymer Synthesis and Analysis Laboratory, Department of Chemistry, Faculty of Sciences and Arts, Çanakkale Onsekiz Mart University, 17020, Çanakkale, Turkey

    Musa Kamacı & İsmet Kaya

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  1. Musa Kamacı
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  2. İsmet Kaya
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Correspondence to İsmet Kaya.

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Kamacı, M., Kaya, İ. Synthesis of Metal-Coordinated Poly(azomethine-urethane)s: Thermal Stability, Optical and Electrochemical Properties. J Inorg Organomet Polym 23, 1159–1171 (2013). https://doi.org/10.1007/s10904-013-9908-8

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  • DOI: https://doi.org/10.1007/s10904-013-9908-8

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