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Preparation and Dielectric Properties of AGS@CuPc/PVDF Composites

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Abstract

GNS/PVDF, AGS/PVDF and AGS@CuPc/PVDF composites were prepared using hot press molding technique. The micromorphologies showed that the dispersion degree of the GNS in the matrix decreases in the following order: AGS@CuPc/PVDF > AGS/PVDF > GNS/PVDF. It could be attributed to AGS treated with copper phthalocyanine (CuPc) exhibit strongest interface bonding with PVDF, and acidification GNS (AGS) have stronger interface bonding with PVDF than GNS. GNS/PVDF composites showed a slight increase in dielectric constant and dielectric loss with the growing content of fillers. AGS/PVDF composites presented a better performance in dielectric constant than that of GNS/PVDF but with a much higher dielectric loss. Especially AGS@CuPc/PVDF three-phase composite displayed better dielectric properties than GNS/PVDF and AGS/PVDF composites, with a dielectric constant 327 and a dielectric loss 0.63 at 10 kHz. It could be attributed to the cooperation of well dispersion of conductive fillers and the electric barrier effects of CuPc.

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References

  1. R.H. Baughman, A.A. Zakhidov, W.A. Heer, Science 297, 787 (2002)

    Article  CAS  Google Scholar 

  2. Z.-M. Dang, Y.-H. Lin, C.-W. Nan, Adv. Mater. 85, 1625 (2003)

    Article  Google Scholar 

  3. X.-Y. Huang, P.-K. Jiang, C.-U. Kim, Appl. Phys. 102, 124103 (2007)

    Article  Google Scholar 

  4. T. Zhou, J.-W. Zha, Y. Hou, D.-R. Wang, J. Zhao, Z.-M. Dang, Appl. Mater. Interfaces 3, 4557 (2011)

    Article  CAS  Google Scholar 

  5. L. Wang, Z.-M. Dang, Appl. Phys. Lett. 87, 042903 (2005)

    Article  Google Scholar 

  6. X.-Y. Huang, P.-K. Jiang, C. Kim, F. Liu, Y. Yina, Eur. Polym. J. 45, 377 (2009)

    Article  CAS  Google Scholar 

  7. H.-P. Xu, Z.-M. Dang, M.-J. Jiang, S.-H. Yao, J.-B. Bai, J. Mater. Chem. 18, 229 (2008)

    Article  CAS  Google Scholar 

  8. D.D.L. Chung, J. Mater. Sci. 39, 2645 (2004)

    Article  CAS  Google Scholar 

  9. Y.-J. Kim, T.-S. Shin, H.-D. Choi, J.-H. Kwon, Y.-C. Chung, Carbon 43, 23–30 (2005)

    Article  Google Scholar 

  10. S. Li, Y. Qin, J. Shi, Z.-X. Guo, Y. Li, D. Zhu, Chem. Mater. 17, 130 (2005)

    Article  CAS  Google Scholar 

  11. X. Liu, Y.-H. Zhang, M. Zhu, X. Yang, C.-R. Rong, G.-B. Wang, Soft Matter 9, 94 (2011)

    CAS  Google Scholar 

  12. Y. Kobayashia, T. Tanasea, T. Tabataa, T. Miwab, M. Konnoa, J. Eur. Ceram. Soc. 28, 117 (2008)

    Article  Google Scholar 

  13. P. Thomas, K.T. Varughese, K. Dwarakanath, K.B.R. Varma, Comp. Sci. Tech. 70, 539 (2010)

    Article  CAS  Google Scholar 

  14. W. Zheng, X.-F. Lu, W. Wang, Z.-J. Wang, M.X. Song, Y. Wang, C. Wang, Phys. Status Solidi A 207, 1870 (2010)

    Article  CAS  Google Scholar 

  15. G. Chen, W. Weng, D. Wu, C.Wu. Eur, Polym. J. 39, 2329 (2003)

    CAS  Google Scholar 

  16. G.-H. Chen, C.-L. Wu, W.G. Weng, Polymer 44, 1781 (2003)

    Article  CAS  Google Scholar 

  17. W. Zheng, S.-C. Wong, Comp. Sci. Tech. 63, 225 (2003)

    Article  CAS  Google Scholar 

  18. V. Causin, C. Marega, A. Marigo, G. Ferrara, A. Ferraro, Euro. Polym. J. 42, 3153 (2006)

    CAS  Google Scholar 

  19. M.J. McAllister, J.-L. Li, D.H. Adamson, H.C. Schnieep, A.A. Abdala, J. Liu, M. Herrera-Alonso, D.L. Milius, R. Car, R.K. Prud’homme, I.A. Aksay, Chem. Mater. 19, 4396 (2007)

    Article  CAS  Google Scholar 

  20. G.-H. Chen, W.-G. Weng, D.-J. Wu, C.-L. Wu, Eur. Polym. J. 39, 2329 (2003)

    Article  CAS  Google Scholar 

  21. M. Zhang, D.-J. Li, D.-F. Wu, C.-H. Yan, P. Lu, G.-M. Qiu, J. Appl. Polym. Sci. 108, 1482 (2008)

    Article  CAS  Google Scholar 

  22. C. Min, D.-M. Yu, Polym. Eng. Sci. 50, 1734 (2010)

    Article  CAS  Google Scholar 

  23. V. Panwar, R.M. Mehra, Eur. Polym. J. 44, 2367 (2008)

    Article  CAS  Google Scholar 

  24. G.K. Rashmi, P.K.C. Narula, Pillai. J. Mater. Sci. 22, 2006 (1986)

    Article  Google Scholar 

  25. D.-F. Ren, W.-W. Wei, Z.-H. Jiang, Y.-H. Zhang, Polym. Plast. Technol. Eng. 51, 1372 (2012)

    Article  CAS  Google Scholar 

  26. Y. Shen, Y.-H. Lin, M. Li, C.-W. Nan, Adv. Mater. 19, 1418 (2007)

    Article  CAS  Google Scholar 

  27. Y. Zhang, Y. Wang, Y. Deng, M. Li, J.-B. Bai, Mater. Lett. 72, 9 (2012)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Alan G. MacDiarmid Laboratory, College of Chemistry, Jilin University, Changchun, 130012, People’s Republic of China

    Qitong Wang, Wenlong Jiang, Shaowei Guan & Yunhe Zhang

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  1. Qitong Wang
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  2. Wenlong Jiang
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  3. Shaowei Guan
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  4. Yunhe Zhang
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Correspondence to Yunhe Zhang.

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Wang, Q., Jiang, W., Guan, S. et al. Preparation and Dielectric Properties of AGS@CuPc/PVDF Composites. J Inorg Organomet Polym 23, 743–750 (2013). https://doi.org/10.1007/s10904-013-9841-x

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  • DOI: https://doi.org/10.1007/s10904-013-9841-x

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