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Hydrothermal Syntheses and Crystal Structures of Two Coordination Polymers with Terephthalic Acid and N-Donor Ligand: 2-Methyldipyrido[3,2-f:2′,3′-h]quinoxaline

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Abstract

Two 3D coordination polymers, [Cd(BDC)(Medpq)·H2O]n 1, and [Co(BDC)(Medpq)·H2O] n 2 (BDC = terephthalic acid, Medpq = 2-Methyldipyrido[3,2-f:2′,3′-h]quinoxaline), have been synthesized by self-assembly. The structure analyses show that both of the two coordination polymers are formed by 1D infinite chains through non-covalent interactions, and both of them are based on 1D zigzag ones. The photoluminescent study of the coordination polymer [Cd(BDC)(Medpq)·H2O] n shows that it exhibit fluorescent emission bands at 567.7 nm.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Yan-Ju Huang & Liang Ni

  2. Department of Chemistry, Tonghua Teachers College, Tonghua, 134002, People’s Republic of China

    Yan-Ju Huang

Authors
  1. Yan-Ju Huang
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  2. Liang Ni
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Correspondence to Liang Ni.

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Huang, YJ., Ni, L. Hydrothermal Syntheses and Crystal Structures of Two Coordination Polymers with Terephthalic Acid and N-Donor Ligand: 2-Methyldipyrido[3,2-f:2′,3′-h]quinoxaline. J Inorg Organomet Polym 21, 97–102 (2011). https://doi.org/10.1007/s10904-010-9426-x

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  • DOI: https://doi.org/10.1007/s10904-010-9426-x

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