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Synthesis and Catalytic Activities of Silica-Supported Multifunctional Azo-Containing Schiff Base Complexes with Cu(II), Co(II), Ni(II) and Mn(II)

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Abstract

A novel 4-((5-formyl-2,4-dihydroxyphenyl)diazenyl)benzylphosphonic acid (FPABP) ligand was synthesized and bound to silica-gel which was activated with 3-aminopropyltriethoxysilane (APTES). Cu(II), Co(II), Ni(II) and Mn(II) complexes of silica-supported ligand (FDPDABP) were synthesized. The ligand and its complexes were characterized by using NMR, FT-IR, elemental analysis, ICP-OES and scanning electron Microscope (SEM). Catalytic properties of the complexes were investigated for the selective oxidation of cyclohexane under microwave power. SiO2-FDPDABP-Cu(II) complex showed good catalytic activitiy for the selective oxidation of cyclohexane to cyclohexanol with 35.61% yield and cyclohexanone with 7.74% yield.

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Acknowledgments

We would like to thank to Prof. Dr. Hakkı Alma and Dr. Murat Ertaş for thermal analyses measurements. The authors also thank to Sütçü İmam University for other measurement supports.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Letters, Kilis 7 Aralık University, Kilis, Turkey

    Serhan Uruş

  2. Environmental Engineering Department, Faculty of Engineering and Architecture, K.Maraş Sütçü İmam University, 46100, Kahramanmaraş, Turkey

    Mustafa Dolaz

  3. Department of Chemistry, Faculty of Science and Letters, K.Maraş Sütçü İmam University, 46100, Kahramanmaraş, Turkey

    Mehmet Tümer

Authors
  1. Serhan Uruş
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  2. Mustafa Dolaz
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  3. Mehmet Tümer
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Correspondence to Serhan Uruş.

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Uruş, S., Dolaz, M. & Tümer, M. Synthesis and Catalytic Activities of Silica-Supported Multifunctional Azo-Containing Schiff Base Complexes with Cu(II), Co(II), Ni(II) and Mn(II). J Inorg Organomet Polym 20, 706–713 (2010). https://doi.org/10.1007/s10904-010-9394-1

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  • DOI: https://doi.org/10.1007/s10904-010-9394-1

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