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Oxazoline-Containing Phosphazene Derivatives Part II Polymer Preparation and Modification Through the Reactivity of Oxazoline Moieties on Cyclophosphazenes

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In this paper we report the synthesis, the characterization and the practical utilization of two cyclophosphazenes (CPs) substituted with two (C-2-OXA) and six (C-6-OXA) 2-(4-hydroxyphenyl)-2-oxazoline groups, respectively. The first chemical observation on these substrates is that the reactivity of the oxazoline groups is preserved even when these products are attached to the phosphorus atoms of a cyclophosphazene ring. By reaction of C-2-OXA with organic molecules, e.g. adipic acid, and macromolecules, e.g. poly(ethylene terephthalate) (PET), the oxazoline substituents open their heterocycles to form cyclolinear polymers or to act as chain extenders. Similarly, the ring-opening polymerization reaction of C-6-OXA in the presence of cationic initiators allows the production of a new class of cyclomatrix polymers. The characterization of the new materials is reported.

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Authors and Affiliations

  1. Dipartimento di Processi Chimici dell’Ingegneria, Universita di Padova, Via F.Marzolo 9, 35125, Padova, Italy

    Roberta Bertani

  2. Dipartimento di Ingegneria dei Materiali e Tecnologie Industriali, Università di Trento, Via Mesiano 77, 38050, Trento, Italy

    Luca Fambri

  3. Enitecnologie S.p.A., Centro Ricerche Novara – Istituto Donegani, Via Fauser 4, 28100, Novara, Italy

    Luisa Fiocca, Giorgio Giannotta & Riccardo Pò

  4. Istituto di Scienze e Tecnologie Molecolari del Consiglio Nazionale delle Ricerche, c/o Dipartimento di Scienze Chimiche, Università di Padova, Via Marzolo 1, 35131, Padova, Italy

    Mario Gleria & Alfonso Venzo

  5. Dipartimento di Scienze Chimiche, Università di Padova, Via Marzolo 1, 35131, Padova, Italy

    Sonia Scalabrin & Eugenio Tondello

Authors
  1. Roberta Bertani
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  2. Luca Fambri
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  3. Luisa Fiocca
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  4. Giorgio Giannotta
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  5. Mario Gleria
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  6. Riccardo Pò
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  7. Sonia Scalabrin
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  8. Eugenio Tondello
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  9. Alfonso Venzo
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Correspondence to Roberta Bertani.

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Dedicated to Prof. C.W.Allen

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Bertani, R., Fambri, L., Fiocca, L. et al. Oxazoline-Containing Phosphazene Derivatives Part II Polymer Preparation and Modification Through the Reactivity of Oxazoline Moieties on Cyclophosphazenes. J Inorg Organomet Polym 17, 387–398 (2007). https://doi.org/10.1007/s10904-007-9129-0

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  • DOI: https://doi.org/10.1007/s10904-007-9129-0

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