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Optical Properties of Some Fluorinated Poly(1,3,4-Oxadiazole-Ether)s in Homogeneous and Heterogeneous Media. Changes Induced by SnO2, NiO and SnO2/NiO Mixed-Oxide Nanoparticles

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Abstract

Optical characteristics of some fluorinated poly(1,3,4-oxadiazole-ether)s in presence of SnO2, NiO and SnO2/NiO mixed-oxide nanoparticles (NPs) was investigated. The interactions between polymers and metal oxide NPs were studied by steady-state UV-Vis absorption and fluorescence spectroscopy techniques. The absorption and fluorescence signals of all investigated polymers was modified by presence of both pure and mixed-oxide nanoparticles. The moderate values of Stern-Volmer quenching constant and non-linear trend of Scott plot indicate the less affinity between metal oxide NPs and polymers. The solvation behavior of some fluorinated poly(1,3,4-oxadiazole-ether)s in chloroform–N,N-dimethylformamide and N,N-dimethylformamide-dimethylsulfoxide mixtures was discussed.

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Authors and Affiliations

  1. “Petru Poni” Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487, Iasi, Romania

    Mihaela Homocianu, Anton Airinei, Alina Mirela Ipate, Petronela Pascariu Dorneanu & Corneliu Hamciuc

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  1. Mihaela Homocianu
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  2. Anton Airinei
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  3. Alina Mirela Ipate
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  4. Petronela Pascariu Dorneanu
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  5. Corneliu Hamciuc
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Correspondence to Mihaela Homocianu.

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Homocianu, M., Airinei, A., Ipate, A.M. et al. Optical Properties of Some Fluorinated Poly(1,3,4-Oxadiazole-Ether)s in Homogeneous and Heterogeneous Media. Changes Induced by SnO2, NiO and SnO2/NiO Mixed-Oxide Nanoparticles. J Fluoresc 26, 217–224 (2016). https://doi.org/10.1007/s10895-015-1704-0

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  • DOI: https://doi.org/10.1007/s10895-015-1704-0

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