Skip to main content
Log in

White Light Emission by Dy3+ Doped Phosphor Matrices: A Short Review

  • ORIGINAL ARTICLE
  • Published:
Journal of Fluorescence Aims and scope Submit manuscript

Abstract

In this review we have studied number of research papers related to white light emission from Dy3+ doped different host matrices. It is observed that most of the Dy3+doped aluminates, silicates, borates etc., emitted blue, green and red colour with specific intensities so that CIE coordinates, appeared near to white light. Correlated Colour Temperature (CCT) values of these phosphors expressed that the white light emission produced, was adaptable to human eyes. Dy3+ ions act as activator in each case. Four peaks at approximately 480, 575, 670, and 757 nm could be seen in most of the Dy3+ doped phosphors. Expected transition responsible for these peaks are 4F9/2 → 6H15/2 (Blue Colour), 4F9/2 → 6H13/2 (Green-Yellow Colour), 4F9/2 → 6H11/2 (Red Colour) and 4F9/2 → 6H9/2 (Brownish Red Colour). Few of the discussed phosphors exhibited long phosphorescence, starting from several minutes to few hours. Mechanism responsible for long lasting white light emission was also discussed. Five different factors, to recognize the phosphors for its suitability as commercial white light phosphor have been discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Yang F, Ma H, Liuc Y, Han B, Feng H, Yu Q (2014) Photoluminescence properties of novel Dy3+ doped Ba5CaAl4O12 phosphors. Ceram Int 40:10189–10192

    Article  CAS  Google Scholar 

  2. Liang CH, Teoh LG, Liu KT, Chang YS (2012) Near white light emission of BaY2ZnO5 doped with Dy3+ ions. J Alloys Compd 517:9–13

    Article  CAS  Google Scholar 

  3. Wang J, Wang J, Duan P (2013) Luminescent properties of Dy3+ doped Sr3Y(PO4)3 for white LEDs. Mater Lett 107:96–98

    Article  CAS  Google Scholar 

  4. Liu Q, Liu Y, Ding Y, Peng Z, Tian X, Yu Q, Dong G (2014) A White light emitting luminescent material Ba3Y(PO4)3:Dy3+. Ceram Int 40:10125–10129

    Article  CAS  Google Scholar 

  5. Shieh J-Y, Wang LK, Chiu ML (2012) A High Color Rendering Index on Multichip LED Light Source. Circuits and Systems 3:107–110

    Article  Google Scholar 

  6. McCamy CS (1992) Correlated colour temperature as an explicit function of chromaticity coordinates. Color Res Appl 17:142–144

    Article  Google Scholar 

  7. Smet PF, Parmentier AB, Poelman D (2011) Selecting conversion phosphors for white light-emitting diodes. J Electrochem Soc 158:R37–R54

    Article  CAS  Google Scholar 

  8. Zhang ZW, Sun XY, Liu L, Peng YS, Shen XH, Zhang WG, Wang DJ (2013) Synthesis and luminescence properties of novel LiSr4(BO3)3:Dy3+ phosphors. Ceram Int 39:1723–1728

    Article  CAS  Google Scholar 

  9. Zhang L, Lu Z, Yang H, Han P, Xu N, Zhang Q (2012) Preparation of Dy3+-activated strontium orthosilicate (Sr2SiO4:Dy3+) phosphors and its photoluminescent properties. J Alloys Compd 512:5–11

    Article  CAS  Google Scholar 

  10. Pavani K, Kumar JS, Sasikala T, Jamalaiah BC, Seo HJ, Moorthy LR (2011) Luminescent characteristics of Dy3+ doped strontium magnesium aluminate phosphor for white LEDs. Mater Chem Phys 129:292–295

    Article  CAS  Google Scholar 

  11. You P, Yin G, Chen X, Yue B, Huang Z, Liao X, Yao Y (2011) Luminescence properties of Dy3+-doped Li2SrSiO4 for NUV-excited white LEDs. Opt Mater 33:1808–1812

    Article  CAS  Google Scholar 

  12. Dillip GR, Ramesh B, Reddy CM, Mallikarjuna K, Ravi O, Dhoble SJ, Joo SW, Raju BDP (2014) X-ray analysis and optical studies of Dy3+ doped NaSrB5O9 microstructures for white light generation. J Alloys Compd 615:719–727

    Article  CAS  Google Scholar 

  13. Zhang X, Lu Z, Meng F, Hu L, Xu X, Lin J, Tang C (2012) Luminescence properties of Ca3Si2O7: Dy3+ phosphor for white light-emitting diodes. Mater Lett 79:292–295

    Article  CAS  Google Scholar 

  14. Sunitha DV, Nagabhushana H, Sharma SC, Nagabhushana BM, Daruka Prasad B, Chakradhar RPS (2014) Study on low temperature solution combustion synthesized Sr2SiO4:Dy3+ nano phosphor for white LED. Spectrochim. Acta A Mol. Biomol. Spectrosc 127:381–387

    Article  PubMed  CAS  Google Scholar 

  15. H. Zhong, X. Li, R. Shen, J. Zhang, J. Sun, H. Zhong,, L. Cheng, Y. Tian, B. Chen, Spectral and thermal properties of Dy3+-doped NaGdTiO4 phosphors, J Alloys Compd 517 (2012) 170–175.

    Article  CAS  Google Scholar 

  16. Kuang J, Liu Y, Zhang J (2006) White-light-emitting long-lasting phosphorescence in Dy3+-doped SrSiO3. J Solid State Chem 179:266–269

    Article  CAS  Google Scholar 

  17. Liu B, Kong L, Shi C (2007) White-light long-lasting phosphor Sr2MgSi2O7:Dy3+. J Lumin 122–123:121–124

    Article  Google Scholar 

  18. Lin L, Zhonghua Z, Weiping Z, Zhiquiang Z, Min Y (2009) Photo-luminescence properties and thermo- luminescence curve analysis of a new white long-lasting phosphor: Ca2MgSi2O7:Dy3+. J Rare Earths 27(5):749–752

    Article  Google Scholar 

  19. Tshabalala MA, Dejene FB (2014) ShreyasS.Pitale, H.C. Swart, O.M. Ntwaeaborwa, generation of white- light from Dy3+ doped Sr2SiO4 phosphor. Physica B 439:126–129

    Article  CAS  Google Scholar 

  20. Chen Y, Cheng X, Liu M, Qi Z, Shi C (2009) Comparison study of the luminescent properties of the white-light long afterglow phosphors: CaxMgSi2O5 + x:Dy3 + (x = 1, 2, 3). J Lumin 129:531–535

  21. Wei RP, Ju ZH, Ma JX, Zhang D, Zang ZP, Liu WS (2009) A novel white afterglow phosphorescent phosphor Ca3SnSi2O9:Dy3+. J Alloys Compd 486:L17–L20

    Article  CAS  Google Scholar 

  22. Rajeswari R, Jayasankar CK, Ramachari D, SurendraBabu S (2013) Synthesis, structural and luminescence properties of near white light emitting Dy3+-doped Y2CaZnO5 Nano-phosphor for solid state lighting. Ceram Int 39:7523–7529

    Article  CAS  Google Scholar 

  23. Ji Y, Cao J, Zhu Z, Li J, Wang Y, Tu C (2012) Synthesis and white light emission of Dy3+ ions doped hexagonal structure YAlO3 Nano-crystalline. J Lumin 132:702–706

    Article  CAS  Google Scholar 

  24. Shrivastava R, Kaur J, Dash M (2015) Studies on white light emission of Sr2MgSi2O7 doped with Dy3+ phosphors. Superlattice Microst 82:262–268

  25. Chemingui S, Ferhi M, Horchani-Naifer K, Férid M (2015) Synthesis and luminescence characteristics of Dy3+ doped KLa(PO3)4. J Lumin 166:82–87

  26. Vishwakarma AK, Kaushal JHA, Jayasimhadri M, Sivaiah B, Bhasker G, Haranathb D (2015) Emerging cool white light emission from Dy3+ doped single phase alkaline earth niobate phosphors for indoor lighting applications, Dalton Trans. doi:10.1039/C5DT02436F

  27. Ratnam BV, Jayasimhadri M, Kiwan J, Sueb LH, Soung-Soo Y, Jung-Hyun J (2015). White Light Emission from NaCaPO4:Dy3+ Phosphor for Ultraviolet-Based White Light-Emitting Diodes. J Am Ceram Soc. doi:10.1111/j.1551-2916.2010.03963.x

  28. Seeta Rama Raju G, Pavitra E, Yu JS (2015) Luminescence properties of Dy3+ ions activated novel warm white- light emitting CaGd2ZnO5 nanophosphors. Ceram Int 41:11228–11233

  29. Zhang ZW, Song AJ, Yue Y, Zhong H, Zhang XY, Ma MZ, Liu RP (2015) White light emission from Ca9Bi(PO4)7:Dy3+ single-phase phosphors for light-emitting diodes. J Alloys Compd 650:410-414

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ravi Shrivastava.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shrivastava, R., Kaur, J. & Dubey, V. White Light Emission by Dy3+ Doped Phosphor Matrices: A Short Review. J Fluoresc 26, 105–111 (2016). https://doi.org/10.1007/s10895-015-1689-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10895-015-1689-8

Keywords

Navigation