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Analytical Evaluation of Cu2+ Selective Behavior of calix[4]arene Derivative

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Abstract

The present article describes the solvatochromic effect including solvent system selection, time study and a detailed complexation study along with exploration of extraction properties of 5,11,17,23-tetrakis[(diethylamino)methyl]-25,26,27,28-tetrahydroxycalix[4]arene (4) that bears nitrogen atom as a donor group available for chelating metal ions. Complexation properties of 4 toward selected transition metal ions have been investigated by UV-visible and fluorescence spectroscopies. The% efficiency of 4 toward selected transition metal ions was found in order Cu2+> Ni2+> Hg2+> Zn2+> Co2+> Cd2+> Pb2+. It has been noticed that 4 is not only proved to be an efficient Cu2+ selective chromoionophore but also possesses an effective extraction property for transferring Cu2+ ions from an aqueous to dichloromethane layer. The FT-IR spectroscopic method has also been applied for further confirmation of the complexation phenomenon of 4 with Cu2+ ion and found adequate.

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Acknowledgements

We thank the National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro/Pakistan for the financial support of this work.

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  1. National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, 76080, Pakistan

    Mansoor Ahmed Qazi, Imdadullah Qureshi & Shahabuddin Memon

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  1. Mansoor Ahmed Qazi
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  2. Imdadullah Qureshi
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  3. Shahabuddin Memon
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Correspondence to Mansoor Ahmed Qazi or Shahabuddin Memon.

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Qazi, M.A., Qureshi, I. & Memon, S. Analytical Evaluation of Cu2+ Selective Behavior of calix[4]arene Derivative. J Fluoresc 21, 1703–1711 (2011). https://doi.org/10.1007/s10895-011-0865-8

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  • DOI: https://doi.org/10.1007/s10895-011-0865-8

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