Abstract
The Li2TiO3 pebble has been recognized as a prominent candidate breeder material. In terms of the functional requirements of the tritium breeders, the open porosity, density and lithium density, crush load, and grain size of the pebbles are important parameters. In order to investigate the effect of the fabrication process on the open porosity of Li2TiO3 pebbles, the Li2TiO3 pebbles were fabricated by three different ways: the graphite bed process, the gel-casting method, and the agar method. The microstructure, crush load, and phase of these pebbles were also investigated. In addition, it also evaluated and optimized the fabrication process for Li2TiO3 pebbles. The optimal crush load, grain size, and open porosity of the pebbles fabricated by the agar method were 86.2 N, 2.5 μm, and 10.2 %, respectively.
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References
D.L. Jassby, J. File, P.C. Bertone et al., The TFTR lithium blanket module program. J. Fusion Energ. 4(1), 57–77 (1985)
C.E. Johnson, K. Noda, N. Roux, Ceramic breeder materials: status and needs. J. Nucl. Mater. 258, 140–148 (1998)
M. Übeyli, Effect of lithium enrichment on the tritium breeding characteristics of various breeders in a fusion driven hybrid reactor. J. Fusion Energ. 28(3), 300–303 (2009)
J.G. Vander Laan, H. Kawamura, N. Roux et al., Ceramic breeder research and development: progress and focus. J. Nucl. Mater. 283, 99–109 (2000)
P. Gierszewski, Review of properties of lithium metatitanate. Fusion Eng. Des. 39, 739–743 (1998)
K. Kataoka, Y. Takahashi, N. Kijima et al., Crystal growth and structure refinement of monoclinic Li2TiO3. Mater. Res. Bull. 44, 168–172 (2009)
N. Roux, S. Tanaka, C. Johnson et al., Ceramic breeder material development. Fusion Eng. Des. 41, 31–38 (1998)
D. Mandal, D. Sathiyamoorthy, V. Govardhana, Rao, Preparation and characterization of lithium–titanate pebbles by solid-state reaction extrusion and spherodization techniques for fusion reactor. Fusion Eng. Des. 87, 7–12 (2012)
D. Mandal, M.R.K. Shenoi, S.K. Ghosh, Synthesis and fabrication of lithium-titanate pebbles for ITER breeding blanket by solid state reaction and spherodization. Fusion Eng. Des. 85, 819–823 (2010)
C.H. Jung, J.Y. Park, W.J. Kim et al., Characterizations of Li2TiO3 prepared by a solution combustion synthesis and fabrication of spherical particles by dry-rolling granulation process. Fusion Eng. Des. 81(8), 1039–1044 (2006)
T.V. Vittal Rao, Y.R. Bamankar, S.K. Mukerjee et al., Preparation and characterization of Li2TiO3 pebbles by internal gelation sol–gel process. J. Nucl. Mater. 426, 102–108 (2012)
X. Wu, Z. Wen, J. Han et al., Fabrication of Li2TiO3 pebbles by water-based sol–gel method. Fusion Eng. Des. 83, 112–116 (2008)
T. Hoshino, M. Nakamichi, Development of fabrication technologies for advanced breeding functional materials For DEMO reactors. Fusion Eng. Des. 87, 486–492 (2012)
T. Hoshino, F. Oikawa, Trial fabrication tests of advanced tritium breeder pebbles using sol–gel method. Fusion Eng. Des. 86, 2172–2175 (2011)
K. Tsuchiya, H. Kawamura, T. Takayama, Control of particle size and density of Li2TiO3 pebbles fabricated by indirect wet processes. J. Nucl. Mater. 345, 239–244 (2005)
K. Tsuchiya, H. Kawamura, Development of wet process with substitution reaction for the mass production of Li2TiO3 pebbles. J. Nucl. Mater. 283, 1380–1384 (2000)
W. Manheimer, Fusion breeding for mid-century sustainable power. J. Fusion Energ. 33(3), 199–234 (2014)
M. Hong, Y. Zhang, Y. Mi, Characterization of Li2TiO3 pebbles by graphite bed process. J. Nucl. Mater. 441, 390–394 (2013)
M. Hong, Y. Zhang, Y. Mi, Y. Jiang et al., Synthesis of Li2TiO3 by sol–gel combustion method and its gel-casting formation. J. Nucl. Mater. 455, 311–315 (2014)
A. Ying, M. Akiba, L.V. Boccaccini et al., Status and perspective of the R&D on ceramic breeder materials for testing in ITER. J. Nucl. Mater. 367, 1281–1286 (2007)
C.E. Johnson, Tritium behavior in lithium ceramics. J. Nucl. Mater. 270, 212–220 (1999)
D. Zhu, S. Peng, X. Chen et al., Fabrication and characterization of Li3TaO4 ceramic pebbles by wet process. J. Nucl. Mater. 396, 245–250 (2010)
T. Hoshino, K. Kato, Y. Natori et al., Development of advanced tritium breeding material with added lithium for ITER-TBM. J. Nucl. Mater. 417, 684–687 (2011)
T. Hoshino, K. Kato, Y. Natori et al., New synthesis method of advanced lithium titanate with Li4TiO4 additives for ITER-TBM. Fusion Eng. Des. 84, 956–959 (2009)
K. Mukai, K. Sasaki, T. Terai et al., Observations on microstructure and crystal structure of sintered lithium metatitanate with excess Li. Fusion Eng. Des. 87, 836–839 (2012)
K. Mukai, K. Sasaki, T. Hashimoto et al., Effect of Li/Ti ratio on microstructure and thermal diffusivity of lithium titanate for solid breeding material. Fusion Eng. Des. 86, 2643–2646 (2011)
Acknowledgments
This work has been financially supported by the National Natural Science Foundation of China (Nos. 51372017 and 51172019), International Thermonuclear Experimental Reactor (ITER) Project of China (No. 2014GB123000) and National Magnetic Confinement Fusion Energy Research Project (No. 2015GB121006).
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Xiang, M., Zhang, Y., Zhang, Y. et al. Effect of the Fabrication Process of Ceramic Pebbles on the Porosity of Li2TiO3 Tritium Breeder. J Fusion Energ 34, 1423–1432 (2015). https://doi.org/10.1007/s10894-015-9991-7
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DOI: https://doi.org/10.1007/s10894-015-9991-7