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Polyoxometalate Clusters: Inorganic Ligands for Functional Materials

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Abstract

Research in polyoxometalates (POMs) is a diverse growing field with variations in application. POMs are consisting of metal ion and oxide. Peripheral oxides of POM can share spare electron pairs to behave as ligands. This property of POM was utilized for constructing coordination polymers (CPs), synthesizing transitional metal substituted POM for catalysis, synthesizing and stabilizing nano-particles, etc. POM connected structures have provided an opportunity of heterogenization of some homogeneous POM catalyst. Furthermore, diamagnetic POM ligands have been suitable for stabilizing and isolating magnetic ions inside clusters. The scope of this review is to summarize the role of POMs as ligands to prepare POM based CPs, synthesize and stabilize metal nano-particles and isolate magnetic ion or unit.

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Fig. 1
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Scheme 1
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Abbreviations

POM:

Polyoxometalate

MOF:

Metal organic framework

NP:

Nano-particle

CP:

Coordination polymer

1D:

One dimensional

2D:

Two dimensional

3D:

Three dimensional

BTC:

1,3,5-Benzenetricarboxylate

TBA:

Tetrabutyl ammonium cation

HER:

Hydrogen evolution reaction

TEOA:

Triethanolamine

bpy:

2,2´-Bipyridine

µ-ox:

Oxalate

arg:

L-arginine

enMe:

1,2´-Propanediamine

NH2-BPY:

NH2-bipyridine

PYI:

Pyrrolidine-2-yl-imidazole

pyr:

Pyrazole

pzta:

5-(2-Pyrazinyl)tetrazole

btp:

2,6-Bis(1,2,4-triazol-1-yl)pyridine

3-dpyb:

N,N´-bis(3-pyridinecarboxamide)-1,4-butane

3-dpye:

N,N´–bis(3–pyridinecarboxamide)–1,2–ethane

POM-2:

[MnMo6O18{(OCH2)3-C-C5H4N}2]3−

DMF:

Dimethyl formamide

POM-2:

[MnMo6O18((OCH2)3CN = CH-3-Py)2]

bim:

Benzimidazole, btx:1,6-bis(1,2,4- triazol-1-y1)hexane

3-bpo:

(2,5-Bis(3-pyridyl)-1,3,4-oxadiazole)

L:

4,4′-Bis((1H-1,2,4-triazol-1-yl) methyl) biphenyl

L1 :

2,3-Diphenylpyrazine

PDA:

1,10-Phenanthroline-2,9-dicarboxylic acid

DAPSC:

2,6-Diacetylpyridine bis(semicarbazone)

bpp:

1,3-Bis(4-pyridyl)propane

Bbtz:

1,4-Bis(triazol-1-ylmethyl) benzene

Btp:

1,3-Bis-(1,2,4-triazol-1-yl) propane

Htrz:

1,2,4-Triazole

Hpzc:

Pyrazine-2-carboxylic acid

pz:

Pyrazine

H2pbtz:

5’-(Pyridin-2-yl)-1H,2’H-3,3’-bi(1,2,4-triazole)

BBTZ:

1,4-Bis(1,2,4-triazol-1-ylmethyl)-benzene

NMP:

N-methyl-2-pyrrolidone

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Acknowledgements

CD acknowledges Prof. Rahul Banerjee for his encouragement to build up this review.

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  1. Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India

    Chandan Dey

  2. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán Martínez No. 2, 46980, Paterna, Spain

    Chandan Dey

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Dey, C. Polyoxometalate Clusters: Inorganic Ligands for Functional Materials. J Clust Sci 33, 1839–1856 (2022). https://doi.org/10.1007/s10876-021-02110-8

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