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Influence of Ring Structures on Optical Properties of Trivalent Bismuth in Bi-Doped Silica Optical Fiber

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Abstract

We report silica fiber with trivalent bismuth (Bi3+) in first-principles calculations. The influences of members of “Si–O–Si” rings are considered to study atomic structures, frontier molecular orbital and optical properties of Bi-doped optical fiber. Our results reveal that the luminescence of Bi3+-doped optical fiber is the result of a combination of Bi3+ ions and silica matrix. Different ring structures affect the luminescence properties, which explained why Bi3+-doped silica fiber usually cover a broad spectral range from the UV to visible light.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China (No. 2017YFB0405100). We acknowledge the computational support from the Beijing Computational Science Research Center (CSRC).

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Authors and Affiliations

  1. State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, Beijing, 100876, China

    Baonan Jia, Pengfei Lu, Jie Zhang, Zhixing Peng & Binbin Yan

  2. Southwest Institute of Technical Physics, Chengdu, 610041, China

    You Wang

  3. School of Electrical Engineering and Telecommunications, University of New South Wales, Sydney, 2052, Australia

    Gang-Ding Peng

Authors
  1. Baonan Jia
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  2. Pengfei Lu
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  3. Jie Zhang
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  4. Zhixing Peng
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  5. Binbin Yan
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  6. You Wang
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  7. Gang-Ding Peng
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Correspondence to Pengfei Lu or Gang-Ding Peng.

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Jia, B., Lu, P., Zhang, J. et al. Influence of Ring Structures on Optical Properties of Trivalent Bismuth in Bi-Doped Silica Optical Fiber. J Clust Sci 29, 861–865 (2018). https://doi.org/10.1007/s10876-018-1362-x

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  • DOI: https://doi.org/10.1007/s10876-018-1362-x

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