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Syntheses, Structures and Properties of Three Heteonuclear Complexes Containing [V10O28]6− Units

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Abstract

Three heteonuclear complexes containing [V10O28]6− units, {[Cu(pyr)(H2O)4]2(H3O)2[V10O28] · 13.5H2O}n (1), {[Ni(pyr)(H2O)4]2(H3O)2[V10O28] · 9.5H2O}n (2) and [Zn2(H2O)14(V10O28)] · H2PPZ (3) are synthesized and characterized by elemental analyses, IR, single crystal X-ray analyses. The complex 1 and 2 have the similar structures which are composed of the [V10O28]6− cluster anion and 1D chain {[M (pyr)(H2O)4]2+}n (M = Cu Ni) cations bridged by pyrazine. In the complex 3, Zn2+ with two coordination modes is bridged by water molecules to build 1D zigzag chains, and then is linked to the bridging oxygen atoms from [V10O28]6− to generate a 2D grid architecture filled with the protoned piperazine (PPZ) molecules. In this paper, the magnetic properties of complex 2 are characterized.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20771062 and 20371027) and Tianjin Science Foundation (No. 08JCZDJC21100).

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China

    Li Wang, Xiu-ping Sun, Mei-ling Liu, Yue-qiang Gao, Wen Gu & Xin Liu

  2. State Key Laboratory of Coordination Chemistry, Nanjin, 210093, People’s Republic of China

    Xin Liu

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  1. Li Wang
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Correspondence to Wen Gu.

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Wang, L., Sun, Xp., Liu, Ml. et al. Syntheses, Structures and Properties of Three Heteonuclear Complexes Containing [V10O28]6− Units. J Clust Sci 19, 531–542 (2008). https://doi.org/10.1007/s10876-008-0196-3

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