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Influence of traffic emissions on the composition of atmospheric particles of different sizes—Part 2: SEM–EDS characterization

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Abstract

In urban areas traffic is the major contributor to atmospheric particulate matter and exposure to these particles currently represents a serious risk to human health. The attention has been recently focused more on the particles of smaller sizes (PM2.5) which penetrate deeper in respiratory system causing severe health effects. Therefore, more information on PM2.5 should be provided, namely concerning morphological and chemical characterization. Aiming further evaluation of the impact of traffic emissions on public health, this work evaluated the influence of traffic on the chemical and morphological characteristics of PM10 and PM2.5, collected at one site influenced by traffic emissions and at one reference site. Chemical and morphological characteristics of 1,000 individual particles were determined by scanning electron microscopy combined with energy dispersive spectrometer (SEM–EDS). Cluster analysis (CA) was used to identify different types of particles that occurred in PM, aiming the identification of the respective emission sources. Traffic PM2.5 were dominated by particles composed of Fe oxides and alloys (67%) which were related to traffic emissions (this percentage was 3.7 times higher than at the background site); in PM2.5–10 the abundance of Fe oxides and alloys were 20% and 0% for the traffic and background sites, respectively. Background PM2.5 were mainly constituted by aluminum silicates (63%) related to natural sources (this percentage was 2.5 times higher than at the traffic site); the abundances of aluminum silicates in PM2.5–10 were 74% and 73% for traffic and background sites, respectively. It was concluded that traffic emissions were mainly present in PM2.5 (the percentage of particles associated to these emissions was 3.4 times higher than in PM2.5–10), while coarse particles were dominated by material of natural origin (the percentage of particles associated was 1.2 and 3.0 times higher than in PM2.5 for traffic and background sites, respectively). Previous results obtained by proton induced X-ray emission (PIXE) were consistent with SEM–EDS analysis that showed to be very useful to complement elemental analysis of different PM2.5 and PM2.5–10.

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References

  • ATSDR: Agency for Toxic Substances and Disease Registry. Toxicological profile information sheet, http://www.atsdr.cdc.gov/toxprofiles (2003)

  • Begonha, A.J.: Meteorização do granito e deterioração da pedra em monumentos e edifícios da cidade do Porto. Doctorate thesis, Faculty of Engineering, University of Porto, Portugal (1997)

  • Breed, C.A., Arocena, J.M., Sutherland, D.: Possible sources of PM10 in Prince George (Canada) as revealed by morphology and in situ chemical composition of particulate. Atmos. Environ. 36, 1721–1731 (2002). doi:10.1016/S1352-2310(01)00500-3

    Article  Google Scholar 

  • Brunekreef, B., Holgate, S.T.: Air pollution and health. Lancet 360, 1233–1242 (2002). doi:10.1016/S0140-6736(02)11274-8

    Article  Google Scholar 

  • Casuccio, G.S., Schlaegle, S.F., Lersch, T.L., Huffman, G.P., Chen, Y., Shah, N.: Measurement of fine particulate matter using electron microscopy techniques. Fuel Process. Technol. 85, 763–779 (2004). doi:10.1016/j.fuproc.2003.11.026

    Article  Google Scholar 

  • Conner, L.H., Norris, G.A., Landis, M.S., Williams, R.W.: Individual particle analysis of indoor, outdoor, and community samples from the 1998 Baltimore particulate matter study. Atmos. Environ. 35, 3935–3946 (2001). doi:10.1016/S1352-2310(01)00191-1

    Article  Google Scholar 

  • Constantino, J.P., Janocko, P.B., Casuccio, G.S.: Assessment of thoracic particulate levels at surface mining operations. Report no. L-1355, Bituminous Coal Research, Inc., 350 Hochberg Road, Monroeville, PA, pp. 25–28 (1983)

  • Dockery, D.W., Pope, C.A.: Acute respiratory effects of particulate air-pollution. Annu. Rev. Public Health 15, 107–132 (1994). doi:10.1146/annurev.pu.15.050194.000543

    Article  Google Scholar 

  • Ghio, A.J., Devlin, R.B.: Inflammatory lung injury after bronchial instillation of air pollution particles. Am. J. Respir. Crit. Care Med. 164, 704–708 (2001)

    Google Scholar 

  • Heinrich, J., Topp, R., Gehring, U., Thefeld, W.: Traffic at residential address, respiratory health, and atopy in adults: the National German Health Survey 1998. Environ. Res. 98, 240–249 (2005). doi:10.1016/j.envres.2004.08.004

    Article  Google Scholar 

  • Holgate, S.T., Samet, J.M., Koren, H.S., Maynard, R.L.: Air Pollution and Health, pp. 123–124. Academic, London (1999a)

    Google Scholar 

  • Holgate, S.T., Samet, J.M., Koren, H.S., Maynard, R.L.: A. Air Pollution and Health, pp. 621–622. Academic, London (1999b)

    Google Scholar 

  • Janssen, N.A.H., van Vliet, P.H.N., Aarts, F., Harssema, H., Brunekreef, B.: Assessment of exposure to traffic related air pollution of children attending schools near motorways. Atmos. Environ. 35, 3875–3884 (2001). doi:10.1016/S1352-2310(01)00144-3

    Article  Google Scholar 

  • Kaiser, J.: Evidence mounts that tiny particles can kill. Science 289, 22–23 (2000). doi:10.1126/science.289.5476.22

    Article  Google Scholar 

  • Kannel, P.R., Lee, S., Kanel, S.R., Khan, S.P.: Chemometric application in classification and assessment of monitoring locations of an urban river system. Anal. Chim. Acta. 582, 390–399 (2007). doi:10.1016/j.aca.2006.09.006

    Article  Google Scholar 

  • Kunzli, N., Kaiser, R., Medina, S., Studnicka, M., Chanel, O., Filliger, P., Herry, M., Horak, J.F., Puybonnieux-Texier, V.: Public-health impact of outdoor and traffic-related air pollution: a European assessment. Lancet 356, 795–801 (2000). doi:10.1016/S0140-6736(00)02653-2

    Article  Google Scholar 

  • Larssen, S., Sluyter, R., Helmis, C.: 1999. Criteria for EUROAIRNET, the EEA Air Quality Monitoring and Information Network.

  • Manly, B.F.J.: Multivariate Statistical Methods—A Primer, 2nd Edition, pp. 129–133. Chapman and Hall, London (1994)

    Google Scholar 

  • McKenna, J.E.: An enhanced cluster analysis program with bootstrap significance testing for ecological community analysis. Environ. Model. Softw. 18, 205–220 (2003). doi:10.1016/S1364-8152(02)00094-4

    Article  Google Scholar 

  • Moreno, T., Gibbons, W., Jones, T., Richards, R.: The geology of ambient aerosols: characterising urban and rural/coastal silicate PM10–2.5 and PM2.5 using high volume cascade collection and scanning electron microscopy. Atmos. Environ. 37, 4265–4276 (2003). doi:10.1016/S1352-2310(03)00534-X

    Article  Google Scholar 

  • Moreno, T., Jones, T.P., Richards, R.J.: Characterization of aerosol particulate matter from urban and industrial environments: examples from Cardiff and Port Talbot, South Wales, UK. Sci. Total Environ. 334–335, 337–346 (2004). doi:10.1016/j.scitotenv.2004.04.074

    Google Scholar 

  • Paoletti, L., Diociaiuti, M., De Berardis, B., Santucci, S., Lozzi, L., Picozzi, P.: Characterisation of aerosol individual particles in a controlled underground area. Atmos. Environ. 33, 3603–3611 (1999). doi:10.1016/S1352-2310(99)00101-6

    Article  Google Scholar 

  • Paoletti, L., De Berardis, B., Diociaiuti, M.: Physico-chemical characterisation of the inhalable particulate matter (PM10) in an urban area: an analysis of the seasonal trend. Sci. Total Environ. 292, 265–275 (2002). doi:10.1016/S0048-9697(01)01134-2

    Article  Google Scholar 

  • Pereira, M.C., Alvim Ferraz, M.C.M., Santos, R.C.: Relevant aspects of air quality in Oporto (Portugal): PM10 and O3. Environ. Assess. Monit. 101, 203–221 (2005)

    Google Scholar 

  • Querol, X., Alastuey, A., Rodriguez, S., Plana, F., Ruiz, C.R., Cots, N., Massague, G., Puig, O.: PM10 and PM2.5 source apportionment in the Barcelona Metropolitan area, Catalonia, Spain. Atmos. Environ. 35, 6407–6419 (2001). doi:10.1016/S1352-2310(01)00361-2

    Article  Google Scholar 

  • Reis, M.A., Oliveira, O.R., Alves, L.C., Rita, E.M.C., Rodrigues, F., Fialho, P., Pio, C.A., Freitas, M.C., And Soares, J.C.: Comparison of continental Portugal and Azores Islands aerosol during a Sahara dust storm. Nucl. Instrum. Methods Phys. Res. B. 189, 272–278 (2002). doi:10.1016/S0168-583X(01)01056-4

    Article  Google Scholar 

  • Salcedo, R.L.R., Alvim Ferraz, M.C.M., Alves, C.A., Martins, F.G.: Time-series analysis of air pollution data. Atmos. Environ. 33, 2361–2372 (1999). doi:10.1016/S1352-2310(99)80001-6

    Article  Google Scholar 

  • Schauer, J.J., Rogge, W.F., Hildemann, L.M., Mazurek, M.A., Cass, G.R.: Source apportionment of airborne particulate mater using organic compounds as tracers. Atmos. Environ. 30, 3837–3855 (1996). doi:10.1016/1352-2310(96)00085-4

    Article  Google Scholar 

  • Slezakova, K., Pereira, M.C., Reis, M.A., Alvim-Ferraz, M.C.: Influence of traffic emissions on the composition of atmospheric particles of different sizes—part 1: concentrations and elemental characterization. J. Atmos. Chem. 58, 55–68 (2007). doi:10.1007/s10874-007-9078-6

    Article  Google Scholar 

  • Wilson, W.E., Chow, J.C., Claiborn, C., Fusheng, W., Engelbrecht, J., Watson, J.G.: Monitoring of particulate matter outdoors. Chemosphere 49, 1009–1043 (2002). doi:10.1016/S0045-6535(02)00270-9

    Article  Google Scholar 

  • Wrobel, A., Rokita, E., Maenhaut, W.: Transport of traffic-related aerosols in urban areas. Sci. Total Environ. 257, 199–211 (2000). doi:10.1016/S0048-9697(00)00519-2

    Article  Google Scholar 

  • Xie, R.K., Seip, H.M., Leinum, J.R., Winje, T., Xiao, J.S.: Chemical characterization of individual particles (PM10) from ambient air in Guiyang City, China. Sci. Total Environ. 343, 261–272 (2004). doi:10.1016/j.scitotenv.2004.10.012

    Google Scholar 

Download references

Acknowledgments

The authors would like to thank to Professor Arlindo Begonha from Faculty of Engineering, University of Porto for help with identification of some of the particles. The authors are also grateful to Fundação Calouste Gulbenkian and to Fundação para Ciência e Tecnologia SFRH/BD/24228/2005 for the financial support of this work.

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  1. LEPAE, Departamento de Engenharia Química, Faculdade de Engenharia, Universidade do Porto, R. Dr. Roberto Frias, 4200-465, Porto, Portugal

    K. Slezakova, J. C. M. Pires, M. C. Pereira, F. G. Martins & M. C. Alvim-Ferraz

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  1. K. Slezakova
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  2. J. C. M. Pires
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  3. M. C. Pereira
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  4. F. G. Martins
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  5. M. C. Alvim-Ferraz
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Correspondence to M. C. Alvim-Ferraz.

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Slezakova, K., Pires, J.C.M., Pereira, M.C. et al. Influence of traffic emissions on the composition of atmospheric particles of different sizes—Part 2: SEM–EDS characterization. J Atmos Chem 60, 221–236 (2008). https://doi.org/10.1007/s10874-008-9117-y

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