Skip to main content

Advertisement

Log in

High spatial resolution monitoring of benzene and toluene in the Urban Area of Taranto (Italy)

  • Original Article
  • Published:
Journal of Atmospheric Chemistry Aims and scope Submit manuscript

Abstract

Atmospheric concentrations of benzene and toluene were assessed during three different seasons in the city of Taranto, using Radiello® diffusive samplers, in order to detect the most critical areas and to point out the sources contributing to pollution (vehicular traffic or industrial activities). High spatial resolution maps were built using a grid of 30 meshes drawn on the urban area of the city. For each mesh a monitoring site as representative as possible was chosen. Besides, in order to describe the highest levels of pollutants to which people is exposed, other 10 sampling sites were detected near high vehicular traffic crossroads or in particular critical zones of the city. The measurements of the concentration of these pollutants were carried out with Radiello® diffusive samplers for thermal desorption. The analysis of the results and the comparison between the map of vehicular traffic flows and the map of the concentrations of benzene suggested that in urban area the main benzene source is the traffic and the most significant pollution phenomena happens in zones characterized by narrow roads. Moreover it was possible to observe that high concentrations of benzene found in the NE zone of Taranto could be assigned to the industrial activities. This hypothesis was confirmed considering the diagnostic ratio between the toluene and benzene concentrations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Angiuli, L., Bruno, P., Caputi, M., Caselli, M., de Gennaro, G., de Rienzo, M.: Radial passive samplers for air quality monitoring. Comparison in field with a BTEX automatic analyser. Preliminary Results Fresenius Environ. Bull. 12, 1167–1172 (2003)

    Google Scholar 

  • Berkowicz, R., Palmgren, F., Hertel, O., Vignati, E.: Using measurements of air pollution in streets for evaluation of urban air quality– meteorological analysis and model calculation. Sci. Total Environ. 189/190, 259–265 (1996)

    Article  Google Scholar 

  • Bertoni, G., Tappa, R., Allegrini, I.: Assessment of a new passive device for monitoring benzene and other volatile aromatic compounds in the atmosphere. Annali di Chimica 90, 249–263 (2000)

    Google Scholar 

  • Bravo, H., Sosa, R., Sánchez, P., Bueno, E., Gonzáles, L.: Concentrations of benzene and toluene in the atmosphere of the southwestern area at Mexico City Metropolitan Zone. Atmos. Environ. 36, 3843–3849 (2002)

    Article  Google Scholar 

  • Brown, J.R., Field, R.A., Goldstone, M.E., Lester, J.N., Perry, R.: Polycyclic aromatic hydrocarbons in central London air during 1991 and 1992. Sci. Total Environ. 177, 73–84 (1996)

    Article  Google Scholar 

  • Brown, R.H., Wright, M.D., Plant, N.T.: The use of diffusive sampling for monitoring of benzene, toluene and xilenes in ambient air. Pure Appl. Chem. 71, 1993–2008 (1999)

    Article  Google Scholar 

  • Brown, R.H.: Monitoring the ambient environment with diffusive samplers: theory and practical considerations. J. Environ. Monit. 2, 1–9 (2000)

    Article  Google Scholar 

  • Bruno, P., Caputi, M., Caselli, M., de Gennaro G., de Rienzo, M.: Reliability of a BTEX radial diffusive sampler for thermal desorption: field measurements. Atmos. Environ. 39, 1347–1355 (2005)

    Article  Google Scholar 

  • Cocheo, V., Boaretto, C., Sacco, P.: High uptake rate radial diffusive sampler suitable for both solvent and thermal desorption. Am. Ind. Hyg. Assoc. J. 57, 897–904 (1996)

    Google Scholar 

  • De Santis, F., Fino, A., Menichelli, S., Vazzana, C., Allegrini, I.: Monitoring the air quality around an oil refinery through the use of diffusive sampling. Anal. Bioanal. Chem. 378, 782–788 (2004)

    Article  Google Scholar 

  • D.M. 60: Ministerial Decree No. 60 of 02 April 2002 on the subject of ambient air quality assessment and management and laying down for the pollutants sulphur dioxide, nitrogen dioxide, nitrogen oxides, particulate matter, lead, benzene and carbon monoxide (2002)

  • European Union Parliament and Council: Directive 2000/69/CE of the European Parliament and Council of the 16 November 2000 concerning the limit values for benzene and carbon monoxide in environmental air. Off. J. Eur. Commun. L313, 12–21 (2000)

    Google Scholar 

  • European Union Parliament and Council: Directive 2003/17/CE of the European Parliament and Council of the 3 March 2003 concerning the quality of petrol and diesel fuel. Off. J. Eur. Commun. L76, 10–19 (2003)

    Google Scholar 

  • Fernandes, M.B., Brickus, L.S.R., Moreira, J.C., Cardoso, J.N.: Atmospheric BTX and polyaromatic hydrocarbons in Rio de Janeiro. Brazil. Chemosphere 47, 417–425 (2002)

    Article  Google Scholar 

  • Gee, I.L., Sollars, C.J.: Ambient air levels of volatile organic compounds in Latin American and Asian cities. Chemosphere 36, 2497–2506 (1998)

    Article  Google Scholar 

  • Górecki, T., Namieśnik, J.: Passive sampling. Trends Anal. Chem. 21, 276–291 (2002)

    Article  Google Scholar 

  • Hallama, R.A., Rosenberg, E., Grasserbauer, M.: Development and application of a thermal desorption method for the analysis of polar volatile organic compounds in workplace air. J. Chromatogr. A 855, 129–151 (1998)

    Google Scholar 

  • Hartmann, R., Vogt, U., Baumbach, G., Seyfioglu, R., Muezzinoglu, A.: Results of emission and ambient air measurements of VOC in Izmir. Environ. Res. Forum 7–8, 107–112 (1997)

    Google Scholar 

  • Hellén, H., Hakola, H., Laurila, T., Hiltunen, V., Koskentalo, T.: Aromatic hydrocarbon and methyl tert-butyl ether measurements in ambient air of Helsinki (Finland) using diffusive samplers. Sci. Total Environ. 298, 55–64 (2002)

    Article  Google Scholar 

  • Hrelia, P., Maffei, F., Angelini, S., Cantelli Forti, G.: A molecular epidemiological approach to health risk assessment of urban air pollution. Toxicol. Lett. 149, 261–267 (2004)

    Article  Google Scholar 

  • International Agency for Research on Cancer (IARC), IARC.: Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. IARC. Lyon 29, 93–95 (1982)

    Google Scholar 

  • International Agency for Research on Cancer (IARC): Monographs on the evaluation of Carcinogenic risks to Humans. IARC. Lyon 71(II), 401–432 (1999)

    Google Scholar 

  • Krupa, S.V., Legge, A.H.: Passive sampling of ambient, gaseous air pollutants: an assessment from an ecological perspective. Environ. Pollut. 107, 31–45 (2000)

    Article  Google Scholar 

  • Leong, S.T., Laortanakul, P.: Indicators of benzene emissions and exposure in Bangkok street. Environ. Res. 92, 173–181 (2003)

    Article  Google Scholar 

  • Muezzinoglu, A., Odabasi, M., Onat, L.: Volatile organic compounds in the air of Izmir. Turkey. Atmos. Environ. 35, 753–760 (2001)

    Article  Google Scholar 

  • Comune of Taranto.: Servizio di valutazione degli effetti dell'inquinamento atmosferico nell'area Urbana di Taranto. Report no. 1, Comune of Taranto, Taranto, Italy (2003)

  • Pfeffer, H.U., Breuer, L.: BTX measurements with diffusive samplers in the vicinity of a cokery: comparison between ORSA-type samplers and pumped sampling. J. Environ. Monit 2, 483–486 (2000)

    Article  Google Scholar 

  • Roche, A., Thevenet, R., Jacob, V., Kalunzny, P., Ferrari, C., Baussand, P., Foster, P.: Performance of a thermally desorbable type-tube diffusive sampler for very low air concentrations monitoring, Atmos. Environ. 33, 1905–1912 (1999)

    Article  Google Scholar 

  • Park, S., Kim, S., Lee, H.: Dispersion characteristics of vehicle emission in an urban street canyon. Sci. Total Environ. 323, 263–271 (2004)

    Article  Google Scholar 

  • van Aalst, R., Edwards, L., Pulles, T., De Saeger, E., Tombrou, M., Tonnesen, D.: Guidance report on preliminary assessment under EC air quality directives. Technical Report no. 11, European Environment Agency (1998)

  • Vardoulakis, S., Gonzales-Flesca, N., Fisher, B.E.A.: Assessment of traffic-related air pollution in two street canyons in Paris: implication for exposure studies. Atmos. Environ. 36, 1025–1039 (2002)

    Article  Google Scholar 

  • Vardoulakis, S., Fisher, B.E.A., Pericleous, K., Gonzales-Flesca, N.: Modelling air quality in street canyons: a review. Atmos. Environ. 37, 155–182 (2003)

    Article  Google Scholar 

  • Wideqvist, U., Vesely, V., Johansson, C., Potter, A., Brorström-Lundén, E., Sjöberg, K., Jonsson, T.: Comparison of measurement methods for benzene and toluene. Atmos. Environ. 37, 1963–1973 (2003)

    Article  Google Scholar 

  • World Health Organization (WHO): Updating and revision of the Air Quality Guidelines for Europe. Report no. EUR/ICP/EHAZ9405/MT12 (1996)

  • Wright, M.D., Plant, N.T., Brown, R.H.: Diffusive sampling of VOCs as an aid to monitoring urban air quality. Environ. Monit. Assess. 52, 57–64 (1998)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. de Gennaro.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bruno, P., Caselli, M., de Gennaro, G. et al. High spatial resolution monitoring of benzene and toluene in the Urban Area of Taranto (Italy). J Atmos Chem 54, 177–187 (2006). https://doi.org/10.1007/s10874-006-9030-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10874-006-9030-1

Keywords

Navigation