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On the Measurement of PANs by Gas Chromatography and Electron Capture Detection

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Abstract

A fast, automated, gas chromatographic system for the airborne measurement of PAN and a series of its homologues is described and its performance is evaluated. Response factors for PAN, PPN, APAN, PiBN, and MPAN have been determined and are discussed with regard to ECD response and to potential losses in the analytical system. Calibration methods used for these tasks are described and compared. The results from this work should help investigators who are employing the widely used GC/ECD method for the measurement of peroxyacyl nitrates to evaluate peaks of PAN homologues that cannot be calibrated for by using the reported response factors.

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Authors and Affiliations

  1. National Center for Atmospheric Research, P.O. Box 3000, Boulder, CO, 80307, USA

    Frank M. Flocke, Andrew J. Weinheimer & Stephen Shertz

  2. Cooperative Institute for Research in Environmental Sciences, Boulder, CO, USA

    Aaron L. Swanson

  3. NOAA Aeronomy Laboratory, Boulder, CO, USA

    James M. Roberts

  4. Metcon GmbH, Glashütten, Germany

    Rainer Schmitt

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  1. Frank M. Flocke
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  2. Andrew J. Weinheimer
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  3. Aaron L. Swanson
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  4. James M. Roberts
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  5. Rainer Schmitt
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Correspondence to Frank M. Flocke.

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Flocke, F.M., Weinheimer, A.J., Swanson, A.L. et al. On the Measurement of PANs by Gas Chromatography and Electron Capture Detection. J Atmos Chem 52, 19–43 (2005). https://doi.org/10.1007/s10874-005-6772-0

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