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Synthesis and Crystal Structure of Ethylenediammonium bis iodate tetra iodic Acid: [C2H10N2] (IO3)2·4HIO3

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Abstract

The synthesis and crystal structure are presented for the ethylenediammonium bis iodate tetra iodic acid. An X-ray investigation has shown that this compound crystallizes in a centrosymmetric monoclinic system, space group P21/c with the lattice parameters: a = 7.2536(2) Å, b = 18.5351(5) Å, c = 7.5685(2) Å, β = 107.937(1)°, V = 968.10(3) Å3. The structure was solved from 5281 independent reflections with R 1 = 0.0229 and wR 2 = 0.0428, and refined with 156 parameters. The structure is built up of [(CH2)2(NH3)2]2+ cations connected to the one-dimensional [HIO3]n chains and to the [H2I4O12]2− clusters by a weak N–H···O hydrogen bonds.

Graphical Abstract

[100] view of the structure of [C2H10N2] (IO3)2·4HIO3. Hydrogen bonds are represented by broken lines.

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Acknowledgments

The authors thank Dr. Hamdi Basma (Faculté des Sciences de Sfax, Tunisia) for assistance in the X-ray data collection.

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Authors and Affiliations

  1. Unité de Recherche de Chimie Industrielle et Matériaux ENIS, Sfax, Tunisie

    K. Saidi, S. Kamoun & H. F. Ayedi

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  1. K. Saidi
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  2. S. Kamoun
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  3. H. F. Ayedi
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Correspondence to K. Saidi.

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Saidi, K., Kamoun, S. & Ayedi, H.F. Synthesis and Crystal Structure of Ethylenediammonium bis iodate tetra iodic Acid: [C2H10N2] (IO3)2·4HIO3 . J Chem Crystallogr 41, 1258–1261 (2011). https://doi.org/10.1007/s10870-011-0084-9

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  • DOI: https://doi.org/10.1007/s10870-011-0084-9

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