Skip to main content
SpringerLink
Log in

Solvothermal Syntheses and Crystal Structures of Two Thiostannates(IV) [M(tepa)]2(μ-Sn2S6) (M = Fe2+ and Co2+)

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Two new thiostannates [M(tepa)]2(μ-Sn2S6) (tepa = tetraethylenepentamine, M = Fe2+ 1 and Co2+ 2) were prepared by solvothermal method. Compounds 1 and 2 are isostructural. Both the compounds crystallize in the tetragonal system, space group I41/a (no. 88) with the crystal parameters of 1: a = 25.683(2) Å, b = 25.683(2) Å, c = 9.9860(9) Å, V = 6,586.7(11) Å3, Z = 8, and 2: a = 25.742(3) Å, b = 25.742(3) Å, c = 9.8977(12) Å, V = 6,558.5(14) Å3, Z = 8. The Sn2S6 4− anion acts as a bidentate bridging ligand connecting two transition metal complex cations by trans terminal S atoms to form neutral centrosymmetric [M(tepa)]2(μ-Sn2S6) moieties.

Index Abstract

The Sn2S6 4− anion acts as a bidentate bridging ligand connecting two transition metal complex cations by trans terminal S atoms to form neutral centrosymmetric [M(tepa)]2(μ-Sn2S6) moieties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Li JQ, Marler B, Kessler H, Soulard M, Kallus S (1997) Inorg Chem 36:4697

    Article  CAS  Google Scholar 

  2. Dehnen S, Zimmermann C (2002) Z Anorg Allg Chem 628:2463

    Article  CAS  Google Scholar 

  3. Fehlker A, Blachnik R (2001) Z Anorg Allg Chem 627:411

    Article  CAS  Google Scholar 

  4. Campbell J, Devereux LA, Gerken M, Mercier HPA, Pirani AM, Schrobilgen GJ (1996) Inorg Chem 35:2945

    Article  CAS  Google Scholar 

  5. Jiang T, Lough AJ, Ozin GA, Young D (1995) Chem Mater 7:245

    Article  CAS  Google Scholar 

  6. Ko Y, Tan K, Nellis DM, Koch S, Parise JB (1995) J Solid State Chem 114:506

    Article  CAS  Google Scholar 

  7. Jiang T, Lough A, Ozin GA, Bedard RL, Broach R (1998) J Mater Chem 8:721

    Article  CAS  Google Scholar 

  8. Ahari H, Lough A, Petrov S, Ozin GA, Bedard RL (1999) J Mater Chem 9:1263

    Article  CAS  Google Scholar 

  9. Tan K, Ko Y, Parise JB (1995) Acta Cryst C51:398–401

    CAS  Google Scholar 

  10. Pirani AM, Mercier HPA, Dixon DA, Borrmann H, Schrobilgen GJ (2001) Inorg Chem 40:4823

    Article  CAS  Google Scholar 

  11. Parise JB, Ko Y, Tan K, Nellis DM, Koch SJ (1995) Solid State Chem 117:219

    Article  CAS  Google Scholar 

  12. Parise JB, KO Y (1994) Chem Mater 6:719

    Article  Google Scholar 

  13. Zheng NF, Bu XH, Wang B, Feng PY (2002) Science 298:2366

    Article  CAS  Google Scholar 

  14. Zimmermann C, Anson CE, Weigend F, Clérac R, Dehnen S (2005) Inorg Chem 44:5686

    Article  CAS  Google Scholar 

  15. Ruzin E, Dehnen S (2006) Z Anorg Allg Chem 632:749

    Article  CAS  Google Scholar 

  16. Zimmermann C, Melullis M, Dehnen S (2002) Angew Chem Int Ed 41:4269

    Article  CAS  Google Scholar 

  17. Brandmayer MK, Clérac R, Weigend F, Dehnen S (2004) Chem Eur J 10:5147

    Article  CAS  Google Scholar 

  18. Dehnen S, Brandmayer MK (2003) J Am Chem Soc 125:6618

    Article  CAS  Google Scholar 

  19. Melullis M, Zimmermann C, Anson CE, Dehnen SZ (2003) Anorg Allg Chem 629:2325

    Article  CAS  Google Scholar 

  20. Jia DX, Zhang Y, Dai J, Zhu QY, Gu XM (2004) Z Anorg Allg Chem 630:313

    Article  CAS  Google Scholar 

  21. Jia DX, Dai J, Zhu QY, Zhang Y, Gu XM (2004) Polyhedron 23:937

    Article  CAS  Google Scholar 

  22. Behrens M, Scherb S, Nather C, Bensch WZ (2003) Anorg Allg Chem 629:1367

    Article  CAS  Google Scholar 

  23. Fu ML, Guo GC, Liu B, Wu AQ (2005) Chin J Inorg Chem 21:25

    Google Scholar 

  24. Chen Z, Wang RJ (1999) Acta Phys Chimi Sin 15:1070

    CAS  Google Scholar 

  25. Gu XM, Dai J, Jia DX, Zhang Y, Zhu QY (2005) Cryst Growth Des 5:1845

    Article  CAS  Google Scholar 

  26. Zhou J, Bian G-Q, Dai J, Zhang Y, Tang A-B, Zhu Q-Y (2007) Inorg Chem 46:1541

    Article  CAS  Google Scholar 

  27. Zhou J, Zhang Y, Tang A-B, Bian G-Q, Jia D-X, Dai J (2007) Inorg Chem Commun 10:348

    Article  Google Scholar 

  28. Wendlandt WW, Hecht HG (1966) Reflectance spectroscopy. Interscience Publishers, New York

    Google Scholar 

  29. Sheldrick GM (1997) SHELXS 97, program for crystal structure determinations. University of Göttingen, Germany

    Google Scholar 

  30. Sheldrick GM (1997) SHELXL 97, program for crystal structure refinements. University of Göttingen, Germany

    Google Scholar 

  31. Lees RJE, Powell AV, Chippindale AM (2005) Polyhedron 24:1941

    Article  CAS  Google Scholar 

  32. Kiebacha R, Benscha W, Hoffmannb R, Pöttgenb RZ (2003) Anorg Allg Chem 629:532

    Article  Google Scholar 

  33. Garden SJ, Pinto AC, Wardell JL, Low JN, Glidewell C (2006) Acta Cryst C62:321

    Google Scholar 

  34. Palchik O, Iyer RG, Liao JH, Kanatzidis MG (2003) Inorg Chem 42:5052

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by National Natural Science Foundation (Grant 20971092), and by the Program of Innovative Research Team of Soochow University.

Author information

Authors and Affiliations

  1. Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, 215123, Suzhou, People’s Republic of China

    Yong Zhang, Ai-Bin Tang, Guo-Qing Bian & Jie Dai

  2. Department of Chemistry and Biology, Yulin Normal University, 537000, Yulin, People’s Republic of China

    Jian Zhou

  3. Department of Chemistry, Soochow University, Suzhou Industrial Park, DuShu Lake Campus, 215123, Suzhou, People’s Republic of China

    Jie Dai

Authors
  1. Yong Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jian Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ai-Bin Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guo-Qing Bian
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jie Dai
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jie Dai.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Y., Zhou, J., Tang, AB. et al. Solvothermal Syntheses and Crystal Structures of Two Thiostannates(IV) [M(tepa)]2(μ-Sn2S6) (M = Fe2+ and Co2+). J Chem Crystallogr 40, 496–500 (2010). https://doi.org/10.1007/s10870-009-9684-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-009-9684-z

Keywords

Search

Navigation