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Synthesis and crystal structure of a one-dimensional chain copper benzoylacetonate complex bridged through trans-1,2-bis(4-pyridyl)ethene ligand

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Abstract

The copper complex [Cu(bzac)2(bpee)]⋅H2O (1) (bzac = benzoylacetonate, bpee = trans-1, 2-bis(4-pyridyl)ethylene) has been synthesized and structurally characterized by X-ray diffraction analysis. It crystallizes in the orthorhombic space group C2221, a = 18.348(4) Å, b = 19.657(4) Å, c = 15.490(3) Å, V = 5586.9(19) Å3, Z = 8. In the crystal of complex 1, the copper atoms have distorted octahedral geometry with four shorter and two longer bonds defined by two nitrogen donors from two trans-1,2-bis(4-pyridyl)ethene (bpee) ligands and four oxygen donors from two benzoylacetonate (bzac) chelating ligands. The compound possesses a one-dimensional linear chain structure with copper ions linked through the rod-like bpee ligands.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, the Key Laboratory of the Organic Synthesis of Jiangsu Province, Suzhou University, Suzhou, 215006, P.R. China

    Baolong Li, Jianping Lang, Shouwu Wang & Yong Zhang

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  1. Baolong Li
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  2. Jianping Lang
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  3. Shouwu Wang
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  4. Yong Zhang
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Correspondence to Baolong Li.

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Li, B., Lang, J., Wang, S. et al. Synthesis and crystal structure of a one-dimensional chain copper benzoylacetonate complex bridged through trans-1,2-bis(4-pyridyl)ethene ligand. J Chem Crystallogr 35, 547–550 (2005). https://doi.org/10.1007/s10870-005-5380-9

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  • DOI: https://doi.org/10.1007/s10870-005-5380-9

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