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Synthesis and crystal structure of 5-allyl-5Hdibenzo[b,f]azepine

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Abstract

The crystals 5H-dibenzo[b,f]azepine 2 and 5-allyl-5H-dibenzo[b,f]azepine 3 were synthesized and characterized by X-ray crystallography. The compound 3 is a novel synthon for the construction of unusual isoxazoli(ne)dine rings bearing at the 5th position of dibenzo[b,f]azepine moiety. The compound 2 (C14H11N) crystallizes in the orthorhombic space group P212121 with the parameters a = 6.036(1) Å, b = 8.250(7) Å, c = 20.528(4) Å, Z = 4 and the final R factor is R1 = 0.0544. The compound 3 (C17H15N) crystallizes in the Hexagonal space group P61 with the parameters a = 11.043(9) Å, c = 18.575 Å, Z = 6 and the final R factor is R1 = 0.0373.

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Authors and Affiliations

  1. Department of Studies in Chemistry, University of Mysore, Mysore, 570 006, India

    M.P. Sadashiva,  Basappa & K.S. Rangappa

  2. Department of Studies in Physics, University of Mysore, Mysore, 570 006, India

    B.H. Doreswamy, M.A. Sridhar & J. Shashidhara Prasad

Authors
  1. M.P. Sadashiva
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  2. B.H. Doreswamy
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  3. Basappa
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  4. K.S. Rangappa
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  5. M.A. Sridhar
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  6. J. Shashidhara Prasad
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Correspondence to K.S. Rangappa.

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Sadashiva, M., Doreswamy, B., Basappa et al. Synthesis and crystal structure of 5-allyl-5Hdibenzo[b,f]azepine. J Chem Crystallogr 35, 171–175 (2005). https://doi.org/10.1007/s10870-005-2953-6

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  • DOI: https://doi.org/10.1007/s10870-005-2953-6

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