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Preparation and multifaceted characterization and optoelectronic potential of Cu/CuO/Cu2O nanoplates in a PVC/PE matrix

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Abstract

In this study, we thoroughly investigate the physicochemical properties of Cu/CuO/Cu2O nanoplates synthesized in distinct plate-like structures. These nanoplates were incorporated into a polymer matrix (PVC/PE) at varying concentrations (0, 1, 2, and 3%). Employing various analytical techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), optical absorption, and alternating current (AC) conductivity measurements, we unravel the structural, morphological, molecular, optical, and electrical characteristics of these nanostructures. The results showcase the potential of these nanocomposites for optoelectronic device applications by exhibiting tunable optical bandgaps and frequency-dependent dielectric properties. In particular, the observed redshift in the absorption spectrum and modulation of the direct bandgap with increasing nanoplate content underscores their application in spectral selectivity and light harvesting. Furthermore, the transition from insulating to conducting behavior upon percolation signifies their utility in transparent conductive coatings. This study provides fundamental insights into the structure–property relationships of Cu/CuO/Cu2O nanoplate polymer nanocomposites for tailored optoelectronic applications.

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Funding

The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University, Arar, KSA for funding this research work through the project number NBU-FFR-2023-0149.

Author information

Authors and Affiliations

  1. Department of Chemistry, College of Science, Northern Border University (NBU), Arar, Saudi Arabia

    A. M. Elbasiony

  2. Physical Chemistry Department, Electrochemistry and Corrosion Laboratory, National Research Centre, El Bohoth St. 33 Dokki, Giza, Egypt

    A. M. Elbasiony

  3. Radiation Research of Polymer Chemistry Department, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority (EAEA), Cairo, Egypt

    Mohamed Mohamady Ghobashy

  4. College of Science and Humanities- Jubail, Imam Abdulrahman Bin Faisal University, Jubail, Saudi Arabia

    Dalal Mohamed Alshangiti & Mohamed Madani

  5. Charged Particles Lab, Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority (EAEA), Cairo, Egypt

    M. M. Abdelhamied

  6. NANOTECH Center, Ural Federal University, Ekaterinburg, Russia, 620002

    A. M. A. Henaish

  7. Physics Department, Faculty of Science, Tanta University, Tanta, 31527, Egypt

    A. M. A. Henaish

  8. Solid State and Accelerator Department, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority (EAEA), Cairo, Egypt

    A. I. Sharshir

Authors
  1. A. M. Elbasiony
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  2. Mohamed Mohamady Ghobashy
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  3. Dalal Mohamed Alshangiti
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  5. M. M. Abdelhamied
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All authors shared equally in writing the manuscript and accepted the responsibility of the entire contents of this manuscript and approved the submission.

Corresponding author

Correspondence to A. I. Sharshir.

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Research data policy

The authors stated that all data exist and are available. CRediT authorship contribution statement A.M. Elbasiony: Funding acquisition, Supervision, Writing – orig- inal draft. A.I. Sharshir: Data curation, Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review & editing, Visualization. Mohamed Mohamady Ghobashy: Visualization. Dalal Mohamed Alshan- giti: Investigation, Supervision. Mohamed Madani: Supervision, Visualization.A.M.A. Henaish: Supervision. M.M. Abdelhamied: Methodology, Supervision.UV Vis spectroscopy measurement.

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Elbasiony, A.M., Ghobashy, M.M., Alshangiti, D.M. et al. Preparation and multifaceted characterization and optoelectronic potential of Cu/CuO/Cu2O nanoplates in a PVC/PE matrix. J Mater Sci: Mater Electron 35, 194 (2024). https://doi.org/10.1007/s10854-023-11915-4

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