Skip to main content
SpringerLink
Log in

Synergy improvement of dielectric properties and thermal conductivity in PVDF composites with core‐shell structured Ni@SiO2

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Developing a high dielectric constant (εr) polymer dielectrics with low dielectric loss and high thermal conductivity (TC) is still continuous demands for advanced electrical power systems. Herein, nickel (Ni) particles were encapsulated by silica (SiO2) via a sol–gel process using sodium silicate as a precursor, and the obtained core–shell Ni@SiO2 powders were blended into poly(vinylidene fluoride) (PVDF) to investigate the effects of SiO2 insulating layer and its thickness on dielectric properties and TC of composites. Compared with pristine Ni, the Ni@SiO2/PVDF composites exhibit a superior εr, and remarkably suppressed loss and conductivity, attributable to the SiO2 interlayer between the core Ni particles which effectively prevents them from direct contacts and significantly reduces the leakage loss. Moreover, the Ni@SiO2/PVDF composites still possess a high TC owing to the restrained thermal interfacial resistance and enhanced interfacial compatibility between the fillers and the matrix. The developed Ni@SiO2/PVDF composites with high k and TC but low loss are potential for microelectronic industry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. X.T. Zhu, J. Yang, D. Dastan, H. Garmestani, R.H. Fan, Z.C. Shi, Compos. A Appl. Sci. Manuf. 125, 105521 (2019)

    Article  CAS  Google Scholar 

  2. J.W. Zha, S.C. Yao, Y. Qiu, M.S. Zheng, Z.M. Dang, IET Nanodielectr. 2(3), 103–108 (2019)

    Article  Google Scholar 

  3. L.H. Zhao, L. Yan, C.M. Wei, Q.H. Li, X.L. Huang, Z.L. Wang, M.L. Fu, J.W. Ren, J. Phys. Chem. C 124, 12723–12733 (2020)

    Article  CAS  Google Scholar 

  4. P. Wang, W.D. Wei, Z.Q. Li, W. Duan, H.L. Hana, Q. Xie, J. Mater. Chem. A 8(6), 3509–3516 (2020)

    Article  CAS  Google Scholar 

  5. J.C. Ma, U. Azhar, C.Y. Zong, Y.B. Zhang, A.H. Xu, C.C. Zhai, L.Q. Zhang, S.X. Zhang, Mater. Des. 164, 107556 (2019)

    Article  CAS  Google Scholar 

  6. Z.D. Wang, Y.H. Cheng, M.M. Yang, J.L. Huang, D.X. Cao, S.Y. Chen, Q. Xie, W.X. Lou, H.J. Wu, Compos. B Eng. . 140, 83–90 (2018)

    Article  CAS  Google Scholar 

  7. M.S. Zheng, C. Zhang, Y. Yang, Z.L. Xing, X. Chen, S.L. Zhong, Z.M. Dang, IET Nanodielectr. 3(3), 94–98 (2020)

    Article  Google Scholar 

  8. W.Y. Zhou, F. Zhang, M.X. Yuan, B. Li, J.D. Peng, Y.Q. Lv, H.W. Cai, X.R. Liu, Q.G. Chen, Z.M. Dang, Mater. Electron. 30(20), 18350–18361 (2019)

    Article  CAS  Google Scholar 

  9. Z.H. Yao, Z. Song, H. Hao, Z.Y. Yu, M.H. Cao, S.J. Zhang, M.T. Lanagan, H.X. Liu, Adv. Mater. 29(20), 1601727 (2017)

    Article  Google Scholar 

  10. V.K. Prateek, R.K. Thakur, Gupta, Chem. Rev. 116(7), 4260–4317 (2016)

    Article  CAS  Google Scholar 

  11. D.L. He, Y. Wang, S.L. Song, S. Liu, Y. Deng, ACS Appl. Mater. Interfaces 9(51), 44839–44846 (2017)

    Article  CAS  Google Scholar 

  12. Z.M. Dang, J.K. Yuan, J.W. Zha, T. Zhou, S.T. Li, G.H. Hu, Progress Mater. Sci. 57(4), 660–723 (2012)

    Article  CAS  Google Scholar 

  13. Y.C. Jiang, J.B. Wang, Q.L. Zhang, H. Yang, D. Shen, F.M. Zhou, Colloids Surf. A 576, 55–62 (2019)

    Article  CAS  Google Scholar 

  14. S.L. Zhong, Z.M. Dang, W.Y. Zhou, H.W. Cai, IET Nanodielectr. 1(1), 41–47 (2018)

    Article  Google Scholar 

  15. M.X. Yuan, G. Zhang, B. Li, T.C. Mike Chung, R. Rajagopalan, M.T. Lanagan, ACS Appl. Mater. Interfaces 12(12), 14154–14164 (2020)

    Article  CAS  Google Scholar 

  16. M.X. Yuan, B. Li, S.H. Zhang, R. Rajagopalan, M.T. Lanagan, ACS Appl. Polym. Mater. 2(3), 1356–1368 (2020)

    Article  CAS  Google Scholar 

  17. Y.C. Jiang, Z. Zhang, Z. Zhou, H. Yang, Q.L. Zhang, Polymers 11, 1541 (2019)

    Article  CAS  Google Scholar 

  18. T. Hu, J. Juuti, H.L. Jantunen, T. Vilkman, J. Eur. Ceram. Soc. 27(13–15), 3997–4001 (2007)

    Article  CAS  Google Scholar 

  19. K. Meeporn, P. Thongbai, Appl. Surf. Sci. 481, 1160–1166 (2019)

    Article  CAS  Google Scholar 

  20. Q.P. Zhang, W.F. Zhu, D.M. Liang, X.L. Wu, R.C. Chen, N. Sun, Y.T. Li, Y.L. Zhou, Appl. Surf. Sci. 487, 77–81 (2019)

    Article  CAS  Google Scholar 

  21. W.Y. Zhou, Y. Gong, L.T. Tu, L. Xu, W. Zhao, J.T. Cai, Y.T. Zhang, A.N. Zhou, J. Alloys Compd. 693, 1–8 (2017)

    Article  CAS  Google Scholar 

  22. T. Huang, C.G. Ma, P.B. Dai, J. Zhang, Compos. Sci. Technol. 176, 46–53 (2019)

    Article  CAS  Google Scholar 

  23. G.L. Wu, Y.H. Cheng, Y.Y. Ren, Y.Q. Wang, Z.D. Wang, H.J. Wu, J. Alloys Compd. 652, 346–350 (2015)

    Article  CAS  Google Scholar 

  24. A.S. Zeraati, M. ArjmandOrcid, U. Sundararaj, ACS Appl. Mater. Interfaces 9(16), 14328–14336 (2017)

    Article  CAS  Google Scholar 

  25. S.H. Liu, J. Wang, H.S. Hao, L.M. Zhao, J.W. Zhai, Ceram. Int. 44, 22850–22855 (2018)

    Article  CAS  Google Scholar 

  26. F. Liang, L. Zhang, W.Z. Lu, Q.X. Wan, G.F. Fan, Appl. Phys. Lett. 108, 072902 (2016)

    Article  Google Scholar 

  27. G.F. Liu, Y. Chen, M.J. Gong, X.Y. Liu, Z.K. Cui, Q.B. Pei, J.L. Gu, C. Huang, Q.X. Zhuang, J. Mater. Chem. C 6, 10829–10837 (2018)

    Article  CAS  Google Scholar 

  28. L. Hu, Y.T. Xia, Q.Q. Wang, H.Y. Yang, Q.L. Zhang, J. Mater. Sci. Mater. Electron. 29, 1269–1279 (2017)

    Article  Google Scholar 

  29. S. Kargar, D. Elhamifar, A. Zarnegaryan, J. Phys. Chem. Solids. 146, 109601 (2020)

    Article  CAS  Google Scholar 

  30. L. Weng, X.M. Wang, X.R. Zhang, L.Z. Guan, L.Z. Liu, H.X. Zhang, W.W. Cui, Polym. Compos. 41(6), 2245–2253 (2020)

    Article  CAS  Google Scholar 

  31. W.Y. Zhou, L. Xu, L.Y. Jiang, J.D. Peng, Y. Gong, X.R. Liu, H.W. Cai, G.H. Wang, Q.G. Chen, J. Alloys Compd. 710, 47–56 (2017)

    Article  CAS  Google Scholar 

  32. D.E. Abulyazied, H.M. Abomostafa, G.M. El komy. J. Inorg. Organometall. Polym. Mater. 30, 2335–2346 (2020)

    Article  CAS  Google Scholar 

  33. M. Panda, V. Srinivasa, A.K. Thakur, Appl. Phys. Lett. 92(13), 3804 (2008)

    Article  Google Scholar 

  34. L. Xu, W.Y. Zhou, B. Li, Y.J. Kou, H.W. Cai, F.X. Chen, G.H. Wang, D.F. Liu, Z.M. Dang, J. Elastomers Plast. 52(4), 304–321 (2020)

    Article  CAS  Google Scholar 

  35. Y. Zhou, S. Chen, D. Wu, L.H. Liu, H. L, D. Zhang, Compos. Commun. 16, 11–19 (2019)

    Article  Google Scholar 

  36. Y. Tong, H. Talebinezhad, X. Lu, Z.Y. Cheng, C. Hill, D. Tucker, IET Nanodielectr. 2(1), 41–47 (2019)

    Article  Google Scholar 

  37. V.P. Anju, S.K. Narayanankutty, Mater. Sci. Eng. B 249, 114418 (2019)

    Article  CAS  Google Scholar 

  38. Z.H. Chen, H.F. Li, G.Y. Xie, K. Yang, RSC Adv. 8(1), 1–9 (2018)

    Article  Google Scholar 

  39. W.Y. Zhou, X. Li, F. Zhang, C.H. Zhang, Z. Li, F.X. Chen, H.W. Cai, X.R. Liu, Q.G. Chen, Z.M. Dang, Compos. A Appl. Sci. Manuf. 137, 106021 (2020)

    Article  CAS  Google Scholar 

  40. W.Y. Zhou, Q.G. Chen, X.Z. Sui, L.N. Dong, Z.J. Wang, Compos. A Appl. Sci. Manuf. 71, 184–191 (2015)

    Article  CAS  Google Scholar 

  41. S.A. Mirkhani, A.S. Zeraati, E. Aliabadian, M. Naguib, U. Sundararaj, ACS Appl. Mater. Interfaces 11(20), 18599–18608 (2019)

    Article  CAS  Google Scholar 

  42. Z.B. Pan, L.M. Yao, J.J. Liu, X.Y. Liu, F.P. Pi, J.W. Chen, B. Shen, J.W. Zhai, J. Mater. Chem. C 7(2), 405–413 (2019)

    Article  CAS  Google Scholar 

  43. S.Y. Chen, Y.H. Cheng, Q. Xie, B. Xiao, Z.D. Wang, J.Y. Liu, Composites Part A 120, 84–94 (2019)

    Article  CAS  Google Scholar 

  44. B. Li, F. Salcedo-GalanFelipe, P.I. Xidas, E. Manias, ACS Appl. Nano Mater. 1(9), 4401–4407 (2018)

    Article  CAS  Google Scholar 

  45. Y. Zhang, C.H. Zhang, Y. Feng, T.D. Zhang, Q.G. Chen, Q.G. Chi, L.Z. Liu, X. Wang, Q.Q. Lei, Nano Energy 66, 104195 (2019)

    Article  CAS  Google Scholar 

  46. W.Y. Zhou, Y. Zhang, J.J. Wang, H. Li, W.H. Xu, B. Li, L.Q. Chen, Q. Wang, ACS Appl. Mater. Interfaces 12, 46767–46778 (2020)

    Article  CAS  Google Scholar 

  47. J.W. Ren, Q.H. Li, L. Yan, L.C. Jia, X.L. Huang, L.H. Zhao, Q.C. Ran, M.L. Fu, Mater. Des. 191, 108663 (2020)

    Article  CAS  Google Scholar 

  48. L.H. Zhao, L. Yan, C.M. Wei, Q.H. Li, X.L. Huang, Z.L. Wang, M.L. Fu, J.W. Ren, J. Phys. Chem. C 124(23), 12723–12733 (2020)

    Article  CAS  Google Scholar 

  49. Z.M. Shen, J.C. Feng, Compos. Sci. Technol. 170, 135–140 (2019)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the financial supports from the National Natural Science Foundation of China (Nos. 51937007, 51577154), and acknowledges the Analytic Instrumentation Center of XUST.

Funding

All authors certify that they have no affiliations with or involvement in any organization or entity with any financial interest or non-financial interest in the subject matter or materials discussed in this manuscript.

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Xi’an University of Science & Technology, Xi’an, 710054, China

    Ting Li, Wenying Zhou, Dan Cao, Yun Wang, Guozheng Cao, Xiangrong Liu, Huiwu Cai & Zhi-Min Dang

  2. College of Material Science and Engineering, Xi’an University of Science & Technology, Xi’an, 710054, China

    Ying Li

  3. State Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing, 100084, China

    Zhi-Min Dang

Authors
  1. Ting Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wenying Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ying Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dan Cao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Guozheng Cao
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Xiangrong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Huiwu Cai
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Zhi-Min Dang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Wenying Zhou or Zhi-Min Dang.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, T., Zhou, W., Li, Y. et al. Synergy improvement of dielectric properties and thermal conductivity in PVDF composites with core‐shell structured Ni@SiO2. J Mater Sci: Mater Electron 32, 4076–4089 (2021). https://doi.org/10.1007/s10854-020-05149-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-020-05149-x

Search

Navigation