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BaSrLaFe12O19 nanorods: optical and magnetic properties

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Abstract

In this work, the Ba0.2Sr0.8−yLayFe12O19 (y = 0.2, 0.4, 0.6 & 0.8) (BSLFO) nanorods were prepared using hydrothermal method. The hexagonal structure and nanorod formation were evidenced by X-ray diffraction patterns and micrographs, respectively. Further, the optical and magnetic properties of the BSLFO nanorods were investigated. Using the UV–Visible spectra of y = 0.2–0.8 contents, the optical bandgap (Eg) was determined. The Eg was increased from 3.502 to 3.714 eV as a function of La content. The Raman modes were detected using the Raman spectra for confirming the hexagonal structure of x = 0.2–0.8. The magnetic hysteresis curve indicated the decreasing trend of saturation magnetization (Ms) from 14.44 ± 0.507 to 4.15 ± 0.162 emu/g with ‘y’. This was determined using the law of approach to saturation (LAS) method. In addition, the magnetic permeability versus temperature (μ′-T) plots showed the decreasing nature of magnetic Curie transition temperature (Tc) from 753 to 703 K with increase of La content. Furthermore, the frequency dependence of magnetic permeability (μ′), magnetic loss (μ″) and relative magnetic loss (rlf: tanδ/μ′) was studied for all samples.

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Acknowledgements

The authors express thankful to Prof. T. Subba Rao, Dept. of Physics, SKU, ATP, for their support towards this work. The authors express thankfulness to Dr. P. Sreeramulu, Assistant Professor (English), GITAM, Bangalore for providing English language editing services to this manuscript.

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Authors and Affiliations

  1. Department of Physics, Sri Krishnadevaraya University, Anantapuramu, A.P, 515003, India

    N. Raghuram & T. Subba Rao

  2. Department of Physics, JNTUA, Anantapuramu, A.P, 515002, India

    N. Suresh Kumar

  3. Department of Physics, GITAM Deemed to be University, Bangalore, Karnataka, 562163, India

    K. Chandra Babu Naidu

  4. Department of Chemistry, GITAM Deemed to be University, Bangalore, Karnataka, 562163, India

    H. Manjunatha & B. Ramakrishna Rao

  5. Department of Chemistry, King Abdulaziz University, Jeddah, 21589, Saudi Arabia

    Anish Khan & Abdullah M. Asiri

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Raghuram, N., Rao, T.S., Kumar, N.S. et al. BaSrLaFe12O19 nanorods: optical and magnetic properties. J Mater Sci: Mater Electron 31, 8022–8032 (2020). https://doi.org/10.1007/s10854-020-03342-6

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