Skip to main content
SpringerLink
Log in

Preparation of Co2TiO4/CoTiO3/Polyaniline ternary nano-hybrids for enhanced destruction of agriculture poison and organic dyes under visible-light irradiation

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Co2TiO4/CoTiO3/Polyaniline ternary nano-hybrids were fabricated via sol–gel method and new gelling agent. The varied preparation factors like the type of calcination temperature, solvent and gelling agent were studied through the dimension and morphologies of final products. The photocatalytic activity of the Co2TiO4/CoTiO3/Polyaniline was verified via destruction of changing pollution like as diazinon, methylene blue, eosin Y, methyl orange, and phenol red. The maximum percentage of destruction of organic pollutions was found to be for diazinon (98.3%). The BET analysis demonstrated that the preparation of nano-hybrids in both of presence valine and of phenylalanine can increase surface from 1.05 m2/g to 13.50 m2/g. The obtained ternary nano-hybrids were characterized through EDX, TEM, XRD, DRS, VSM, SEM, and FT-IR.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Scheme 3
Fig. 5
Scheme 4
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. A. Ibhadon, P. Fitzpatrick, Heterogeneous photocatalysis: recent advances and applications. Catalysts 3(1), 189–218 (2013)

    Article  CAS  Google Scholar 

  2. D.W. Bahnemann, C. Kormann, M.R. Hoffmann, Preparation and characterization of quantum size zinc oxide: a detailed spectroscopic study. J. Phys. Chem. 91(14), 3789–3798 (1987)

    Article  CAS  Google Scholar 

  3. A. SobhaniNasab, S. Pourmasoud, F. Ahmadi, M. Wysokowski, T. Jesionowski, H. Ehrlich, M. Rahimi-Nasrabadi, Mater. Lett. 238, 159–162 (2019)

    Article  CAS  Google Scholar 

  4. T. Ivetić et al., Investigation of zinc stannate synthesis using photoacoustic spectroscopy. Sci. Sinter. 39(2), 153–160 (2007)

    Article  Google Scholar 

  5. S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, J. Mater. Sci.: Mater. El 27, 3240 (2016)

    CAS  Google Scholar 

  6. S.M. Peymani-Motlagh, A. Sobhani-Nasab, M. Rostami, H. Sobati, M. Eghbali-Arani, M. Fasihi-Ramandi, M.R. Ganjali, M. Rahimi-Nasrabadi, J. Mater. Sci.: Mater. El 30(7), 6902–6909 (2019)

    CAS  Google Scholar 

  7. A. Sobhani-Nasab, M. Behpour, J. Mater. Sci.: Mater. El 27(11), 11946–11951 (2016)

    CAS  Google Scholar 

  8. X. Chen, C. Burda, J. Am. Chem. Soc. 130(15), 5018–5019 (2008)

    Article  CAS  Google Scholar 

  9. O. Vigil et al., Transparent conducting oxides as selective filters in thermophotovoltaic devices. J. Phys. 17(41), 6377 (2005)

    CAS  Google Scholar 

  10. S.M. Hosseinpour-Mashkani, M. Ramezani, A. Sobhani-Nasab, M. Esmaeili-Zare, J. Mater. Sci.: Mater. El 26(8), 6086–6091 (2015)

    CAS  Google Scholar 

  11. M. Salavati-Niasari, F. Soofivand, A. Sobhani-Nasab, M. Shakouri-Arani, M. Hamadanian, S. Bagheri, J. Mater. Sci.: Mater. El 28(20), 14965 (2017)

    CAS  Google Scholar 

  12. S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, M. Mehrzad, J. Mater. Sci.: Mater. El 27(6), 5758 (2016)

    CAS  Google Scholar 

  13. S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, J. Mater. Sci.: Mater. El 27(7), 7548 (2016)

    CAS  Google Scholar 

  14. F. Ahmadi, M. Rahimi-Nasrabadi, M. Behpour, J. Mater. Sci.: Mater. El 28, 1531–1536 (2017)

    CAS  Google Scholar 

  15. M. Rostami, M. Rahimi-Nasrabadi, M.R. Ganjali, F. Ahmadi, A. Fallah Shojaei, M. Delavar Rafiee, J. Mater. Sci.: Mater. El 52, 7008–7016 (2017)

    Article  CAS  Google Scholar 

  16. M. Rahimi-Nasrabadi, F. Ahmadi, M. Eghbali-Arani, J. Mater. Sci.: Mater. El 27, 13294–13299 (2016)

    CAS  Google Scholar 

  17. M. Rahimi-Nasrabadi, M. Behpour, A. Sobhani-Nasab, M. Rangraz Jeddy, J. Mater. Sci.: Mater. El 27, 11691 (2016)

    CAS  Google Scholar 

  18. M. Rahimi-Nasrabadi, M. Behpour, A. Sobhani-Nasab, S.M. Hosseinpour-Mashkani, J. Mater. Sci.: Mater. El 26, 9776 (2015)

    CAS  Google Scholar 

  19. S. Ahmed et al., J. Environ. Manage. 92(3), 311–330 (2011)

    Article  CAS  Google Scholar 

  20. Y. Zhang et al., Destruction of diazinon in apple juice by ultrasonic treatment. Ultrason. Sonochem. 17(4), 662–668 (2010)

    Article  CAS  Google Scholar 

  21. R.D.C. Soltani et al., J. Ind. Eng. Chem. 20(4), 1861–1868 (2014)

    Article  CAS  Google Scholar 

  22. M. Ramezani, S.M. Hosseinpour-Mashkani, J. Electron. Mater. 46(2), 1371–1377 (2017)

    Article  CAS  Google Scholar 

  23. S. Khanahmadzadeh et al., Mater. Sci. Semicond. Process. 31, 599–603 (2015)

    Article  CAS  Google Scholar 

  24. A. Sobhani-Nasab et al., J. Clust. Sci. 26(4), 1305–1318 (2015)

    Article  CAS  Google Scholar 

  25. S.M. Asgarian, S. Pourmasoud, Z. Kargar, A. Sobhani-Nasab, M. Eghbali-Arani, Mater. Res. Express 6(1), 015023 (2018)

    Article  CAS  Google Scholar 

  26. M. Maddahfar, M. Ramezani, M. Sadeghi, A. Sobhani-Nasab, J. Mater. Sci.: Mater. El 26(10), 7745–7750 (2015)

    CAS  Google Scholar 

  27. M. Ramezani, A. Sobhani-Nasab, S.M. Hosseinpour-Mashkani, J. Mater. Sci.: Mater. El 26, 4848 (2015)

    CAS  Google Scholar 

  28. M. Eghbali-Arani, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, S. Pourmasoud, J. Electron. Mater. 47(7), 3757 (2018)

    Article  CAS  Google Scholar 

  29. S.S. Hosseinpour-Mashkani, A. Sobhani-Nasab, J. Mater. Sci.: Mater. El 28, 16459 (2017)

    CAS  Google Scholar 

  30. A. Khoshroo, L. Hosseinzadeh, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, H. Ehrlich, J. Electroanal. Chem. 823, 61–66 (2018)

    Article  CAS  Google Scholar 

  31. Ortega-Zarzosa, G., et al., J. Sol-Gel. Sci. Technol. 24(1): 23–29 (2002)

    Article  CAS  Google Scholar 

  32. J. Cheng et al., RSC Adv. 4(15), 7627–7633 (2014)

    Article  CAS  Google Scholar 

  33. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, S. Afr. J. Chem. 70, 44–48 (2017)

    CAS  Google Scholar 

  34. M. Salavati-Niasari et al., J. Mater. Sci.: Mater. El 28(20), 14965–14973 (2017)

    CAS  Google Scholar 

  35. M.T. Taghizadeh, F.N.B. Kheljan, M. Vatanparast, J. Mater. Sci.: Mater. El 29(2), 978–984 (2018)

    CAS  Google Scholar 

  36. A. Sobhani-Nasab et al., Ultrason. Sonochem. 50, 46–58 (2019)

    Article  CAS  Google Scholar 

  37. A. Kadam et al., J. Photochem. Photobiol., B 154, 24–33 (2016)

    Article  CAS  Google Scholar 

  38. S.-Q. Liu, Environ. Chem. Lett. 10(3), 209–216 (2012)

    Article  CAS  Google Scholar 

  39. H. Kooshki et al., Sep. Purif. Technol. 211, 873–881 (2019)

    Article  CAS  Google Scholar 

  40. A. Sobhani-Nasab, M. Behpour, J. Mater. Sci.: Mater. El 27(11), 11946 (2016)

    CAS  Google Scholar 

  41. Ali Sobhani-Nasab, M. Behpour, J. Mater. Sci.: Mater. El 27, 1191 (2016)

    CAS  Google Scholar 

  42. M. Maddahfar, M. Ramezani, M. Sadeghi, A. Sobhani-Nasab, J. Mater. Sci.: Mater. El 26, 7745 (2015)

    CAS  Google Scholar 

  43. F. Sedighi, M. Esmaeili-Zare, A. Sobhani-Nasab, M. Behpour, J. Mater. Sci.: Mater. El 29, 13737 (2018)

    CAS  Google Scholar 

  44. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, J. Electron. Mater. 45(7), 3612–3620 (2016)

    Article  CAS  Google Scholar 

  45. M. Ramezani, S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, H.G. Estarki, J. Mater. Sci.: Mater. El 26(10), 7588 (2015)

    CAS  Google Scholar 

  46. C.Y. Kuo et al., Water Sci. Technol. 70(8), 1428 (2014)

    Article  CAS  Google Scholar 

  47. M.A. Bhosale, B.M. Bhanage, J. Clust. Sci. 28(3), 1215–1224 (2017)

    Article  CAS  Google Scholar 

  48. H. Li et al., Appl. Catal. B 207, 134–142 (2017)

    Article  CAS  Google Scholar 

  49. D.J. Yang et al., Adv. Funct. Mater. 20(24), 4258–4264 (2010)

    Article  CAS  Google Scholar 

  50. A. Sobhani-Nasab, S.M. Hosseinpour-Mashkani, M. Salavati-Niasari, H. Taqriri, S. Bagheri, K. Saberyan, J. Mater. Sci.: Mater. El 26, 5735–5742 (2015)

    CAS  Google Scholar 

  51. A. Sobhani-Nasab, M. Rangraz-Jeddy, A. Avanes, M. Salavati-Niasari, J. Mater. Sci.: Mater. El 26, 9552–9560 (2015)

    CAS  Google Scholar 

  52. A. Sobhani-Nasab, M. Behpour, M. Rahimi-Nasrabadi, F. Ahmadi, S. Pourmasoud, J. Mater. Sci.: Mater. El 30, 5854 (2019)

    CAS  Google Scholar 

Download references

Acknowledgements

The authors wish to thank the Kashan University of Medical Sciences (kums) for their support (Grant No. 98069).

Author information

Authors and Affiliations

  1. Chemical Injuries Research Center, Systems Biology and Poisonings Institute, Baqiyatallah University of Medical Sciences, Tehran, Iran

    Mehdi Rahimi-Nasrabadi

  2. Department of Chemistry, Faculty of Pharmacy, Baqiyatallah University of Medical Sciences, Tehran, Iran

    Mehdi Rahimi-Nasrabadi

  3. Department of Addiction Studies, School of Medicine, Kashan University of Medical Sciences, Kashan, Iran

    Amir Ghaderi

  4. Clinical Research Development Unit-Matini/Kargarnejad Hospital, Kashan University of Medical Sciences, Kashan, Iran

    Amir Ghaderi

  5. Physiology Research Center, Institute for Basic Sciences, Kashan University of Medical Sciences, Kashan, Iran

    Hamid Reza Banafshe

  6. Department of Pharmacology, School of Medicine, Kashan University of Medical Sciences, Kashan, Iran

    Hamid Reza Banafshe

  7. Department of Physics, University of Kashan, Kashan, Iran

    Mohammad Eghbali-Arani & Saeid Pourmasoud

  8. Young Researchers and Elites Club, Arak Branch, Islamic Azad University, Arak, Iran

    Maryam Akbari

  9. Physiology Research Center, Iran University of Medical Sciences, Tehran, Iran

    Farhad Ahmadi

  10. Department of Medicinal Chemistry, School of Pharmacy-International Campus, Iran University of Medical Sciences, Tehran, Iran

    Farhad Ahmadi

  11. Social Determinants of Health (SDH) Research Center, Kashan University of Medical Sciences, Kashan, Iran

    Ali Sobhani-Nasab

  12. Core Research Lab, Kashan University of Medical Sciences, Kashan, Iran

    Ali Sobhani-Nasab

Authors
  1. Mehdi Rahimi-Nasrabadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Amir Ghaderi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hamid Reza Banafshe
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mohammad Eghbali-Arani
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Maryam Akbari
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Farhad Ahmadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Saeid Pourmasoud
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Ali Sobhani-Nasab
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ali Sobhani-Nasab.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rahimi-Nasrabadi, M., Ghaderi, A., Banafshe, H.R. et al. Preparation of Co2TiO4/CoTiO3/Polyaniline ternary nano-hybrids for enhanced destruction of agriculture poison and organic dyes under visible-light irradiation. J Mater Sci: Mater Electron 30, 15854–15868 (2019). https://doi.org/10.1007/s10854-019-01908-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-019-01908-7

Search

Navigation