Abstract
CoS2–CuS nanocomposites were synthesized through a simple ultrasound-assisted sol–gel technology facilely. The preparation of CoS2–CuS on cellulose fiber was carried out successfully. The microstructure, surface morphology and the optical properties of the as-synthesized catalyst samples had been considered with the XRD, SEM, UV–Vis spectra and photoluminescence. The chemical states of samples were checked with XPS. The mean crystallite sizes of CuS nanoparticles, CoCu-1 and CoCu-1/CNF are 20.85, 44.0, and 74.14 nm, respectively. The band-gap values was found 2.18, 2.14 and 2.11 eV for CuS nanoparticles, CoCu-1 and CoCu-1/CNF, respectively. The photocatalytic properties of the sample were estimated by the degradation of ciprofloxacin and ofloxacin antibiotic with UV-light irradiation. Compared with CuS nanoparticles, CoS2–CuS, the results indicate that the as-prepared CoS2–CuS on cellulose nanocomposites display great photocatalytic properties for the photo-degradation of ciprofloxacin and Ofloxacin. The results demonstrated that the highest amount of degradation (98.11, and 88.0%) of ciprofloxacin and ofloxacin was occured in pH 5 at 60 min under UV irradiation. The high catalytic activity of the CoS2–CuS on cellulose nanocomposites can be attributed to the core–shell-liked nanostructure and the synergistic effect between the CoS2 and the CuS and also, the presence of cellulose fiber causes the surface area of the photocatalyst was improved. These investigations suggest the potential application of CoS2–CuS on cellulose nanocomposites for water purification. The results demonstrated that CoCu-1/CNF nanocomposites had great antibacterial, anti-inflammatory, antioxidant properties.
Similar content being viewed by others
Change history
20 February 2024
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1007/s10854-024-12205-3
References
Z.-D. Meng, K. Ullah, L. Zhu, S. Ye, W.-C. Oh, Mater. Sci. Semicond. Process. 27, 173–180 (2014)
K. Subramanyam, N. Sreelekha, D. Amaranatha Reddy, G. Murali, R.P. Vijayalakshmi, Solid State Sci. 65, 68–78 (2017)
D. Caihua Ding, W. Su, Y. Ma, H. Zhao, Jin, Appl. Surf. Sci. 403, 1–8 (2017)
Z. Hang Zhou, H. Lv, M. Liu, H. Liang, Electrochim. Acta 250, 376–383 (2017)
X. Zhang, X.J. Liu, G. Wang, H. Wang, J. Colloid Interface Sci. 505, 23–31 (2017)
M.B. Cortie, A.M. McDonagh, Chem. Rev. 111, 3713 (2011)
X. Chen, R. Paul, L. Dai, Nat. Sci. Rev. 4, 453 (2017)
X. Huang, X.Y. Qi, F. Boey, H. Zhang, Chem. Soc. Rev. 41, 666 (2012)
Q. Liu, Z. Chang, Z. Li, X.B. Zhang, 2 (2018) 1700231
L. Zhu, S.-B. Jo, S. Ye, K. Ullah, W.-C. Oh, J. Ind. Eng. Chem. 22, 264–271 (2015)
W. Li, G. Wang, Y. Feng, Z. Li, Appl. Surf. Sci. 428, 154–164 (2018)
J. Tang, S. Ni, Q. Chen, J. Zhang, X. Yang, Mater. Lett. 201, 13–17 (2017)
L. Pan Zeng, X. Huang, Y. Zhang, Y. Han, Chen, Appl. Surf. Sci. 427, 242–252 (2018)
S. Feng Luan, D. Zhang, K. Chen, Zheng, Xuming Z, Talanta 182, 529–535 (2018)
A. Fayroz, N.M. Sabah, Z. Ahmed, S. Hassan, H. Rasheed, Sens Actuators A 249, 68–76 (2016)
M. Annie Freeda, C.K. Mahadevan, J. Alloy. Compd. 726, 1–10 (2017)
L. Wang, S. Zhao, X. Wu, S. Guo, J. Liu, N. Liu, H. Huang, Yang L, Zhenhui K, RSC Adv. 6, 66893–66899 (2016)
J. Alok Mittal, A. Mittal, V.K. Malviya, Gupta, J. Colloid Interface Sci. 344, 497–507 (2010)
K. Vinod, R. Gupta, A. Jain, S. Nayak, Agarwal, Mater Sci Eng C 31, 1062–1067 (2011)
A. Tawfik, V.K. Saleh, Gupta, J. Colloid Interface Sci. 371, 101–106 (2012)
M.K. Hadi Khani, P. Rofouei, V.K. Arab, Gupta, J Hazard Mater 183, 402–409 (2010)
V.K. Gupta, R. Kumar, A. Nayak, T.A. Saleh, M.A. Barakat, Adv. Coll. Interface. Sci. 193–194, 24–34 (2013)
R. Saravanan, E. Sacari, F. Gracia, M.K. Mohammad, K.G. Vinod, J. Mol. Liq. 221, 1029–1033 (2016)
R. Manoj Devaraj, Saravanan, R. Deivasigamani, V. Gupta, S. Jayadevan. J. Mol. Liq. 221, 930–941 (2016)
R. Saravanan, S. Joicy, V.K. Gupta, V. Narayanan, A. Stephen, Mater. Sci. Eng. C 33, 4725–4731 (2013)
R. Saravanan, S. Karthikeyan, V.K. Gupta, G. Sekaran, A. Stephen, Mater. Sci. Eng. C 33, 91–98 (2013)
R. Saravanan, E. Thirumal, V.K. Gupta, V. Narayanan, A. Stephen, J. Mol. Liq. 177, 394–401 (2013)
H. Nourali Mohammadi, V.K. Khani, Gupta, J. Colloid Interface Sci. 362, 457–462 (2011)
M. Ahmaruzzaman, K. Vinod, J. Coll. Interface Sci. 362, 457–462 (2011)
A. Tawfik, K. Saleh, V. Gupta, Sep. Purif. Technol. 89, 245–251 (2012)
R. Saravanan, N. Karthikeyan, V.K. Gupta, E. Thirumal, A. Stephen, Mater. Sci. Eng C 33, 2235–2244 (2013)
R. Saravanan, M. Mansoob Khan, V.K. Gupta, E. Mosquera, A. Stephen, J. Colloid Interface Sci. 452, 126–133 (2015)
R. Saravanan, M.M. Khan, V.K. Gupta, E. Mosquera, F. Gracia, V. Narayanan, A. Stephen, RSC Adv. 5, 34645–34651 (2015)
M. Ghaedi, S. Hajjati, Z. Mahmudi, I. Tyagi, V.K. Gupta, Chem. Eng. J. 268, 28–37 (2015)
V.K. Gupta, N. Atar, M.L. Yola, Z. Üstündağ, L. Uzun. Water Res. 48, 210–217 (2014)
M. Arash Asfaram, S. Ghaedi, Agarwal, I. Tyagi, V. Gupta. RSC Adv. 5, 18438–18450 (2015)
V.K. Gupta, A. Fakhri, S. Agarwal, N. Sadeghi, Int. J. Biol. Macromol. 102, 840–846 (2017)
B. Xin, Z. Ren, P. Wang, J. Liu, L. Jing, H. Fu, Appl. Surf. Sci. 253, 4390–4395 (2007)
A. Fakhri, S. Behrouz, Sol. Energy 112, 163–168 (2015)
V.S. Suvith, D. Philip, Spectrochim. Acta A 118, 526 (2014)
P.C. Nagajyothi, T.V.M. Sreekanth, J. Lee, K.D. Lee, J. Photochem. Photobiol. B 130, 299 (2013)
C.-J. Chen, P.-T. Chen, M. Basu, M. Basu, R.-S. Liu, J. Mater. Chem. A, 3, 46 (2015)
A. Sana Riyaz, A. Parveen, Perspect Sci. 8, 632–635 (2016)
S. Canbin Ouyang, J. Feng, S. Huo, Wang, Green Energy Environ. 2, 134–141 (2017)
W. Xu, S. Zhu, Y. Liang, Z. Li, Z. Cui, Sci. Rep., 5, 18125 (2015)
M. Konsolakis, S.A.C. Carabineiro, G.E. Marnellos, M.F. Asad, J.L. Figueiredo, J. Colloid Interface Sci. 496, 141–149 (2017)
K.A. Rieger, M. Porter, J.D. Schiffman, Materials, 9, 297 (2016)
M. Lykaki, E. Pachatouridou, S.A.C. Carabineiro, E. Iliopoulou, M. Konsolakis, Appl. Catal. B 230, 18–28 (2018)
A. Fakhri, S. Behrouz, Sol. Energy 117, 187–191 (2015)
M.R.R. Mojgan Hosseini, A. Kahkha, Fakhri, S. Tahami, M.J. Lariche. J. Photochem. Photobiol. B 185, 24–31 (2018)
A. Fakhri, R. Khakpour, J. Lumin. 160, 233–237 (2015)
R. Wei Gao, A. Razavi, Fakhri, Int. J. Biol. Macromol. 114, 357–362 (2018)
S.K. Tripathy, A. Mishra, S.K. Jha, R. Wahabd, A.A. Al-Khedhairyd, Anal. Methods 5, 1456 (2013)
K. Yu, Z. Wu, Q. Zhao, B. Li, Y. Xie, J. Phys. Chem. C 112, 2244 (2008)
L. Kronik, Y. Shapira, Surf. Interface Anal. 31, 954–965 (2001)
B.K. Bammannavar, L.R. Naik, B.K. Chougule, J. Appl. Phys. 104, 064123 (2008)
C.G. Koops, Phys. Rev. 83, 121–124 (1951)
M. Mojgan Hosseini, A. Sarafbidabad, Z. Fakhri, S. NoorMohammadi, Int/ J. Biol. Macromol., https://doi.org/10.1016/j.ijbiomac.2018.06.176
M. El-Kemary, H. El-Shamy, I. El-Mehasseb, J. Lumin., 130 (2010) 2327–2331
F.K. Nahid Khoshnamvand, A. Mostafapour, M. Faraji, AMB Express 8, 48 (2018)
A. Hassani, A. Khataee, S. Karaca, J. Mol. Catal. A 409, 149–161 (2015)
A. Gupta, A. Umar, S. Kaur, A. Sood, S.K. Dhir, A. Kansal, Mater. Res. Bull. 99, 359–366 (2018)
M.S. Peres, M.G. Maniero, J.R. Guimarães, Photochem. Photobiol. Sci. 14, 556–562 (2015)
E.S. Elmolla, M. Chaudhuri, J. Hazard. Mater. 173, 445–449 (2010)
J. Blanco, S. Malato, P. Fernández, A. Vidal, Sol. Energy 67, 317–330 (1999)
A. Mojgan Hosseini, A. Pourabadeh, J. Fakhri, S.T. Hallajzadeh, Int. J. Biol. Macromol. (2018) https://doi.org/10.1016/j.ijbiomac.2018.07.065
S.K. Tripathy, A.S.K. Mishra, R. Jha, A.A. Wahab, Al-Khedhairy, J. Mater. Sci., 24 (2013) 2082
S.A.C. Carabineiro, T. Thavorn-Amornsri, M.F.R. Pereira, J.L. Figueiredo, Water Res. 45, 4583–4591 (2011)
A.R. Silva, P.M. Martins, S. Teixeira, S.A.C. Carabineiro, K. Kuehn, G. Cuniberti, M.M. Alves, S. Lanceros-Mendezagh, L. Pereira, RSC Adv. 6, 95494 (2016)
Acknowledgements
The authors gratefully acknowledge supporting of this research by the, Islamic Azad University, Science research Branch. The project was supported in part by the Joint Special Foundation on basic research in Local Colleges and Universities for the Science and Technology Department of Yunnan Province of China under Grant No. 2017FH001-106 and the Natural Science Foundation for the Higher Education Institutions of Anhui Province of China under Grant Nos. KJ2016A368, KJ2016A369 and 2016jyxm0552.
Author information
Authors and Affiliations
Corresponding authors
Additional information
This article has been retracted. Please see the retraction notice for more detail: https://doi.org/10.1007/s10854-024-12205-3
About this article
Cite this article
Zheng, ZB., Sun, JJ., Fakhri, A. et al. RETRACTED ARTICLE: Synthesis, photocatalytic, optical, electronic and biological properties of the CoS2–CuS on cellulose nanocomposites as novel nano catalyst by a sonochemical technology. J Mater Sci: Mater Electron 29, 18531–18539 (2018). https://doi.org/10.1007/s10854-018-9969-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-9969-0