Abstract
TiO2/Cu2O heterojunction solar cells have been successfully deposited on Ti foils using the electrochemical route. The effect of deposition potential on the efficiency of TiO2/Cu2O heterojunction solar cells has been studied. The SEM images show yarn ball like morphology of Cu2O layer. The XPS spectra indicate the formation of TiO2/Cu2O heterojunction from their corresponding oxidation states. Raman spectroscopy displays single anatase phase of TiO2 in presence of Cu2O. From J–V characteristics of TiO2/Cu2O heterojunction, the solar cell parameters such as Jsc, Voc, Pmax, fill factor and efficiency have been measured. The heterojunction solar cell shows 41% maximum fill factor and power conversion efficiency 0.21%.
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P.C. Huang, C.C. Sung, J.H. Chen, R.C. Hsiao, C.Y. Hsu, J. Mater. Sci.: Mater. Electron. 29, 1444 (2018)
J.J.M. Vequizo, M. Ichimura, Appl. Phys. Express 7, 045501 (2014)
A. Dewasi, A. Mitra, J. Mater. Sci.: Mater. Electron. 28, 18075 (2017)
L. Ion, I. Enculescu, S. Iftimie, V. Ghenescu, C. Tazlaoanu, C. Besleaga, T.L. Mitran, V.A. Antohe, M.M. Gugiu, S. Antohe, Chalcogenide Lett. 7, 521 (2010)
A. Radu, S. Iftimie, V. Ghenescu, C. Besleaga, V.A. Antohe, G. Bratina, L. Ion, S. Craciun, M. Girtan, S. Antohe, Dig. J. Nanomater. Biostruct. 6, 1141 (2011)
X. Ma, X. Ni, J. Mater. Sci.: Mater. Electron. 26, 1129 (2015)
Ö Pehlivan, D. Menda, O. Yılmaz, A.O. Kodolbaş, O. Özdemir, Ö Duygulu, K. Kutlu, M. Tomak, Mater. Sci. Semicond. Process. 22, 69 (2014)
C. Sima, C. Grigoriu, S. Antohe, Thin Solid Films 519, 595 (2010)
S. Rȕhle, H.N. Barad, Y. Bouhadana, D.A. Keller, A. Ginsburg, K. Shimanovich, K. Majhi, R. Lovrincic, A.Y. Anderson, A. Zaban, Phys. Chem. Chem. Phys. 16, 7066 (2014)
Q. Yang, M. Long, L. Tan, Y. Zhang, J. Ouyang, P. Liu, A. Tang, ACS Appl. Mater. Interfaces 7, 12719 (2015)
T.-Y. Tsai, S.-J. Chang, T.-J. Hsueh, H.-T. Hsueh, W.-Y. Weng, C.-L. Hsu, B.-T. Dai, Nanoscale Res. Lett. 6, 575 (2011)
D. Barreca, G. Carraro, A. Gasparotto, C. Maccato, M. Cruz-Yusta, J.L. Gόmez-Camer, J. Morales, C. Sada, L. Sánchez, ACS Appl. Mater. Interfaces 4, 3610 (2012)
Y. Liu, H. Zhou, J. Li, H. Chen, D. Li, B. Zhou, W. Cai, Nano-Micro Lett. 2, 277 (2010)
J. Xue, Q. Shen, W. Liang, X. Liu, B. Xu, Mater. Lett. 92, 239 (2013)
H. Yan, T. Zhao, X. Li, Ceram. Int. 42, 14862 (2016)
Y. Li, H. Yu, C. Zhang, L. Fu, G. Li, Z. Shao, B. Yi, J. Electroanal. Chem. 688, 228 (2013)
P.K. Pagare, A.P. Torane, Microchim. Acta 183, 2983 (2016)
J. Wang, G. Ji, Y. Liu, M.A. Gondal, X. Chang, Catal. Commun. 46, 17 (2014)
N.L. Tarwal, K.V. Gurav, S.H. Mujawar, S.B. Sadale, K.W. Nam, W.R. Bae, A.V. Moholkar, J.H. Kim, P.S. Patil, J.H. Jang, Ceram. Int. 40, 7669 (2014)
M. Pavan, S. Rühle, A. Ginsburg, D.A. Keller, H.-N. Barad, P.M. Sberna, D. Nunes, R. Martins, A.Y. Anderson, A. Zaban, E. Fortunato, Solar Energy Mater. Solar Cells 132, 549 (2015)
T. Han, D. Zhou, H. Wang, X. Zheng, J. Environ. Chem. Eng. 3, 2453 (2015)
J.F. Moulder, W.F. Stickle, P.E. Sobol, K.D. Bomben, Handbook of X-ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data, (Perkin Elmer, Waltham, 1995)
L. Zhao, W. Dong, F. Zheng, L. Fang, M. Shen, Electrochim. Acta 80, 354 (2012)
Y. Hou, X.Y. Li, Q.D. Zhao, X. Quan, G.H. Chen, Appl. Phy. Lett. 95, 093108 (2009)
J. Zhang, Y. Wang, C. Yu, X. Shu, L. Jiang, J. Cui, Z. Chen, T. Xie, Y. Wu, New J. Chem. 38, 4975 (2014)
S.A. Pawar, R.S. Devan, D.S. Patil, V.V. Burungale, T.S. Bhat, S.S. Mali, S.W. Shin, J.E. Ae, C.K. Hong, Y.R. Ma, J.H. Kim, P.S. Patil, Electrochim. Acta 117, 470 (2014)
Q. Sun, Y. Li, X. Sun, L. Dong, ACS Sustain. Chem. Eng. 1, 798 (2013)
K.P. Priyanka, V.R. Revathy, P. Rosmin, B. Thrivedu, K.M. Elsa, J. Nimmymol, K.M. Balakrishna, T. Varghese, Mater. Charact. 113, 144 (2016)
S.S. Mali, P.S. Shinde, C.A. Betty, P.N. Bhosale, W.J. Lee, P.S. Patil, Appl. Surf. Sci. 257, 9737 (2011)
P.K. Pagare, A.P. Torane, J. Mater. Sci.: Mater. Electron. 28, 1386 (2017)
A.P. Torane, C.H. Bhosale, Mater. Res. Bull. 38, 847 (2003)
Z. Zhang, P. Wang, J. Mater. Chem. 22, 2456 (2012)
L.-K. Tsui, L. Wu, N. Swami, G. Zangari, ECS Electrochem. Lett. 1, D15 (2012)
M. Ichimura, Y. Kato, Mater. Sci. Semicond. Process. 16, 1538 (2013)
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Authors are very thankful to Research Advisory Committee and Department of Physics, Yashavantrao Chavan Institute of Science, Satara for financial assistance to complete this work.
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Pagare, P.K., Torane, A.P. Effect of deposition potential on efficiency of TiO2/Cu2O photoelectrochemical cells. J Mater Sci: Mater Electron 29, 8473–8479 (2018). https://doi.org/10.1007/s10854-018-8860-3
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DOI: https://doi.org/10.1007/s10854-018-8860-3