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Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles

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Abstract

In this study, Fe-alloyed CdZnS nanoparticles (NPs) with 1% Fe concentration (Fe (1%): CdZn (2%)S) were synthesized by chemical precipitation at room temperature. The synthesized NPs were used as a catalyst for the decomposition of methylene blue under UV light. The obtained results showed that the photocatalytic activity of Fe (1%): CdZn (2%)S NPs was higher than that of CdZn (2%)S NPs. It was determined that the kinetics of the photocatalytic degradation of the methylene blue (MB) correspond to the pseudo-second order kinetics model. In addition to the photocatalytic properties, the structural, morphological and optical properties of Fe (1%): CdZn (2%)S NPs were investigated.

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References

  1. D. Ratna, B.S. Padhi, Pollution due to synthetic dyes toxicity and carcinogenicity studies and remediation. Int. J. Environ. Sci. 3, 3 (2012)

    Google Scholar 

  2. M. Sharma, T. Jain, S. Singh, O.P. Pandey, Photocatalytic degradation of organic dyes under UV-visible light using capped ZnS nanoparticles. Sol. Energy 86, 626 (2012)

    Article  Google Scholar 

  3. N.E. Fard, R. Fazali, R. Ghiasi, Band gap energies and photocatalytic properties of CdS and Ag/CdS nanoparticles for Azo dye degradation. Chem. Eng. Technol. 39, 149 (2016)

    Article  Google Scholar 

  4. C.L.T. Martines, R. Kho, O.I. Mian, R.K. Mehra, Efficient photocatalytic degradation of environmental pollutants with mass- produced ZnS nanocrystals. J. Colloid Interface Sci. 240, 525 (2001)

    Article  Google Scholar 

  5. S.A. Palthane, S.A. Vanalakar, T.S. Bhat. P.S. Patil, S.D. Sartale, L.D. Kadam, Photocatalyticdegradation of methylene blue by hydrothermally synthesized CZTS nanoparticles. J. Mater. Sci. 28, 8186 (2017)

    Google Scholar 

  6. V. Etacheri, C.D. Valentin, J. Schneider, D. Dahnemann, S.C. Pillai, Visible-light activation of TiO2 photocatalyst: advances in theory and experiments. J. Photochem. Photobiol. C 25, 1 (2015)

    Article  Google Scholar 

  7. T. Takata, C. Pan, K. Domen, Recent progress in oxynitridephotocatalyst for visible-light- driven water splitting. Sci. Technol. Adv. Mater. 16, 3 (2015)

    Article  Google Scholar 

  8. H.R. Pourtedal, A. Norozi, M.H. Keshavarz, A. Semnani, Nanoparticles of zinc sulfide doped with manganese, nickel and copper as nanophotocatalyst in the degradation of organic dyes. J. Hazard. Mater. 162, 674 (2011)

    Article  Google Scholar 

  9. J.K. Wang, L.J. Xu, Advanced oxidation processes for waste water treatment: Formation of Hydroxyl radical and application. Crit. Rev. Environ. Sci. Technol. 42, 251 (2011)

    Article  Google Scholar 

  10. H. Zhou, Y. Qu, T. Zeid, X. Duan, Towards highly efficient photocatalyst using the semiconductor nanoarchitectures. Energy Environ. Sci. 5, 6732 (2012)

    Article  Google Scholar 

  11. C.V. Reddy, J. Shim, M. Cho, Synthesis, structural, optical and photocatalytic properties of CdS/ZnS core/shell nanoparticles. J. Phys. Chem. Solids 103, 209 (2017)

    Article  Google Scholar 

  12. V. Krishnakumar, R. Ranjith, J. Jayaprakash, S. Boobas, J. Venkatesan, Enhancement of photocatalytic degradation of methylene blue under-visible light using transparent Mg-doped CdS-PVA nano-composite films. J. Mater. Sci. 28, 13990 (2017)

    Google Scholar 

  13. J.H. Li, A.H. lu, F. Liu, L.Z. Fan, Synthesis of ZnS/ dravite composite and its photocatalytic activity of on degradation of methylene blue. Solid State Ion. 179, 1387 (2008)

    Article  Google Scholar 

  14. S. Iravani, H. Korbekandi, S.V. Mirmohammadi, B. Zolfaghari, Synthesis of Silver nanoparticles: chemical, physical and biological methods. Res. Pharm. Sci. 9, 385 (2014)

    Google Scholar 

  15. X. Xu, L. Hu, N. Gao, S. Liu, S. Wageh, A.A.A. Ghamdi, A. Alshahrie, X. Fang, 2015. Controlled growth from ZnS nanoparticles to ZnS and ZnS-CdS nanoparticle hybrids with enhanced photoactivity. Adv. Funct. Mater. 25, 445

    Article  Google Scholar 

  16. G. Darya, l Ivan, S. Valery, Synthesis of CdS nanoparticles by laser ablation of metallic cadmium target in presence different precursors. Adv. Mater. Res. 1085, 182 (2015)

    Article  Google Scholar 

  17. M.M. Rashad, A.A. Ismail, I. Osama, I.A. Ibrahim, A.H.T. Kandil, Photocatalytic decomposition of dyes using ZnO doped SnO2 nanoparticles prepared by solvothermal method. Arab. J. Chem. 7, 171 (2014)

    Article  Google Scholar 

  18. S.M.H. Mashkani, M. Maddahfar, A.S. Nasab, Novel silver-doped CdMoO4: synthesis, characterization and its photocatalytic performance for methylene orange degradation through the sonochemical method. J. Mater. Sci. 27, 477 (2016)

    Google Scholar 

  19. S. Horoz, O. Baytar, O. Sahin, H. Kilicvuran, Photocatalytic degradation of methylene blue with Co-alloyed CdZnS nanoparticles. J. Mater. Sci. 28, 1 (2017)

    Google Scholar 

  20. S. Horoz, O. Sahin, Investigations of structural, optical, and photovoltaic properties of Fe-alloyed ZnS quantum dots. J. Mater. Sci. 28, 9559 (2017)

    Google Scholar 

  21. S. Horoz, L. Li, Q. Dai, J. Chen, B. Yakami, J. Pikal, W. Wang, T. Tang, CdSe quantum dots synthesized by laser ablation inwater and their photovoltaic applications. Appl. Phys. Lett. 101, 223902 (2012)

    Article  Google Scholar 

  22. S. Horoz, B. Yakami, U. Poudyal, J. Pikal, W. Wang, T. Tang, Controlled synthesis of Eu2+ and Eu3+ doped ZnS quantum dots and their photovoltaic and magnetic properties. AIP Adv. 6, 045119 (2016)

    Article  Google Scholar 

  23. L. Brus, Electronic wave functions in semiconductor clusters: experiment and theory. J. Phys. Chem. 90, 2555 (1986)

    Article  Google Scholar 

  24. J. Theerthagiri, R.A. Senthil, J. Madhavan, Synthesis, characterization and optical properties of CdxZn1–xS nanocrystals. Mater. Sci. Forum 832, 158 (2015)

    Article  Google Scholar 

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Acknowledgements

This study was supported by Research Fund of the Siirt University. Project Code: 2016 SIUFEB 36.

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Correspondence to Sabit Horoz.

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Baytar, O., Sahin, O., Kilicvuran, H. et al. Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles. J Mater Sci: Mater Electron 29, 4564–4568 (2018). https://doi.org/10.1007/s10854-017-8406-0

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  • DOI: https://doi.org/10.1007/s10854-017-8406-0

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