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Synthesis of hexagonal Co3+-substituted Sr-ferrites via ball-milling assisted ceramic process and their magnetic properties

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Abstract

M-type hexagonal SrCoxFe12−xO19 (x = 0, 0.1, 0.2, and 0.3) have been synthesized by the ball-milling assisted ceramic process. The influence of Co substitutions on the crystalline structure, lattice strain, morphology, and magnetic behaviors has been investigated. The results show that a high-crystallized hexagonal SrCoxFe12−xO19 is obtained when the precursor is calcined at 950 °C in air for 3 h. Lattice parameters and grain size of SrCoxFe12−xO19 increase with the increase in substitution content (x). Hysteresis behavior varies with substitution content (x) and calcination temperature. M-type hexagonal SrCoxFe12−xO19 (x = 0, 0.1, and 0.2), calcined at 950 °C, with uniaxial anisotropy exhibits a broad M–H loop and rectangular shape. At higher calcination temperature (1050 and 1200 °C) or substitution content (x) is equal to 0.3, the character of the hysteresis loop of SrCoxFe12−xO19 changes from hard into semi-hard. The trend of specific saturation magnetization of SrCoxFe12−xO19, calcined at 950 °C, increases with the decrease in lattice strains. SrFe12O19, calcined at 950 °C, has the highest specific saturation magnetization value (91.30 emu/g) and magnetic moment (17.36 µ B). With the increase of calcination temperature, magnetic domain type of ferrites changes from a single magnetic domain to a multi-domain type.

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Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (Grant No. 21603040) and the Guangxi Natural Science Foundation of China (Grant Nos. 2016GXNSFDA380034, 2016GXNSFBA380062).

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Authors and Affiliations

  1. Guangxi Key Laboratory of Electrochemical Energy Materials, Collaborative Innovation Center of Renewable Energy Materials, Guangxi University, Nanning, 530004, People’s Republic of China

    Xuehang Wu

  2. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, 530004, People’s Republic of China

    Wen Chen, Wenwei Wu, Yu Ning & Shasha Chen

  3. Guangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, Nanning, 530004, People’s Republic of China

    Wenwei Wu

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  1. Xuehang Wu
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  2. Wen Chen
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Correspondence to Wenwei Wu.

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Wu, X., Chen, W., Wu, W. et al. Synthesis of hexagonal Co3+-substituted Sr-ferrites via ball-milling assisted ceramic process and their magnetic properties. J Mater Sci: Mater Electron 28, 18815–18824 (2017). https://doi.org/10.1007/s10854-017-7831-4

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