Skip to main content

Advertisement

SpringerLink
Log in

Facial synthesis of MnO2/three dimensional graphene composite and its application in supercapacitors

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

MnO2 nanoparticle/three dimensional graphene composite (MnO2/3DG) was synthesized by a hydrothermal template-free method and subsequent ultrasonic treatment in KMnO4 solution. The MnCO3/3DG particles can be detected after the hydrothermal process, which may be produced through the reaction between Mn2+ and \({\text{C}}{{\text{O}}_{\text{3}}}^{{\text{2}} - }\) due to the decarboxylation of GO under the hydrothermal condition. The final product MnO2/3DG displayed high specific capacitance (324 F g− 1 at 0.4 A g−1) and good cycle stability (91.1% capacitance retention after 5000 cycles). Furthermore, the asymmetric supercapacitor assembled with MnO2/3DG and activated carbon (AC) exhibits an energy density of 33.78 Wh kg−1 at the powder density of 380 W kg−1. The excellent supercapacitance of the MnO2/3DG composite may be due to the high pseudocapacitance of the dispersed MnO2 nanoparticles and the conductive graphene with three dimensional porous microstructure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. Z. Yu, L. Tetard, L. Zhai, J. Thomas, Energy Environ. Sci. 8, 702 (2015)

    Article  Google Scholar 

  2. X. Zhang, H. Zhang, C. Li, K. Wang, X. Sun, Y. Ma, Rsc Adv. 4, 45862 (2014)

    Article  Google Scholar 

  3. J. Tang, R.R. Salunkhe, J. Liu, N.L. Torad, M. Imura, S. Furukawa, Y. Yamauchi, J. Am. Chem. Soc. 137, 1572 (2015)

    Article  Google Scholar 

  4. Y. Boyjoo, M. Wang, V.K. Pareek, J. Liu, M. Jaroniec, Chem. Soc. Rev. 45, 6013 (2016)

    Article  Google Scholar 

  5. H. Tian, M. Saunders, A. Dodd, K. O’Donnell, M. Jaroniec, S. Liu, J. Liu, J. Mater. Chem. A 4, 3721 (2016)

    Article  Google Scholar 

  6. T. Yang, R. Zhou, D.-W. Wang, S.P. Jiang, Y. Yamauchi, S.Z. Qiao, M.J. Monteiro, J. Liu, Chem. Commun. 51, 2518 (2015)

    Article  Google Scholar 

  7. Y. Boyjoo, Y. Cheng, H. Zhong, H. Tian, J. Pan, V.K. Pareek, S.P. Jiang, J.-F. Lamonier, M. Jaroniec, J. Liu, Carbon 116, 490 (2017)

    Article  Google Scholar 

  8. S. Faraji, F.N. Ani, Renew. Sust. Energy Rev. 42, 823 (2015)

    Article  Google Scholar 

  9. L.L. Zhang, X.S. Zhao, Chem. Soc. Rev. 38, 2520 (2009)

    Article  Google Scholar 

  10. W. Li, G. He, J. Shao, Q. Liu, K. Xu, J. Hu, I.P. Parkin, Electrochim. Acta 186, 1 (2015)

    Article  Google Scholar 

  11. L. Feng, Y. Zhu, H. Ding, C. Ni, J. Power Sources 267, 430 (2014)

    Article  Google Scholar 

  12. S.S. Raut, B.R. Sankapal, New J. Chem. 40, 2619 (2016)

    Article  Google Scholar 

  13. V. Velmurugan, U. Srinivasarao, R. Ramachandran, M. Saranya, A.N. Grace, Mater. Res. Bull. 84, 145 (2016)

    Article  Google Scholar 

  14. T.Z. Liu, X.D. Zhang, B.J. Li, J. Ding, Y.S. Liu, G. Li, X.H. Meng, Q. Cai, J.M. Zhang, RSC Adv. 4, 50765 (2014)

    Article  Google Scholar 

  15. J. Lv, X. Yang, H. Zhou, L. Kang, Z. Lei, Z. Liu, Mater. Res. Bull. 84, 429 (2016)

    Article  Google Scholar 

  16. Y. He, W. Chen, J. Zhou, X. Li, P. Tang, Z. Zhang, J. Fu, E. Xie, ACS Appl. Mater. Interfaces 6, 210 (2014)

    Article  Google Scholar 

  17. C. Gong, Y. He, J. Zhou, W. Chen, W. Han, Z. Zhang, P. Zhang, X. Pan, Z. Wang, E. Xie, ACS Appl. Mater. Interfaces 6, 14844 (2014)

    Google Scholar 

  18. D.G. Lee, J.H. Kim, B.-H. Kim, Electrochim. Acta 200, 174 (2016)

    Article  Google Scholar 

  19. C. Yang, M. Zhou, Q. Xu, Phys. Chem. Chem. Phys. 15, 19730 (2013)

    Article  Google Scholar 

  20. V. Veeramani, B. Dinesh, S.-M. Chen, R. Saraswathi, J. Mater. Chem. A 4, 3304 (2016)

    Article  Google Scholar 

  21. J. Hao, Y. Zhong, Y. Liao, D. Shu, Z. Kang, X. Zou, C. He, S. Guo, Electrochim. Acta 167, 412 (2015)

    Article  Google Scholar 

  22. Q. Chen, Y. Meng, C. Hu, Y. Zhao, H. Shao, N. Chen, L. Qu, J. Power Sources 247, 32 (2014)

    Article  Google Scholar 

  23. S. Deng, D. Sun, C. Wu, H. Wang, J. Liu, Y. Sun, H. Yan, Electrochim. Acta 111, 707 (2013)

    Article  Google Scholar 

  24. J. Ge, H. Yao, W. Hu, X. Yu, Y. Yan, L. Mao, H. Li, S. Li, S. Yu, Nano Energy 2, 505 (2013)

    Article  Google Scholar 

  25. B. Zhao, M.N. Lu, Z.X. Wang, Z. Jiao, P.F. Hu, Q. Gao, Y. Jiang, L.L. Cheng, J. Alloy Compd. 663, 180 (2016)

    Article  Google Scholar 

  26. Y. Zhao, Y. Meng, H. Wu, Y. Wang, Z. Wei, X. Li, P. Jiang, Rsc Adv. 5, 90307 (2015)

    Article  Google Scholar 

  27. S. Sun, P. Wang, S. Wang, Q. Wu, S. Fang, Mater. Lett. 145, 141 (2015)

    Article  Google Scholar 

  28. Y. He, W. Chen, X. Li, Z. Zhang, J. Fu, C. Zhao, E. Xie, Acs Nano 7, 174 (2013)

    Article  Google Scholar 

  29. W. Hummers, R. Offeman, J. Am. Chem. Soc. 80, 1339 (1958)

    Article  Google Scholar 

  30. K. Makgopa, P.M. Ejikeme, C.J. Jafta, K. Raju, M. Zeiger, V. Presser, K.I. Ozoemena, J. Mater. Chem. A 3, 3480 (2015)

    Article  Google Scholar 

  31. S. Sun, S. Wang, T. Xia, X. Li, Q. Jin, Q. Wu, L. Wang, Z. Wei, P. Wang, J. Mater. Chem. A 3, 20944 (2015)

    Article  Google Scholar 

  32. V. Khomenko, E. Raymundo-Pinero, F. Beguin, J. Power Sources 195, 4234 (2010)

    Article  Google Scholar 

  33. Y. Qiao, S. Li, Y. Yu, C. Chen, J. Mater. Chem. A 1, 860 (2013)

    Article  Google Scholar 

  34. S. Sun, S. Wang, S. Li, Y. Li, Y. Zhang, J. Chen, Z. Zhang, S. Fang, P. Wang, J. Mater. Chem. A 4, 18646 (2016)

    Article  Google Scholar 

  35. L. Zhou, X. Kong, M. Gao, F. Lian, B. Li, Z. Zhou, H. Cao, Inorg. Chem. 53, 9228 (2014)

    Article  Google Scholar 

  36. K. Hu, X. Xie, T. Szkopek, M. Cerruti, Chem. Mater. 28, 1756 (2016)

    Article  Google Scholar 

  37. Y. Xu, G. Shi, X. Duan, Acc. Chem. Res. 48, 1666 (2015)

    Article  Google Scholar 

  38. S. Wu, W. Chen, L. Yan, J. Mater. Chem. A 2, 2765 (2014)

    Article  Google Scholar 

  39. Q.T. Qu, Y. Shi, S. Tian, Y.H. Chen, Y.P. Wu, R. Holze, J. Power Sources 194, 1222 (2009)

    Article  Google Scholar 

  40. F. Li, Y.X. Zhang, M. Huang, Y. Xing, L.L. Zhang, Electrochim. Acta 154, 329 (2015)

    Article  Google Scholar 

  41. Y. Liu, D. He, H. Wu, J. Duan, Y. Zhang, Electrochim. Acta 164, 154 (2015)

    Article  Google Scholar 

  42. H. Gao, F. Xiao, C.B. Ching, H. Duan, ACS Appl. Mater. Interfaces 4, 2801 (2012)

    Article  Google Scholar 

  43. W. Chen, Y. He, X. Li, J. Zhou, Z. Zhang, C. Zhao, C. Gong, S. Li, X. Pan, E. Xie, Nanoscale 5, 11733 (2013)

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to thank the National Natural Science Foundation of China (21301159), Natural Science Research Assistance Program from the Education Department of Henan Province (15A150083) and Program of Zhengzhou City for Science and Technology (20150440) for financial support.

Author information

Authors and Affiliations

  1. Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou, 450002, China

    Peiyuan Wang, Chao Zhou, Shen Wang, Huajie Kong, Yannan Li, Shaodan Li & Shumin Sun

Authors
  1. Peiyuan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chao Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shen Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Huajie Kong
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yannan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shaodan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Shumin Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shumin Sun.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, P., Zhou, C., Wang, S. et al. Facial synthesis of MnO2/three dimensional graphene composite and its application in supercapacitors. J Mater Sci: Mater Electron 28, 12514–12522 (2017). https://doi.org/10.1007/s10854-017-7074-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-7074-4

Keywords

Search

Navigation