Abstract
Antiferroelectric materials form a potential candidate for ceramic-based high energy storage applications owing to their low loss and high energy density. Here, we demonstrate that the antiferroelectric phase with high energy-storage properties in 0.94Bi0.5+x Na0.5−x TiO3–0.06BaTiO3 (BNTx–BT) ceramics at room-temperature is modulated by tailoring compositions. Our results show that the metastable antiferroelectric phase at room-temperature modulated by the Bi/Na ratio with a high excess in Bi3+ and/or a deficiency in Na+, can be induced to the FE phase by applying electrical field, leading to double hysteresis. The high energy storage density W = 1.76 J/cm3 for x = 0.05 BNTx–BT ceramics by modulating Bi/Na ratio is obtained, suggesting a promising candidate lead-free energy-storage material.
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Acknowledgments
Part of this work was financially supported by the National Nature Science Foundation of China (11564007, 61561015, and 61361007) and Guangxi Key Laboratory of Information Materials (1310001-Z) and the Natural Science Foundation of Guangxi (Grant Nos. 2012GXNSFGA60002 and 2015GXNSFAA139250).
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Li, Q., Zhou, C., Xu, J. et al. Tailoring antiferroelectricity with high energy-storage properties in Bi0.5Na0.5TiO3–BaTiO3 ceramics by modulating Bi/Na ratio. J Mater Sci: Mater Electron 27, 10810–10815 (2016). https://doi.org/10.1007/s10854-016-5187-9
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DOI: https://doi.org/10.1007/s10854-016-5187-9