Abstract
Effect of dimethyl borate (C3H9BO3) composition on the structure, morphology, thickness, elemental composition, optical absorption, photoluminescence of ZnO nanotubes and the performance of the DSSC has been studied. It was found that the structure, diameter, thickness, elemental composition, optical absorption and morphology of ZnO nanostructure are significantly influenced by the composition of dimethyl borate. The diameter and thickness of ZnO nanotubes decrease with the increase in the composition of C3H9BO3. The photoluminescence increases with the composition of C3H9BO3. The DSSC utilizing ZnO nanotubes synthesized at 1 wt% C3H9BO3 yields the J SC and η of 1.9 mA cm−2 and 0.222 %, respectively.
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S. Ameen, M.S. Akhtar, H.K. Seo, Y.S. Kim, H.S. Shin, Influence of Sn doping on ZnO nanostructures from nanoparticles to spindle shape and their photoelectrochemical properties for dye sensitized solar cells. Chem. Eng. J. 187, 351–356 (2012)
A. Tubtimtae, M.-W. Lee, ZnO nanorods on undoped and indium-doped ZnO thin films as a TCO layer on nonconductive glass for dye-sensitized solar cells. Superlattice Microstruct. 52, 987–996 (2012)
J. Zhang, W. Peng, Z. Chen, H. Chen, L. Han, Effect of cerium doping in the TiO2 photoanode on the electron transport of dye-sensitized solar cells. J. Phys. Chem. C 116, 19182–19190 (2012)
J.C. Zhang, Z.Y. Han, Q.Y. Li, X.Y. Yang, Y. Yu, W.L. Cao, N, S-doped TiO2 anode effect on performance of dye-sensitized solar cells. J. Phys. Chem. Solids 72, 1239–1244 (2011)
M.Y.A. Rahman, A.A. Umar, S.K.M. Saad, M.M. Salleh, A. Ishaq, Effect of dye on the performance of nitrogen doped TiO2 solar cell prepared via ammonia treated liquid phase deposition technique. J. New Mater. Electrochem. Syst. 17, 33–37 (2014)
T. Ma, M. Akiyama, E. Abe, High-efficiency dye-sensitized solar cell based on a nitrogen doped nanostructured titania electrode. Nano Lett. 5, 2543–2547 (2005)
C.K. Lim, H. Huang, C.L. Chow, P.Y. Tan, X. Cheng, M.S. Tse, O.K. Tan, Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode. J. Phys. Chem. C 116, 19659–19664 (2012)
Y.-B. Tang, C.-S. Lee, J. Xu, Z.-T. Liu, Z.-H. Chen, Z. He, Y.-L. Cao, G. Yuan, H. Song, L. Chen, L. Luo, H.-M. Cheng, W.-J. Zhang, I. Bello, S.-T. Lee, Incorporation of graphenes in nanostructured TiO2 films via molecular grafting for dye-sensitized solar cell application. ACS Nano 4, 3482–3488 (2010)
B.N. Pawar, G. Cai, D. Ham, R.S. Mane, T. Ganesh, A. Ghule, R. Sharma, K.D. Jadhava, S.H. Han, Preparation of transparent and conducting boron-doped ZnO electrode for its application in dye-sensitized solar cells Sol. Energy Mater. Sol. Cells 93, 524–527 (2009)
V. Kumar, N. Singh, V. Kumar, L.P. Purohit, A. Kapoor, O.M. Ntwaeaborwa, H.C. Swart, Doped zinc oxide window layers for dye sensitized solar cells. J. Appl. Phys. 114, 134506 (2013)
P. Dhamodharan, C. Manoharan, S. Dhanapandian, M. Bououdina, S. Ramalingam, Preparation and characterization of spray deposited Sn-doped ZnO thin films onto ITO substrate as photoanode in dye sensitized solar cell. J. Mater. Sci. Mater. Electron. 26, 4830–4839 (2015)
İ. Polat, Effects of Na-doping on the efficiency of ZnO nanorods-based dye sensitized solar cells. J. Mater. Sci. Mater. Electron. 25, 3721–3726 (2014)
İ. Polat, S. Yılmaz, E. Bacaksız, Y. Atasoy, M. Tomakin, Synthesis and fabrication of Mg-doped ZnO-based dye-synthesized solar cells. J. Mater. Sci. Mater. Electron. 25, 3173–3178 (2015)
S. Jana, A.S. Vuk, A. Mallick, B. Orel, P.K. Biswas, Effect of boron doping on optical properties of sol–gel based nanostructured zinc oxide films on glass. Mater. Res. Bull. 46, 2392–2397 (2011)
M. Caglar, S. Ilican, Y. Caglar, F. Yakuphanoglu, Boron doped nanostructure ZnO films onto ITO substrate. J. Alloys Compd. 509, 3177–3182 (2011)
B.J. Lokhande, P.S. Patil, M.D. Uplane, Studies on structural, optical and electrical properties of boron doped zinc oxide films prepared by spray pyrolysis technique. Phys. B 302–303, 59–63 (2001)
B.N. Pawar, S.R. Jadkar, M.G. Takwale, Deposition and characterization of transparent and conductive sprayed ZnO:B thin films. J. Phys. Chem. Solids 66, 1779–1782 (2005)
S.Y. Myong, J. Steinhauser, R. Schluchter, S. Fay, E. Vallat-Sauvain, A. Shah, C. Ballif, A. Rufenacht, Temperature dependence of the conductivity in large-grained boron-doped ZnO films. Sol. Energy Mater. Sol. Cells 91, 1269–1274 (2007)
S. Fay, U. Kroll, C. Bucher, E. Vallat-Sauvain, A. Shah, Low pressure chemical vapour deposition of ZnO layers for thin-film solar cells: temperature-induced morphological changes. Sol. Energy Mater. Sol. Cells 86, 385–397 (2005)
I. Iwantono, W. Nurwidya, L.R. Lestari, F.Y. Naumar, S. Nafisah, A.A. Umar, M.Y.A. Rahman, M.M. Salleh, Effect of growth temperature and time on ZnO films properties and the performance of dye-sensitized solar cell. J. Solid State Electrochem. 19, 1217–1221 (2015)
L. Roza, M.Y.A. Rahman, A.A. Umar, M.M. Salleh, Direct growth of oriented ZnO nanotubes by self-selective etching at lower temperature for photo-electrochemical (PEC) solar cell application. J. Alloys Compd. 618, 153–158 (2015)
M.Y.A. Rahman, L. Roza, A.A. Umar, M.M. Salleh, Effect of acid boric composition on the properties of ZnO thin film nanotubes and the performance of dye-sensitized solar cell (DSSC). J Alloys Compd. 648, 86–91 (2015)
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This work was supported by The Ministry of higher Education of Malaysia under research Grant FRGS/2/2013/SG02/UKM/02/5, FRGS/2/2013/SG02/UKM/02/8 and GUP-2013-030.
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Rahman, M.Y.A., Roza, L., Umar, A.A. et al. Effect of dimethyl borate composition on the performance of boron doped ZnO dye-sensitized solar cell (DSSC). J Mater Sci: Mater Electron 27, 2228–2234 (2016). https://doi.org/10.1007/s10854-015-4015-y
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DOI: https://doi.org/10.1007/s10854-015-4015-y