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Enhanced multiferroic properties of Nd and Co co-doped BiFeO3 ceramics

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Abstract

The Nd and Co co-doped Bi1−x Nd x Fe0.96Co0.04O3 (x = 0.02–0.20) powders and ceramics were synthesized by a modified solid state method. The structure distortion was observed from rhombohedral into orthorhombic phase by X-ray diffraction. The enhanced ferroelectric and ferromagnetic behavior of the ceramics was obtained by Nd and Co co-doping. With increasing Nd concentration, the remnant polarization and the remnant magnetization were improved. When x = 0.1, the co-doped Bi1−x Nd x Fe0.96Co0.04O3 ceramics possessed the largest remnant polarization of 11.77 μC/cm2. When x = 0.15, the largest remnant magnetization reached to 0.3319 emu/g. The relationship between the multiferroic properties and A, B site co-substitution was investigated.

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References

  1. C.W. Nan, M.I. Bichurin, S.X. Dong, D. Viehland, G. Srinivasan, J. Appl. Phys. 103, 031101-1–031101-35 (2008)

    Article  Google Scholar 

  2. C. Ederer, N.A. Spaldin, Phys. Rev. B 71, 224103-1–224103-9 (2005)

    Google Scholar 

  3. N.A. Hill, J. Phys. Chem. B 104, 6694–6709 (2000)

    Article  Google Scholar 

  4. S.K. Pradhan, J. Mater. Sci.: Mater. Electron. 24, 3581–3586 (2013)

    Google Scholar 

  5. S. Pattanayak, R.N.P. Choudhary, S.R. Shannigrahi, P.R. Das, R. Padhee, J. Magn. Magn. Mater. 341, 158–164 (2013)

    Article  Google Scholar 

  6. S.C. Yang, A. Kumar, V. Petkov, S. Priya, J. Appl. Phys. 113, 144101-1–144101-5 (2013)

    Google Scholar 

  7. G.L. Yuan, S.W. Or, J.M. Liu, Z.G. Liu, Appl. Phys. Lett. 89, 0529051–0529053 (2006)

    Google Scholar 

  8. R. Koferstein, J. Alloys Compd. 590, 324–330 (2014)

    Article  Google Scholar 

  9. N.A. Hill, A. Filippetti, J. Magn. Magn. Mater. 242–245, 976–979 (2002)

    Article  Google Scholar 

  10. G. Catalan, J.F. Scott, Adv. Mater. 21, 2463–2485 (2009)

    Article  Google Scholar 

  11. G.S. Lotey, N.K. Verma, J. Nanopart. Res. 14, 742-1–742-11 (2012)

    Article  Google Scholar 

  12. N. Jeon, D. Rout, I.W. Kim, S.-J.L. Kang, Appl. Phys. Lett. 98, 072901-1–072901-3 (2011)

    Google Scholar 

  13. Q. Zhang, X.H. Zhu, Y.H. Xu, H.B. Gao, Y.J. Xiao, D.Y. Liang, J.L. Zhu, J.G. Zhu, D.Q. Xiao, J. Alloys Compd. 546, 57–62 (2013)

    Article  Google Scholar 

  14. G. Schileo, Prog. Solid State Chem. 41, 87–98 (2013)

    Article  Google Scholar 

  15. C. Ponzoni, R. Rosa, M. Cannio, V. Buscaglia, E. Finocchio, P. Nanni, C. Leonelli, J. Alloys Compd. 558, 150–159 (2013)

    Article  Google Scholar 

  16. Z.Q. Hu, M.Y. Li, Y. Yu, J. Liu, L. Pei, J. Wang, X.L. Liu, B.F. Yu, X.Z. Zhao, Solid State Commun. 150, 1088–1091 (2010)

    Article  Google Scholar 

  17. X.H. Zheng, P.J. Chen, N. Ma, Z.H. Ma, D.P. Tang, J. Mater. Sci.: Mater. Electron. 23, 990–994 (2012)

    Google Scholar 

  18. Z.W. Chen, W.L. Jin, J. Mater. Sci.: Mater. Electron. 25, 4039–4045 (2014)

    Google Scholar 

  19. M.H. Basiri, H. Shokrollahi, G. Isapour, J. Magn. Magn. Mater. 354, 184–189 (2014)

    Article  Google Scholar 

  20. M. Arora, P.C. Sati, S. Chauhan, H. Singh, K.L. Yadav, S. Chhoker, M. Kumar, Mater. Lett. 96, 71–73 (2013)

    Article  Google Scholar 

  21. X.J. Xi, S.Y. Wang, W.F. Liu, H.J. Wang, F. Guo, X. Wang, J. Gao, D.J. Li, J. Magn. Magn. Mater. 355, 259–264 (2014)

    Article  Google Scholar 

  22. Q. Xu, H. Zai, D. Wu, T. Qiu, M.X. Xu, Appl. Phys. Lett. 95, 112510-1–112510-3 (2009)

    Google Scholar 

  23. J.M. Xu, G.L. Ye, M. Zeng, J. Alloys Compd. 587, 308–312 (2014)

    Article  Google Scholar 

  24. R.D. Shannon, Acta Cryst. A 32, 751–767 (1976)

    Article  Google Scholar 

  25. S. Karimi, I.M. Reaney, E. Levin, I. Sterianou, Appl. Phys. Lett. 94, 112903-1–112903-3 (2009)

    Google Scholar 

  26. J.A. Dean, Lange’s handbook of chemistry, 15th edn. (McGraw-Hill, New York, 1999)

    Google Scholar 

  27. G.D. Hu, S.H. Fan, C.H. Yang, W.B. Wu, Appl. Phys. Lett. 92, 192905-1–192905-3 (2008)

    Google Scholar 

  28. V.A. Khomchenko, D.V. Karpinsky, A.L. Kholkin, N.A. Sobolev, G.N. Kakazer, J.P. Araoujo, I.O. Trovanchuk, B.F.O. Costa, J.A. Paixao, J. Appl. Phys. 108, 074109-1–074109-5 (2010)

    Article  Google Scholar 

  29. Y. Yao, W. Liu, C.L. Mak, J. Alloys Compd. 527, 157–162 (2012)

    Article  Google Scholar 

  30. I. Levin, S. Karimi, V. Provenzano, C.L. Dennis, H. Wu, T.P. Comyn, T.J. Stevenson, R.I. Smith, I.M. Reaney, Phys. Rev. B 81, 020103-1–020103-4 (2010)

    Google Scholar 

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Acknowledgments

This work is supported by the National Natural Science Foundation of China (Grant No. 61271141).

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Correspondence to Jianmei Xu.

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Xu, J., Ye, G., Zeng, M. et al. Enhanced multiferroic properties of Nd and Co co-doped BiFeO3 ceramics. J Mater Sci: Mater Electron 26, 6907–6912 (2015). https://doi.org/10.1007/s10854-015-3308-5

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