Abstract
Gas-sensing performances can often be enhanced significantly once the size of sensing nanomaterials approaches a critical value of 15 nm. Here, we synthesize, by a simple hydrothermal method accompanied by the calcination process, ultrathin ZnO nanosheets with a thickness as thin as 10–13 nm. We find that the prepared zinc hydroxide carbonate precursor is largely agglomerated, yet transformed to the ultrathin ZnO nanosheets in a dispersive fashion after the calcination process. The as-prepared ultrathin nanosheets exhibit excellent gas-sensing functions to ethanol gas at the optimal temperature as low as 300 °C under the concentration of 50 ppm, rendering them a promising sensing material for the on-site detection of ethanol.
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References
X.H. Lu, D. Wang, J.R. Li, C.Y. Su, D.B. Kuang, Y.X. Tong, J. Phys. Chem. C 113, 13574–13582 (2009)
Y.H. Tong, J. Cheng, Y.L. Liu, G.G. Siu, Scr. Mater. 60, 1093–1096 (2009)
Y.X. Wang, X.Y. Li, G. Lu, G.H. Chen, Y.Y. Chen, Mater. Lett. 62, 2359–2362 (2008)
W.W. Guo, T.M. Liu, W. Zeng, D.J. Liu, Y. Chen, Z.C. Wang, Mater. Lett. 65, 3384–3387 (2011)
X. Liu, J. Zhang, L. Wang, T. Yang, X. Guo, S. Wu, S. Wang, J. Mater. Chem. 21, 349–356 (2011)
C. Woell, Prog. Surf. Sci. 82, 55–120 (2007)
T.G. You, J.F. Yan, Z.Y. Zhang, J. Li, J.X. Tian, J.N. Yun, W. Zhao, Mater. Lett. 66, 246–249 (2012)
F. Lu, W.P. Cai, Y.G. Zhang, Adv. Funct. Mater. 18, 1047–1056 (2008)
B.X. Li, Y.F. Wang, J. Phys. Chem. C 114, 890–896 (2010)
C. Xu, J. Tamaki, N. Miura, N. Yamazoe, Sens. Actuators B 3, 147–155 (1991)
N. Yamazoe, Sens. Actuators B 5, 7–19 (1991)
N. Hongsith, E. Wongrat, T. Kerdcharoen, S. Choopun, Sens. Actuators B 144, 67–72 (2010)
Y. Zeng, T. Zhang, L. Qiao, Mater. Lett. 63, 843–846 (2009)
J.H. Lee, Sens. Actuators B 140, 319–336 (2009)
A. Rothschild, Y. Komem, J. Appl. Phys. 95, 6374–6380 (2004)
F. Gyger, C. Hubner, C. Feldmann, N. Barsan, U. Weimar, Chem. Mater. 22, 4821–4827 (2010)
W.W. Guo, T.M. Liu, H.J. Zhang, R. Sun, Y. Chen, W. Zeng, Z.C. Wang, Sens. Actuators B 166, 492–499 (2012)
L.F. Liu, W. Wang, Q. Peng, Y.D. Li, Adv. Mater. 17, 764–767 (2005)
H. Gong, J.Q. Hu, J.H. Wang, C.H. Ong, F.R. Zhu, Sens. Actuators B 115, 247–251 (2006)
G. Neri, A. Bonavita, G. Micali, G. Rizzo, E. Callone, G. Carturan, Sens. Actuators B 132, 224–233 (2008)
N. Yamazoe, G. Sakai, K. Shimanoe, Catal. Surv. Asia 7, 63–75 (2003)
D.J. Liu, T.M. Liu, C.L. Lv, W. Zeng, J. Mater. Sci. Mater. Electron. 23, 576–581 (2012)
A.D. Garje, R.C. Aiyer, J. Mater. Sci. Mater. Electron. 19, 547–552 (2008)
V.V. Sysoev, J. Goschnick, T. Schneider, E. Strelcov, A. Kolmakov, Nano Lett. 7, 3182–3188 (2007)
Acknowledgments
This work was supported in part by National Natural Science of China (51202302) and China Postdoctoral Science Foundation (No. 2012M511904). Z.W. appreciates financial supports from the Grant-in-Aid for Young Scientists (A) (grant no. 24686069) and the Challenging Exploratory Research (grant no. 24656376).
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Guo, W., Liu, T., Gou, Z. et al. Hydrothermal synthesis of ultrathin ZnO nanosheets and their gas-sensing properties. J Mater Sci: Mater Electron 24, 1764–1769 (2013). https://doi.org/10.1007/s10854-012-1009-x
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DOI: https://doi.org/10.1007/s10854-012-1009-x