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Low temperature sintering and properties of lead-free (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 ceramics with Ba(Cu0.5W0.5)O3 addition

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Abstract

The low-temperature sintering behavior of (Ba0.85Ca0.15)(Zr0.10Ti0.90)O3 (BCZT) piezoelectric ceramics with Ba(Cu0.5W0.5)O3 (BCW) addition has been investigated. The addition of 0.1 wt% BCW promotes the sinterability of BCZT ceramics owing to the generation of a liquid phase, resulting in a reduction of sintering temperature from 1,540 to 1,350 °C. The piezoelectric coefficient (d 33), and the electromechanical coupling factor (kp) of the BCZT − 0.1 wt%BCW specimen sintered at 1,350 °C were 555 pC/N and 55 %, respectively, while Curie temperature (Tc) increases from 85 to 95 °C.

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Acknowledgments

This work was supported by the programs from the National Nature Science Foundation of China (No. 51102056) and Guangxi Nature Science Foundations of China (No. 2010GXNSFD013007, 2011GXNSFB018008), and Program for Excellent Talents in Guangxi Higher Education Institutions, and Research Program of Guangxi Education Department (201012MS085).

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Correspondence to Wenhua Li.

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Li, W., Liu, X., Ma, J. et al. Low temperature sintering and properties of lead-free (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 ceramics with Ba(Cu0.5W0.5)O3 addition. J Mater Sci: Mater Electron 24, 1551–1555 (2013). https://doi.org/10.1007/s10854-012-0971-7

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  • DOI: https://doi.org/10.1007/s10854-012-0971-7

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