Preparation and magnetic properties of Ni–Zr doped barium strontium hexaferrite

Abstract

M-type Hexaferrites B_0.5Sr_0.5Fe_12−2x Ni _x Zr _x O₁₉ were synthesized and investigated. The XRD patterns show single phase of the magnetoplumbite barium strontium ferrite and no other phases were present. The samples exhibit well defined crystallization; all of them are hexagonal platelet grains. As the substitution level increased from x = 0.2 to 0.8 mol%, the grains are agglomerated and the average diameter increased. This suggests that Ni–Zr substitution increases the grain size, as observed in the FE-SEM micrographs. The results of magnetic measurement revealed that M_s of barium strontium hexaferrite increased when the value of x increased from 0 to 0.4 mol% and then decreased with the increasing Ni–Zr content. The H_c decreases remarkably with increasing Ni and Zr ions content. Hard magnetic material is converted into soft magnetic material when the substitution level is increased from 0.2 to 0.8 mol%. In particular, Ba_0.5Sr_0.5Fe_12−2x Ni _x Zr _x O₁₉ with x = 0.2, 0.4, 0.6, 0.8 mol% has suitable magnetic characteristics with particle size small enough for high-density magnetic recording applications.