Abstract
In the present work a chemical reduction method is followed to grow CdS nanoparticles at room temperature with varying the amount of reducing agent sodiumborohydride. The dispersed samples in ethanol are characterized using electron diffraction techniques. Simultaneously optical absorption, photoluminescence and longtime photorelaxation of these samples are studied at room temperature. An increase in band gap is observed in each case as compared to bulk CdS. Also particle size decreases with increased amount of reducing agent. Simultaneously long time relaxation increases with decrease of stoichiometric ratio of reducing agent. An attempt is made to correlate the structural, optical, electrical and opto-electrical properties.
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References
A.P. Alivisatos, Science 271, 933 (1996)
X.G. Peng, L. Manna, W.D. Yang, J. Wickham, E. Scher, A. Kadavanich, A.P. Alivisatos, Nature 404, 59 (2000)
M.G. Bawendi, M.L. Steigerwald, L.E. Brus, Annu. Rev. Phys. Chem. 41, 477 (1990)
T. Trindade, P.O. Brien, N.L. Pickett, Chem. Mater. 13, 3843 (2001)
M.G. Bawendi, P.J. Caroll, W.L. Wilson, L.E. Brus, J. Chem. Phys. 96, 1335 (1992)
V.L. Colvin, M.C. Schlamp, A.P. Alivisatos, Nature 370, 354 (1994)
W.U. Huynh, J.J. Dittmer, A.P. Alivisatos, Science 295, 2425 (2002)
C.T. Tsai, D.S. Chouu, S.L. Yang, J. Appl. Phys. 79, 9105 (1996)
N. Tessler, V. Medvedev, M. Kazes, U. Banin, Science 295, 1506 (2002)
H. Mattoussi, L.H. Radzilowski, L.O. Dabbousi, E.L. Thomus, M.G. Bawendi, M.F. Rubner, J. Appl. Phys. 83, 7965 (1998)
T. Taguchi, Y. Endoh, Y. Nozue, Appl. Phys. Lett. 56, 342 (1991)
S.H. Sun, C.B. Murray, J. Appl. Phys. 85, 4325 (1999)
R. Rosseti, J.L. Ellison, J.M. Gibson, L.E. Brus, J. Chem. Phys. 80, 552 (1984)
Y. Wang, N. Herron, J. Phys. Chem. 95, 525 (1991)
T. Trindade, P.O. Brien, X. Zhang, Chem. Matter. 9, 523 (1997)
S. Yu, Y. Wu, J. Yang, Z. Han, Y. Quan, X. Liu, Y. Xie, Chem. Matter. 10, 2309 (1998)
C.B. Murray, D.J. Norris, M.G. Bawendi, J. Am. Chem. Soc. 115, 8706 (1993)
Y.D. Li, H.W. Liao, Y.T. Qian, Y. Ding, Y. Fan, Y. Zhang, Inorg. Chem. 38, 138 (1999)
G. Henshaw, P. Parkin, G. Shaw, J. Mater. Sci. Lett. 15, 1741 (1996)
W. Wang, I. Germanenko, M.S. El-Shall, Chem. Matter. 14, 3028 (2002)
A.P. Alivisatos, J. Phys. Chem. 100, 13226 (1996)
S. Okamoto, Y. Kanemitsu, H. Hosokawa, K. Murakoshi, S. Yanagida, Solid State Commun. 101, 7 (1998)
N. Chestnoy, T.D. Harris, R. Hull, L.E. Brus, J. Phys. Chem. 90, 3393 (1986)
Acknowledgments
Authors are acknowledging Department of Physics of Vidyasagar University for XRD measurement. Authors are thankful to IIT Kharagpur for graciously allow the use of TEM measurement.
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Bhattacharya, R., Das, T.K. & Saha, S. Synthesis and characterization of CdS nanoparticles. J Mater Sci: Mater Electron 22, 1761–1765 (2011). https://doi.org/10.1007/s10854-011-0359-0
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DOI: https://doi.org/10.1007/s10854-011-0359-0