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Facile fabrication of compressible, magnetic and superhydrophobic poly(DVB-MMA) sponge for high-efficiency oil–water separation

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Abstract

Oil spills cause serious environmental pollution and serious waste of resources, hydrophobic porous absorbent has been deemed as a simple, low-cost, efficient and environment-friendly in oil–water separation. In this paper, a facile emulsion template method was developed to fabricate an interconnected porous poly(DVB-MMA) sponge. A novel co-Pickering stabilization system of Span 80 and NiFe2O4 nanoparticles was applied to fabricate ultra-concentrated internal phase W/O emulsions. After further polymerization, the resulting sponge showed excellent adsorption selectivity due to superhydrophobicity and superlipophilicity. Also, the characterization results exhibited that the composite had superior thermal stability, low density, high porosity and flexible three-dimensional porous structure. Besides, waste PS plastic was introduced to enhance the structural integrity of composite, and the addition of NiFe2O4 provided the material with magnetic operability. High oil adsorption capacity (up to 44.3–101.0 g/g), high oil retention, fast adsorption rate and superior recyclability allowed the material to be used in the fields of oil–water separation and oil pollution treatment.

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Funding

This research was funded by [Colleges Innovation Project of Guangdong Province], grant number [2017KQNCX093], [Science and Technology Plan Project of Zhanjiang City], grant number [2018A01042], [College Student Innovation and Entrepreneurship Training Program of Guangdong Ocean University], grant number [CXXL2018108, CXXL2019300, CXXL2020294, CXXL2020301], [Guangdong Climbing Project], grant number [pdjh2020a0271], and [Innovation University Program of Guangdong Ocean University], grant number [Q18304]. The APC was funded by [Scientific Research Start-up Funds of Guangdong Ocean University], grant number [R18018].

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Authors and Affiliations

  1. Faculty of Chemistry and Environmental Science, Guangdong Ocean University, Zhanjiang, 524088, People’s Republic of China

    Chuanming Yu, Jin’e Jiang, Yeyuan Liu, Ke Liu, Ziqing Situ, Lifen Tian, Wenjing Luo, Pengzhi Hong & Yong Li

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Yu, C., Jiang, J., Liu, Y. et al. Facile fabrication of compressible, magnetic and superhydrophobic poly(DVB-MMA) sponge for high-efficiency oil–water separation. J Mater Sci 56, 3111–3126 (2021). https://doi.org/10.1007/s10853-020-05471-z

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