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Anti-corrosion reinforcement of waterborne polyurethane coating with polymerized graphene oxide by the one-pot method

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Abstract

The research and preparation of excellent anti-corrosion coatings is still a difficult task and critical to practical applications. In this paper, phosphoric acid, dodecylbenzenesulfonic acid (DBSA), and polyaniline (PANI) were polymerized in-situ onto graphene oxide (GO) by the one-pot method to prepare dodecylbenzenesulfonic acid-PANI/phosphorylated graphene oxide (DPPGO). The results of TEM, FTIR, Raman spectrum, XRD, TGA, and XPS analysis showed that the DPPGO was successfully prepared. The SEM observations showed that DPPGO has best dispersibility and compatibility than GO and PANI/phosphorylated graphene oxide (PPGO) in waterborne polyurethane (WPU) matrix. To achieve anti-corrosion performance, a new type of graphene-based polymer nanocomposites water-based coating was developed and tested by electrochemical measurements. Through a series of electrochemical tests, it is concluded that the anti-corrosion performance of a composite coating DPPGO is significantly improved. The excellent anti-corrosion properties are due to the perfect dispersion and good compatibility of DPPGO in WPU.

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Acknowledgements

The authors gratefully acknowledge financial support from the Natural Science Foundation of Tianjin China (Grant No. 19JCZDJC37800).

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Authors and Affiliations

  1. Tianjin Key Laboratory of Advanced Fibers and Energy Storage, School of Material Science and Engineering, Tiangong University, Tianjin, 300387, China

    Yu-Jie Ning, Ze-Ru Zhu, Wei-Wei Cao, Lei Wu, Li-Chao Jing, Tao Wang, Xiao-Tong Yuan, Ling-Hong Teng, Peng-Shuai Bin & Hong-Zhang Geng

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  1. Yu-Jie Ning
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  2. Ze-Ru Zhu
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Correspondence to Wei-Wei Cao or Hong-Zhang Geng.

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Ning, YJ., Zhu, ZR., Cao, WW. et al. Anti-corrosion reinforcement of waterborne polyurethane coating with polymerized graphene oxide by the one-pot method. J Mater Sci 56, 337–350 (2021). https://doi.org/10.1007/s10853-020-05243-9

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