Abstract
Rationally designing noble-metal-free metallic cocatalysts modified graphitic carbon nitride (g-C3N4) as heterostructured photocatalysts is an efficient strategy for enhancing photocatalytic hydrogen (H2) evolution. Herein, uniform molybdenum diselenide (MoSe2) nanoparticles were synthesized through a simple solvothermal approach, and the MoSe2 nanoparticles anchored g-C3N4 nanosheets were subsequently prepared by a solution-phase strategy. The resulting MoSe2/g-C3N4 nanocomposite displayed good performance toward visible-light photocatalytic H2 production. The optimal amount of MoSe2 nanoparticles was 7% of composite by weight, displaying the highest H2 production rate of 287.3 μmol h−1 g−1. The excellent photocatalytic performance of the MoSe2/g-C3N4 hybrids was ascribed to the introduction of MoSe2 nanoparticles, which facilitated the charge separation and dramatically promoted the photoelectron transport. The insight into the charge transfer through the interface between MoSe2 nanoparticles and g-C3N4 nanosheets was revealed by photoluminescence spectra, electrochemical and photoelectrochemical experiments. This work provides solid evidence that MoSe2 nanoparticles can be a promising cocatalyst loaded g-C3N4 for enhanced photocatalytic performance.
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Hosseini SE, Wahid MA (2016) Hydrogen production from renewable and sustainable energy resources: promising green energy carrier for clean development. Renew Sust Energ Rev 57:850–866
Wang Q, Hisatomi T, Suzuki Y, Pan Z, Seo J, Katayama M, Minegishi T, Nishiyama H, Takata T, Seki K, Kudo A, Yamada T, Domen K (2017) Particulate photocatalyst sheets based on carbon conductor layer for efficient Z-scheme pure-water splitting at ambient pressure. J Am Chem Soc 139:1675–1683
Qi K, Cheng B, Yu J, Ho W (2017) A review on TiO2-based Z-scheme photocatalysts. Chin J Catal 38:1936–1955
Meng A, Zhang L, Cheng B, Yu J (2019) Dual cocatalysts in TiO2 photocatalysis. Adv Mater. 46:1807660
Cheng L, Xiang Q, Liao Y, Zhang H (2018) CdS-based photocatalysts. Energy. Environ Sci 11:1362–1391
Li Q, Li X, Wageh S, Al-Ghamdi AA, Yu J (2015) CdS/graphene nanocomposite photocatalysts. Adv Energy Mater 5:1500010
Ong W-J, Tan L-L, Ng YH, Yong S-T, Chai S-P (2016) Graphitic carbon nitride (g-C3N4)-based photocatalysts for artificial photosynthesis and environmental remediation: Are we a step closer to achieving sustainability? Chem Rev 116:7159–7329
Masih D, Ma Y, Rohani S (2017) Graphitic C3N4 based noble-metal-free photocatalyst systems: a review. Appl Catal B: Environ 206:556–588
Wen J, Xie J, Chen X, Li X (2017) A review on g-C3N4-based photocatalysts. Appl Surf Sci 391:72–123
Xu X, Tian X, Sun B, Liang Z, Cui H, Tian J, Shao M (2020) 1 T-phase molybdenum sulfide nanodots enable efficient electrocatalytic nitrogen fixation under ambient conditions. Appl Catal B: Environ 272:118984
Zhang M, Wang X (2014) Two dimensional conjugated polymers with enhanced optical absorption and charge separation for photocatalytic hydrogen evolution. Energy Environ Sci 7:1902–1906
Ye S, Wang R, Wu M-Z, Yuan Y-P (2015) A review on g-C3N4 for photocatalytic water splitting and CO2 reduction. Appl Surf Sci 358:15–27
Mousavi M, Habibi-Yangjeh A (2018) Integration of NiWO4 and Fe3O4 with graphitic carbon nitride to fabricate novel magnetically recoverable visible-light-driven photocatalysts. J Mater Sci 53:9046–9063
Zhang J, Zhang M, Sun RQ, Wang X (2012) A facile band alignment of polymeric carbon nitride semiconductors to construct isotype heterojunctions. Angew Chem Int Ed 51:10145–10149
Jo W-K, Selvam NCS (2017) Z-scheme CdS/g-C3N4 composites with RGO as an electron mediator for efficient photocatalytic H2 production and pollutant degradation. Chem Eng J 317:913–924
Cheng F, Yin H, Xiang Q (2017) Low-temperature solid-state preparation of ternary CdS/g-C3N4/CuS nanocomposites for enhanced visible-light photocatalytic H2-production activity. Appl Surf Sci 391:432–439
Tian J, Chen Z, Jing J, Feng C, Sun M, Li W (2020) Enhanced photocatalytic performance of the MoS2/g-C3N4 heterojunction composite prepared by vacuum freeze drying method. J Photochem Photobiol A: Chem 390:112260
Xu C, Wang J, Gao B, Dou M, Chen R (2019) Synergistic adsorption and visible-light catalytic degradation of RhB from recyclable 3D mesoporous graphitic carbon nitride/reduced graphene oxide aerogels. J Mater Sci 54:8892–8906
Zhang J, Zhang G, Chen X, Lin S, Möhlmann L, Dołęga G, Lipner G, Antonietti M, Blechert S, Wang X (2012) Co-monomer control of carbon nitride semiconductors to optimize hydrogen evolution with visible light. Angew Chem Int Ed 51:3183–3187
Zhou Y, Zhang L, Huang W, Kong Q, Fan X, Wang M, Shi J (2016) N-doped graphitic carbon-incorporated g-C3N4 for remarkably enhanced photocatalytic H2 evolution under visible light. Carbon 99:111–117
Zhang G, Zhang M, Ye X, Qiu X, Lin S, Wang X (2014) Iodine modified carbon nitride semiconductors as visible light photocatalysts for hydrogen evolution. Adv Mater 26:805–809
Zeng D, Zhou T, Ong W-J, Wu M, Duan X, Xu W, Chen Y, Zhu Y-A, Peng D-L (2019) Sub-5 nm ultra-fine FeP nanodots as efficient co-catalysts modified porous g-C3N4 for precious-metal-free photocatalytic hydrogen evolution under visible light. ACS Appl Mater Interfaces 11:5651–5660
Cao S, Wang CJ, Fu WF, Chen Y (2017) Metal phosphides as co-catalysts for photocatalytic and photoelectrocatalytic water splitting. Chemsuschem 10:4306–4323
Tong Z, Yang D, Li Z, Nan Y, Ding F, Shen Y, Jiang Z (2017) Thylakoid-inspired multishell g-C3N4 nanocapsules with enhanced visible-light harvesting and electron transfer properties for high-efficiency photocatalysis. ACS Nano 11:1103–1112
Han Q, Wang B, Zhao Y, Hu C, Qu L (2015) A Graphitic-C3N4 “seaweed” architecture for enhanced hydrogen evolution. Angew Chem Int Ed 54:11433–11437
Ge J, Liu Y, Jiang D, Zhang L, Du P (2019) Integrating non-precious-metal cocatalyst Ni3N with g-C3N4 for enhanced photocatalytic H2 production in water under visible-light irradiation. Chin J Catal 40:160–167
Chen L, Huang H, Zheng Y, Sun W, Zhao Y, Francis PS, Wang X (2018) Noble-metal-free Ni3N/g-C3N4 photocatalysts with enhanced hydrogen production under visible light irradiation. Dalton Trans 47:12188–12196
He K, Xie J, Yang Z, Shen R, Fang Y, Ma S, Chen X, Li X (2017) Earth-abundant WC nanoparticles as an active noble-metal-free co-catalyst for the highly boosted photocatalytic H2 production over g-C3N4 nanosheets under visible light. Catal Sci Technol 7:1193–1202
He K, Xie J, Liu Z-Q, Li N, Chen X, Hu J, Li X (2018) Multi-functional Ni3C cocatalyst/g-C3N4 nanoheterojunctions for robust photocatalytic H2 evolution under visible light. J Mater Chem A 6:13110–13122
Zhang J, Wu M, He B, Wang R, Wang H, Gong Y (2019) Facile synthesis of rod-like g-C3N4 by decorating Mo2C co-catalyst for enhanced visible-light photocatalytic activity. Appl Surf Sci 470:565–572
Liu J, Jia Q, Long J, Wang X, Gao Z, Gu Q (2018) Amorphous NiO as co-catalyst for enhanced visible-light-driven hydrogen generation over g-C3N4 photocatalyst. Appl Catal B: Environ 222:35–43
Indra A, Acharjya A, Menezes PW, Merschjann C, Hollmann D, Schwarze M, Aktas M, Friedrich A, Lochbrunner S, Thomas A, Driess M (2017) Boosting visible-light-driven photocatalytic hydrogen evolution with an integrated nickel phosphide-carbon nitride system. Angew Chem Int Ed 56:1653–1657
Zeng D, Xu W, Ong W-J, Xu J, Ren H, Chen Y, Zheng H, Peng D-L (2018) Toward noble-metal-free visible-light-driven photocatalytic hydrogen evolution: Monodisperse sub-15 nm Ni2P nanoparticles anchored on porous g-C3N4 nanosheets to engineer 0D-2D heterojunction interfaces. Appl Catal B: Environ 221:47–55
Yuan Y-J, Shen Z, Wu S, Su Y, Pei L, Ji Z, Ding M, Bai W, Chen Y, Yu Z-T, Zou Z (2019) Liquid exfoliation of g-C3N4 nanosheets to construct 2D-2D MoS2/g-C3N4 photocatalyst for enhanced photocatalytic H2 production activity. Appl Catal B: Environ 246:120–128
Dong G, Qiu P, Meng F, Wang Y, He B, Yu Y, Liu X, Li Z (2020) Facile synthesis of sulfur-doped polymeric carbon nitride/MoS2 face-to-face heterojunction for highly efficient photocatalytic interfacial charge separation. Chem Eng J 384:123330
Liang Z, Xue Y, Guo Y, Zhang G, Cui H, Tian J (2020) Rationalizing and controlling the phase transformation of semi-metallic 1T′-phase and semi-conductive 2H-phase MoS2 as cocatalysts for photocatalytic hydrogen evolution. Chem Eng J 396:125344
Zhou Y, Ye X, Lin D (2019) One-pot synthesis of non-noble metal WS2/g-C3N4 photocatalysts with enhanced photocatalytic hydrogen production. Int J Hydrogen Energy 44:14927–14937
Jin Z, Zhang M, Wang M, Feng C, Wang Z-S (2017) Metal selenides as efficient counter electrodes for dye-sensitized solar cells. Acc Chem Res 50:895–904
Lu T, Dong S, Zhang C, Zhang L, Cui G (2017) Fabrication of transition metal selenides and their applications in energy storage. Coord Chem Rev 332:75–99
Wang F, Li Y, Shifa TA, Liu K, Wang F, Wang Z, Xu P, Wang Q, He J (2016) Selenium-enriched nickel selenide nanosheets as a robust electrocatalyst for hydrogen generation. Angew Chem Int Ed 55:6919–6924
Yin Y, Zhang Y, Gao T, Yao T, Zhang X, Han J, Wang X, Zhang Z, Xu P, Zhang P, Cao X, Song B, Jin S (2017) Synergistic phase and disorder engineering in 1T-MoSe2 nanosheets for enhanced hydrogen-evolution reaction. Adv Mater 29:1700311
Najafi L, Bellani S, Oropesa-Nuñez R, Ansaldo A, Prato M, Del Rio Castillo AE, Bonaccorso F (2018) Engineered MoSe2-based heterostructures for efficient electrochemical hydrogen evolution reaction. Adv Energy Mater 8:1703212
Zeng D, Xiao L, Ong W-J, Wu P, Zheng H, Chen Y, Peng D-L (2017) Hierarchical ZnIn2S4/MoSe2 nanoarchitectures for efficient noble-metal-free photocatalytic hydrogen evolution under visible light. Chemsuschem 10:4624–4631
Zeng D, Wu P, Ong W-J, Tang B, Wu M, Zheng H, Chen Y, Peng D-L (2018) Construction of network-like and flower-like 2H-MoSe2 nanostructures coupled with porous g-C3N4 for noble-metal-free photocatalytic H2 evolution under visible light. Appl Catal B: Environ 233:26–34
Ong W-J, Putri LK, Tan Y-C, Tan L-L, Li N, Ng YH, Wen X, Chai S-P (2017) Unravelling charge carrier dynamics in protonated g-C3N4 interfaced with carbon nanodots as co-catalysts toward enhanced photocatalytic CO2 reduction: a combined experimental and first-principles DFT study. Nano Res 10:1673–1696
He F, Chen G, Zhou Y, Yu Y, Li L, Hao S, Liu B (2016) ZIF-8 derived carbon (C-ZIF) as a bifunctional electron acceptor and HER cocatalyst for g-C3N4: construction of a metal-free, all carbon-based photocatalytic system for efficient hydrogen evolution. J Mater Chem A 4:3822–3827
Tian L, Min S, Wang F (2019) Integrating noble-metal-free metallic vanadium carbide cocatalyst with CdS for efficient visible-light-driven photocatalytic H2 evolution. Appl Catal B: Environ 259:118029
Cui Y, Ding Z, Liu P, Antonietti M, Fu X, Wang X (2012) Metal-free activation of H2O2 by g-C3N4 under visible light irradiation for the degradation of organic pollutants. PCCP 14:1455–1462
Zhou S, Liu Y, Li J, Wang Y, Jiang G, Zhao Z, Wang D, Duan A, Liu J, Wei Y (2014) Facile in situ synthesis of graphitic carbon nitride (g-C3N4)-N-TiO2 heterojunction as an efficient photocatalyst for the selective photoreduction of CO2 to CO. Appl Catal B: Environ 158:20–29
Xie D, Tang W, Wang Y, Xia X, Zhong Y, Zhou D, Wang D, Wang X, Tu J (2016) Facile fabrication of integrated three-dimensional C-MoSe2/reduced graphene oxide composite with enhanced performance for sodium storage. Nano Res 9:1618–1629
Wang X, Ma W, Xu Z, Wang H, Fan W, Zong X, Li C (2018) Metal phosphide catalysts anchored on metal-caged graphitic carbon towards efficient and durable hydrogen evolution electrocatalysis. Nano Energy 48:500–509
Zeng D, Lu Z, Gao X, Wu B, Ong WJ (2019) Hierarchical flower-like ZnIn2S4 anchored with well-dispersed Ni12P5 nanoparticles for high-quantum-yield photocatalytic H2 evolution under visible light. Catal Sci Technol 9:4010–4016
Shen R, Liu W, Ren D, Xie J, Li X (2019) Co1.4Ni0.6P cocatalysts modified metallic carbon black/g-C3N4 nanosheet Schottky heterojunctions for active and durable photocatalytic H2 production. Appl Surf Sci 466:393–400
Hu S, Li F, Fan Z, Wang F, Zhao Y, Lv Z (2015) Band gap-tunable potassium doped graphitic carbon nitride with enhanced mineralization ability. Dalton Trans 44:1084–1092
Zhao S, Zhang Y, Zhou Y, Fang J, Wang Y, Zhang C, Chen W (2018) Fabrication of sandwich-structured g-C3N4/Au/BiOCl Z-scheme photocatalyst with enhanced photocatalytic performance under visible light irradiation. J Mater Sci 53:6008–6020
Feng C, Chen Z, Hou J, Li J, Li X, Xu L, Sun M, Zeng R (2018) Effectively enhanced photocatalytic hydrogen production performance of one-pot synthesized MoS2 clusters/CdS nanorod heterojunction material under visible light. Chem Eng J 345:404–413
Liang Z, Bai X, Hao P, Guo Y, Xue Y, Tian J, Cui H (2019) Full solar spectrum photocatalytic oxygen evolution by carbon-coated TiO2 hierarchical nanotubes. Appl Catal B: Environ 243:711–720
Sun B, Liang Z, Qian Y, Xu X, Han Y, Tian J (2020) Sulfur vacancy-rich O-doped 1T-MoS2 nanosheets for exceptional photocatalytic nitrogen fixation over CdS. ACS Appl Mater Interfaces 12:7257–7269
Fu Y, Li Z, Liu Q, Yang X, Tang H (2017) Construction of carbon nitride and MoS2 quantum dot 2D/0D hybrid photocatalyst: direct Z-scheme mechanism for improved photocatalytic activity. Chin J Catal 38:2160–2170
Acknowledgements
This work was supported by the Scientific Research Startup Foundation of Guangxi University, Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, and the Project of Improving the Basic Ability of Young Teachers in Guangxi Colleges and Universities (No. 2019KY0001).
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Lu, Z., Zeng, D., Zheng, H. et al. Enhanced interfacial electron transfer and boosted visible-light photocatalytic hydrogen evolution activity of g-C3N4 by noble-metal-free MoSe2 nanoparticles. J Mater Sci 55, 13114–13126 (2020). https://doi.org/10.1007/s10853-020-04945-4
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DOI: https://doi.org/10.1007/s10853-020-04945-4