Abstract
A novel Bi2MoO6/reduced graphene oxide/BiOBr (Bi2MoO6/RGO/BiOBr) composite was successfully synthesized via a facile solvothermal synthesis and precipitation method. The Bi2MoO6/RGO/BiOBr composite was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, UV–vis diffuse reflectance spectroscopy (UV–vis DRS) and photoelectrochemical measurements. The photocatalytic properties were explored for removal of methylene blue (MB) and norfloxacin (NFX) under visible-light irradiation. The Bi2MoO6/RGO/BiOBr composite exhibits the highest degradation rate compared with Bi2MoO6, BiOBr and Bi2MoO6/BiOBr composite, and that removal ratios of MB and NFX were 96.93% and 78.12%, respectively. A Z-scheme catalytic mechanism suitable for the system was proposed based on the results of UV–vis DRS, free radical trapping experiments and M–S carve analysis, in which RGO as an electronic medium can accelerate electron transfer. It is noteworthy that the close contact interface structure promotes the separation of electrons and holes and improves the photocatalytic performance.
Similar content being viewed by others
References
Lin H (1999) The study of oxygen spillover and back spillover on Pt/TiO2 by a potential dynamic sweep method. Mol Catal 144(1):189–197
Legrini O, Oliveros E, Braun A-M (1993) Photochemical processes for water treatment. Chem Rev 93(2):671–698
Wei X-X, Chen C-M, Guo S-Q et al (2014) Advanced visible-light-driven photocatalyst BiOBr–TiO2–graphene composite with graphene as a nano-filler. J Mater Chem A 2(13):4667–4675
Zhang M, Shao C, Mu J et al (2011) One-dimensional Bi2MoO6/TiO2 hierarchical heterostructures with enhanced photocatalytic activity. CrystEngComm 14(2):605–612
Zhao S, Chen S, Yu H, Quan X (2012) g-C3N4/TiO2 hybrid photocatalyst with wide absorption wavelength range and effective photogenerated charge separation. Sep Purif Technol 99(8):50–54
Shang M, Wang W, Zhang L (2009) Preparation of BiOBr lamellar structure with high photocatalytic activity by CTAB as Br source and template. J Hazard Mater 167(1):803–809
Huo Y, Zhang J, Dai K, Li Q, Liang C (2019) All-solid-state artificial Z-scheme porous g-C3N4/Sn2S3-DETA heterostructure photocatalyst with enhanced performance in photocatalytic CO2 reduction. Appl Catal B Environ 241:528–538
Li Z, Wang X, Zhang J, Liang C, Lu L, Dai K (2019) Preparation of Z-scheme WO3(H2O)0.333/Ag3PO4 composites with enhanced photocatalytic activity and durability. Chin J Catal 40(3):326–334
Lv J, Zhang J, Liu J, Li Z, Dai K, Liang C (2017) Bi SPR-promoted Z-scheme Bi2MoO6/CdS-diethylenetriamine composite with effectively enhanced visible light photocatalytic hydrogen evolution activity and stability. ACS Sustain Chem Eng 6(1):696–706
Wang Z, Lv J, Zhang J, Dai K, Liang C (2017) Facile synthesis of z-scheme BiVO4/porous graphite carbon nitride heterojunction for enhanced visible-light-driven photocatalyst. Appl Surf Sci 430:595–602
Zhang S, Wang D (2015) Preparation of novel BiOBr/CeO2 heterostructured photocatalysts and their enhanced photocatalytic activity. RSC Adv 5(113):93032–93040
Xing Y, He Z, Que W (2016) Synthesis and characterization of ZnO nanospheres sensitized BiOBr plates with enhanced photocatalytic performances. Mater Lett 182:210–213
Shan L, Liu Y, Chen H (2017) An α-Bi2O3/BiOBr core–shell heterojunction with high photocatalytic activity. Dalton Trans 46(7):2310
Tian G, Chen Y, Zhou W et al (2010) Facile solvothermal synthesis of hierarchical flower-like Bi2MoO6 hollow spheres as high performance visible-light driven photocatalysts. J Mater Chem 21(3):887–892
Tian Y, Cheng F, Xiang Z et al (2014) Solvothermal synthesis and enhanced visible light photocatalytic activity of novel graphitic carbon nitride-Bi2MoO6 heterojunctions. Powder Technol 267(15):126–133
Xu Y, Zhang W (2013) Monodispersed Ag3PO4 nanocrystals loaded on the surface of spherical Bi2MoO6 with enhanced photocatalytic performance. Dalton Trans 42(4):1094–1101
Hu T, Yang Y, Dai K, Zhang J, Liang C (2018) A novel Z-scheme Bi2MoO6/BiOBr photocatalyst for enhanced photocatalytic activity under visible light irradiation. Appl Surf Sci 456(31):473–481
Wang Z, Hu T, Dai K, Zhang J, Liang C (2017) Construction of Z-scheme Ag3PO4/Bi2WO6 composite with excellent visible-light photodegradation activity for removal of organic contaminants. Chin J Catal 38(12):2021–2029
Lv J, Dai K, Zhang J, Lu L, Liang C, Geng L et al (2017) In situ controllable synthesis of novel surface plasmon resonance-enhanced Ag2WO4/Ag/Bi2MoO6 composite for enhanced and stable visible light photocatalyst. Appl Surf Sci 391:507–515
Zhang R, Cai Y, Zhu X (2019) A novel photocatalytic membrane decorated with PDA/RGO/Ag3PO4 for catalytic dye decomposition. Colloid Surface A 563:68–76
Zhang Y, Zhu Y, Yu J (2013) Enhanced photocatalytic water disinfection properties of Bi2MoO6–RGO nanocomposites under visible light irradiation. Nanoscale 5(14):6307–6310
Chen P-L, Chen I-W (2010) Reactive cerium (IV) oxide powders by the homogeneous precipitation method. J Am Ceram Soc 76(6):1577–1583
Wang S, Yang X, Zhang X (2017) A plate-on-plate sandwiched Z-scheme heterojunction photocatalyst: BiOBr–Bi2MoO6 with enhanced photocatalytic performance. Appl Surf Sci 391:194–201
Fu Y, Chen H, Sun X, Wang X (2012) Combination of cobalt ferrite and graphene: highperformance and recyclable visible-light photocatalysis. Appl Catal B Environ 111–112:280–287
Qiu F, Li W, Wang F et al (2017) In-situ synthesis of novel Z-scheme SnS2/BiOBr photocatalysts with superior photocatalytic efficiency under visible light. J Colloid Interface Sci 493:1–9
Kong L, Jiang Z, Xiao T (2011) Exceptional visible-light-driven photocatalytic activity over BiOBr–ZnFe2O4 heterojunctions. Chem Commun 47(19):5512–5514
Xie L-J, Ma J-F, Xu G-J (2008) Preparation of a novel Bi2MoO6 flake-like nanophotocatalyst by molten salt method and evaluation for photocatalytic decomposition of rhodamine B. Mater Chem Phys 110(2–3):197–200
Chen F, Yang Q, Li X et al (2017) Hierarchical assembly of graphene-bridged Ag3PO4/Ag/BiVO4 (040) Z-scheme photocatalyst: An efficient, sustainable and heterogeneous catalyst with enhanced visible-light photoactivity towards tetracycline degradation under visible light irradiation. Appl Catal B Environ 200:330–342
Liu Y, Yang ZH, Song PP et al (2018) Facile synthesis of Bi2MoO6/ZnSnO3 heterojunction with enhanced visible light photocatalytic degradation of methylene blue. Appl Surf Sci 430:561–570
Li H, Li W, Wang F, Liu F et al (2018) Fabrication of Pt nanoparticles decorated Gd-doped Bi2MoO6 nanosheets: design, radicals regulating and mechanism of Gd/Pt–Bi2MoO6 photocatalyst. Appl Surf Sci 427:1046–1053
Xu Y-S, Zhang W-D et al (2013) Anion exchange strategy for construction of sesame-biscuit-like Bi2O2CO3/Bi2MoO6 nanocomposites with enhanced photocatalytic activity. Appl Catal B Environ 140–141(8):306–316
Zhang M, Shao C, Mu J, Zhang Z et al (2012) One-dimensional Bi2MoO6/TiO2 hierarchical heterostructures with enhanced photocatalytic activity. CrystEngComm 14:605–612
Wang Z, Zhang J, Lv J, Dai K, Liang C (2017) Plasmonic Ag2MoO4/AgBr/Ag composite excellent photocatalytic performance and possible photocatalytic mechanism. Appl Surf Sci 396:791–798
Meng X, Zhang Z (2016) Plasmonic ternary Ag–rGO–Bi2MoO6 composites with enhanced visible light-driven photocatalytic activity. J Catal 344:616–630
Luo Y, Huang Q, Li B et al (2017) Synthesis and characterization of Cu2O-modified Bi2O3 nanospheres with enhanced visible light photocatalytic activity. Appl Surf Sci 357:1072–1079
Ma D, Wu J, Gao M, Xin Y, Chai C (2017) Enhanced debromination and degradation of 2, 4-dibromophenol by an Z-scheme Bi2MoO6/CNTs/g-C3N4 visible light photocatalyst. Chem Eng J 316:461–470
Jia Y, Ma Y, Tang J, Shi W (2018) Hierarchical nanosheet-based Bi2MoO6 microboxes for efficient photocatalytic performance. Dalton Trans 47:5542–5547
Shi Q, Zhao W, Xie L et al (2016) Enhanced visible-light driven photocatalytic mineralization of indoor toluene via a BiVO4/reduced graphene oxide/Bi2O3 all-solid-state Z-scheme system. J Alloys Compd 662:108–117
Xu B, He P, Liu H et al (2014) A 1D/2D helical CdS/ZnIn2S4 nano-heterostructure. Angew Chem Int Ed 126:2339–2343
Song S, Meng A, Jiang S, Cheng B, Jiang C (2017) Construction of Z-scheme Ag2CO3/N-doped graphene photocatalysts with enhanced visible-light photocatalytic activity by tuning the nitrogen species. Appl Surf Sci 396:1368–1374
Xu D, Cheng B, Wang W et al (2018) Ag2CrO4/g-C3N4/graphene oxide ternary nanocomposite Z-scheme photocatalyst with enhanced CO2, reduction activity. Appl Catal B Environ 231:368–380
Cai T, Liu Y, Wang L, Zhang S et al (2017) Silver phosphate-based Z-scheme photocatalytic system with superiorsunlight photocatalytic activities and anti-photocorrosion performance. Appl Catal B Environ 208:1–13
Liu Y, Wang R, Yang Z et al (2015) Enhanced visible-light photocatalytic activity of Z-scheme graphitic carbon nitride/oxygen vacancy-rich zinc oxide hybrid photocatalysts. Chin J Catal 36(12):2135–2144
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zhang, R., Han, Q., Li, Y. et al. Fabrication and characterization of high efficient Z-scheme photocatalyst Bi2MoO6/reduced graphene oxide/BiOBr for the degradation of organic dye and antibiotic under visible-light irradiation. J Mater Sci 54, 14157–14170 (2019). https://doi.org/10.1007/s10853-019-03883-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-019-03883-0